2,6-Nonadienal, (E,Z)-
- Formula: C9H14O
- Molecular weight: 138.2069
- IUPAC Standard InChIKey: HZYHMHHBBBSGHB-ODYTWBPASA-N
- CAS Registry Number: 557-48-2
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: Nonadien-2(trans)-6-(cis)-al; 2-(trans)-6-(cis)-Nonadienal; 2-trans-6-cis-Nonadien-1-al; trans,cis-2,6-Nonadien-1-al; Cucumber aldehyde; trans,cis-2,6-Nonadienal; trans-2,cis-6-Nonadienal; Violet leaf aldehyde; 2,6-(E,Z)-Nonadienal; (2E,6Z)-Nonadienal; (E)-2,(Z)-6-Nonadienal; (E,Z)-2,6-Nonadienal; (E,Z)-Nona-2,6-dienal; Nona-2,6(E,Z)-dienal; Nona-2(E),6(Z)-dienal; Nona-trans-2,cis-6-dienal; t2,c6-Nonadienal; (2E,6Z)-Nona-2,6-dienal; 2,6-Nonadienal, (2E,6Z)-; 2,6-Nonadienal; (2E,6Z)-2,6-Nonadienal; (E; Z)-2,6-nonadienal; cis,trans-nona-2,6-dienal; (Z,E)-2,6-Nonadienal; (E,Z)-2,6-Nonenal; (2E,6Z)-nona-2,6-dien-1-al
- Permanent link for this species. Use this link for bookmarking this species for future reference.
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- Other data available:
- Options:
Normal alkane RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | PTE-5 | HP-5 MS | DB-5 | RTX-5 MS | 5 % Phenyl methyl siloxane |
Column length (m) | 30. | 30. | 60. | 30. | 30. |
Carrier gas | Helium | Helium | Helium | Helium | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.32 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.50 | 0.25 |
Tstart (C) | 80. | 70. | 35. | 50. | |
Tend (C) | 300. | 290. | 240. | 225. | 250. |
Heat rate (K/min) | 7. | 5. | 6. | 6. | 3. |
Initial hold (min) | 3. | 5. | |||
Final hold (min) | 5. | 10. | 5. | 10. | |
I | 1149. | 1153. | 1154. | 1155. | 1153. |
Reference | Fabri, Coimbra, et al., 2012 | Radulovic, Dordevic, et al., 2010 | Mallia, Escher, et al., 2009 | Watcharananun, Cadwallader, et al., 2009 | Zellner, Bicchi, et al., 2008 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-5 | HP-101 | HP-1 | DB-5 | DB-5 |
Column length (m) | 30. | 25. | 50. | 60. | 30. |
Carrier gas | He | He | He | He | H2 |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.2 | 0.2 | 0.25 | 0.3 |
Phase thickness (μm) | 0.2 | 0.5 | 0.25 | 0.25 | |
Tstart (C) | 70. | 70. | 60. | 35. | 35. |
Tend (C) | 240. | 200. | 250. | 280. | 240. |
Heat rate (K/min) | 5. | 3. | 2. | 5. | 8. |
Initial hold (min) | 2. | 2. | 2.5 | ||
Final hold (min) | 15. | 60. | 4. | 2. | |
I | 1152. | 1145. | 1127. | 1150. | 1148. |
Reference | Asekun, Olusegun, et al., 2007 | Mastelic, Jerkovic, et al., 2006 | Bendimerad and Bendiab, 2005 | Dhanda, Pegg, et al., 2003 | Triqui and Bouchriti, 2003 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-1 | DB-5 | DB-5 | HP-5 | DB-5 |
Column length (m) | 50. | 30. | 30. | 30. | 30. |
Carrier gas | He | He | He | H2 | He |
Substrate | |||||
Column diameter (mm) | 0.2 | 0.32 | 0.32 | 0.32 | 0.32 |
Phase thickness (μm) | 0.5 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 60. | 40. | 40. | 45. | 40. |
Tend (C) | 220. | 230. | 230. | 230. | 290. |
Heat rate (K/min) | 2. | 6. | 6. | 3. | 7. |
Initial hold (min) | 2. | 2. | 1. | ||
Final hold (min) | 40. | 10. | 10. | 10. | |
I | 1117. | 1154. | 1154. | 1148. | 1157. |
Reference | Valette, Fernandez, et al., 2003 | Czerny and Schieberle, 2002 | Czerny and Schieberle, 2002 | Darriet, Pons, et al., 2002 | Lin, Rouseff, et al., 2002 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5MS | DB-5MS | DB-5 | DB-5 | DB-5 |
Column length (m) | 60. | 30. | 30. | 30. | |
Carrier gas | He | He | H2 | H2 | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.32 | 0.32 | 0.32 | |
Phase thickness (μm) | 0.25 | 0.25 | 0.5 | 0.5 | 0.25 |
Tstart (C) | 40. | 40. | 60. | 60. | 34. |
Tend (C) | 200. | 195. | 245. | 245. | 200. |
Heat rate (K/min) | 2. | 5. | 3. | 3. | 5. |
Initial hold (min) | 5. | 5. | 3. | 3. | 3. |
Final hold (min) | 30. | 40. | 20. | 20. | 10. |
I | 1153. | 1151. | 1156. | 1156. | 1148. |
Reference | Lee, Suriyaphan, et al., 2001 | Suriyaphan, Drake, et al., 2001 | Kotseridis and Baumes, 2000 | Kotseridis and Baumes, 2000 | Schlüter, Steinhart, et al., 1999 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5 MS | HP-1 | HP-1 | Ultra-1 | SE-54 |
Column length (m) | 60. | 25. | 25. | 50. | 30. |
Carrier gas | Helium | He | |||
Substrate | |||||
Column diameter (mm) | 0.32 | 0.32 | 0.32 | 0.2 | 0.52 |
Phase thickness (μm) | 0.25 | 1.5 | |||
Tstart (C) | 40. | 35. | 35. | 40. | 5. |
Tend (C) | 200. | 250. | 250. | 240. | 230. |
Heat rate (K/min) | 3. | 4. | 4. | 4. | 6. |
Initial hold (min) | 5. | ||||
Final hold (min) | 30. | 10. | |||
I | 1151. | 1117. | 1117. | 1150. | 1149. |
Reference | Suriyaphan, Drake, et al., 1999 | Ong and Acree, 1998 | Ong, Acree, et al., 1998 | Hashizume and Samuta, 1997 | Milo and Grosch, 1996 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | SE-54 | SE-54 | OV-101 | OV-101 | RTX-5 |
Column length (m) | 30. | 30. | 12. | 15. | 30. |
Carrier gas | He | He | |||
Substrate | |||||
Column diameter (mm) | 0.52 | 0.52 | 0.32 | 0.32 | 0.52 |
Phase thickness (μm) | 1.5 | 1.5 | 1.5 | ||
Tstart (C) | 5. | 5. | 35. | 35. | 5. |
Tend (C) | 230. | 230. | 225. | 250. | 230. |
Heat rate (K/min) | 6. | 6. | 6. | 6. | 6. |
Initial hold (min) | 3. | 3. | |||
Final hold (min) | |||||
I | 1154. | 1154. | 1122. | 1123. | 1149. |
Reference | Milo and Grosch, 1996 | Milo and Grosch, 1996 | Roberts and Acree, 1996 | Chisholm, Guiher, et al., 1995 | Milo and Grosch, 1995 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | OV-101 | OV-101 | OV-101 | OV-101 | DB-1 |
Column length (m) | 50. | 50. | 50. | 50. | 50. |
Carrier gas | N2 | N2 | Nitrogen | Nitrogen | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.32 |
Phase thickness (μm) | |||||
Tstart (C) | 80. | 80. | 70. | 80. | 0. |
Tend (C) | 200. | 200. | 200. | 200. | 250. |
Heat rate (K/min) | 2. | 2. | 2. | 2. | 3. |
Initial hold (min) | |||||
Final hold (min) | |||||
I | 1121. | 1124. | 1126. | 1123. | 1124. |
Reference | Tamura, Nakamoto, et al., 1995 | Tamura, Nakamoto, et al., 1995 | Sugisawa, Nakamura, et al., 1990 | Sugisawa, Nakamura, et al., 1990 | Habu, Flath, et al., 1985 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|
Active phase | DB-1 | OV-101 | OV-101 | DB-1 |
Column length (m) | 50. | 50. | 50. | 60. |
Carrier gas | ||||
Substrate | ||||
Column diameter (mm) | 0.32 | 0.32 | 0.32 | 0.32 |
Phase thickness (μm) | ||||
Tstart (C) | 50. | 40. | 50. | 50. |
Tend (C) | 250. | 225. | 225. | 250. |
Heat rate (K/min) | 3. | 4. | 4. | 4. |
Initial hold (min) | 0.1 | 0.1 | 0.1 | |
Final hold (min) | 30. | 30. | 5. | |
I | 1122. | 1127. | 1124. | 1123. |
Reference | Habu, Flath, et al., 1985 | Stern, Flath, et al., 1985 | Stern, Flath, et al., 1985 | Flath, Mon, et al., 1983 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Fabri, Coimbra, et al., 2012
Fabri, R.F.; Coimbra, E.; Almeida, A.C.; Siqueira, E.P.; Alves, T.M.A.; Zani, C.L.; Scio, E.,
Essential oil of Mitracarpus frigidus as a potent sourse of bioactive compounds,
Annals of the Brazilian Academy of Sciences, 2012, 84, 4, 1073-1080, https://doi.org/10.1590/S0001-37652012000400021
. [all data]
Radulovic, Dordevic, et al., 2010
Radulovic, N.; Dordevic, N.; Markovic, M.; Palic, R.,
Volatile constituents of Glechoma Hirsuta Waldst. Kit. and G. Hederacea L. (Lamiaceae),
Bull. Chem. Soc. Ethiop., 2010, 24, 1, 67-76, https://doi.org/10.4314/bcse.v24i1.52962
. [all data]
Mallia, Escher, et al., 2009
Mallia, S.; Escher, F.; Dubois, S.; Schieberle, P.; Schlichtherle-Cerny, H.,
Characterization and quantification of odor-active compounds in unsaturated fatty acid/conjugated linoleic acid (UFA/CLA)-enriched butter and in conventional butter during storage and induced oxidation,
J. Agric. Food Chem., 2009, 57, 16, 7464-7472, https://doi.org/10.1021/jf9002158
. [all data]
Watcharananun, Cadwallader, et al., 2009
Watcharananun, W.; Cadwallader, K.R.; Huangrak, K.; Kim, H.; Lorjaroenphon, Y.,
Identification of predominant odorants in Thai desserts flavored by smoking with Tian Op, a traditional Thai scented candle,
J. Agric. Food Chem., 2009, 57, 3, 996-1005, https://doi.org/10.1021/jf802674c
. [all data]
Zellner, Bicchi, et al., 2008
Zellner, B.d'A.; Bicchi, C.; Dugo, P.; Rubiolo, P.; Dugo, G.; Mondello, L.,
Linear retention indices in gas chromatographic analysis: a review,
Flavour Fragrance J., 2008, 23, 5, 297-314, https://doi.org/10.1002/ffj.1887
. [all data]
Asekun, Olusegun, et al., 2007
Asekun, O.T.; Olusegun, E.; Adebola, O.,
The volatile constituents of the leaves and flowers of Kigelia africana Benth.,
Flavour Fragr. J., 2007, 22, 1, 21-23, https://doi.org/10.1002/ffj.1723
. [all data]
Mastelic, Jerkovic, et al., 2006
Mastelic, J.; Jerkovic, I.; Mesic, M.,
Volatile constituents from flowers, leaves, bark and wood of Prunus mahaleb L.,
Flavour Fragr. J., 2006, 21, 2, 306-313, https://doi.org/10.1002/ffj.1596
. [all data]
Bendimerad and Bendiab, 2005
Bendimerad, N.; Bendiab, S.A.T.,
Composition and antibacterial activity of Pseudocytisus integrifolius (Salisb.) essential oil from Algeria,
J. Agric. Food Chem., 2005, 53, 8, 2947-2952, https://doi.org/10.1021/jf047937u
. [all data]
Dhanda, Pegg, et al., 2003
Dhanda, J.S.; Pegg, R.B.; Shand, P.J.,
Saskatchewan specialty livestock value-added program - Saskatchewan agri-food innovation fund (AFIF) Project #98000016, 2003, retrieved from http://www.agr.gov.sk.ca/afif/Projects/19980016.pdf. [all data]
Triqui and Bouchriti, 2003
Triqui, R.; Bouchriti, N.,
Freshness assessments of Moroccan sardine (Sardina pilchardus): comparison of overall sensory changes to instrumentally determined volatiles,
J. Agric. Food Chem., 2003, 51, 26, 7540-7546, https://doi.org/10.1021/jf0348166
. [all data]
Valette, Fernandez, et al., 2003
Valette, L.; Fernandez, X.; Poulain, S.; Loiseau, A.-M.; Lizzani-Cuvelier, L.; Levieil, R.; Restier, L.,
Volatile constituents from Romanesco cauliflower,
Food Chem., 2003, 80, 3, 353-358, https://doi.org/10.1016/S0308-8146(02)00272-8
. [all data]
Czerny and Schieberle, 2002
Czerny, M.; Schieberle, P.,
Important aroma compounds in freshly ground wholemeal and white wheat flour-identification and quantitative changes during sourdough fermentation,
J. Agric. Food Chem., 2002, 50, 23, 6835-6840, https://doi.org/10.1021/jf020638p
. [all data]
Darriet, Pons, et al., 2002
Darriet, P.; Pons, M.; Henry, R.; Dumont, O.; Findeling, V.; Cartolaro, P.; Calonnec, A.; Dubourdieu, D.,
Impact odorants contributing to the fungus type aroma from grape berries contaminated by powdery mildew (Uncinula necator); incidence of enzymatic activities of the yeast Saccharomyces cerevisiae,
J. Agric. Food Chem., 2002, 50, 11, 3277-3282, https://doi.org/10.1021/jf011527d
. [all data]
Lin, Rouseff, et al., 2002
Lin, J.; Rouseff, R.L.; Barros, S.; Naim, M.,
Aroma composition changes in early season grapefruit juice produced from thermal concentration,
J. Agric. Food Chem., 2002, 50, 4, 813-819, https://doi.org/10.1021/jf011154g
. [all data]
Lee, Suriyaphan, et al., 2001
Lee, G.-H.; Suriyaphan, O.; Cadwallader, K.R.,
Aroma components of cooked tail meat of American lobster (Homarus americanus),
J. Agric. Food Chem., 2001, 49, 9, 4324-4332, https://doi.org/10.1021/jf001523t
. [all data]
Suriyaphan, Drake, et al., 2001
Suriyaphan, O.; Drake, M.; Chen, X.Q.; Cadwallader, K.R.,
Characteristic aroma components of British farmhouse cheddar cheese,
J. Agric. Food Chem., 2001, 49, 3, 1382-1387, https://doi.org/10.1021/jf001121l
. [all data]
Kotseridis and Baumes, 2000
Kotseridis, Y.; Baumes, R.,
Identification of impact odorants in Bordeaux red grape juice, in the commercial yeast used for its fermentation, and in the produced wine,
J. Agric. Food Chem., 2000, 48, 2, 400-406, https://doi.org/10.1021/jf990565i
. [all data]
Schlüter, Steinhart, et al., 1999
Schlüter, S.; Steinhart, H.; Schwarz, F.J.; Kirchgessner, M.,
Changes in the odorants of boiled carp fillet (Cyprinus carpio L.) as affected by increasing methionine levels in feed,
J. Agric. Food Chem., 1999, 47, 12, 5146-5150, https://doi.org/10.1021/jf9902604
. [all data]
Suriyaphan, Drake, et al., 1999
Suriyaphan, O.; Drake, M.A.; Cadwallader, K.R.,
Identification of volatile off-flavors in reduced-fat cheddar cheeses containing lecitin,
Lebensm.-Wiss. u. Technol., 1999, 32, 5, 250-254, https://doi.org/10.1006/fstl.1999.0543
. [all data]
Ong and Acree, 1998
Ong, P.K.C.; Acree, T.E.,
Gas chromatography/olfactory analysis of lychee (Litchi chinesis Sonn.),
J. Agric. Food Chem., 1998, 46, 6, 2282-2286, https://doi.org/10.1021/jf9801318
. [all data]
Ong, Acree, et al., 1998
Ong, P.K.C.; Acree, T.E.; Lavin, E.H.,
Characterization of volatiles in rambutan fruit (Nephelium lappaceum L.),
J. Agric. Food Chem., 1998, 46, 2, 611-615, https://doi.org/10.1021/jf970665t
. [all data]
Hashizume and Samuta, 1997
Hashizume, K.; Samuta, T.,
Green odorants of grape cluster stem and their ability to cause a wine stemmy flavor,
J. Agric. Food Chem., 1997, 45, 4, 1333-1337, https://doi.org/10.1021/jf960635a
. [all data]
Milo and Grosch, 1996
Milo, C.; Grosch, W.,
Changes in the odorants of boiled salmon and cod as affected by the storage of the raw material,
J. Agric. Food Chem., 1996, 44, 8, 2366-2371, https://doi.org/10.1021/jf9507203
. [all data]
Roberts and Acree, 1996
Roberts, D.D.; Acree, T.E.,
Effects of heating and cream addition on fresh raspberry aroma using a retronasal aroma simulator and gas chromatography olfactometry,
J. Agric. Food Chem., 1996, 44, 12, 3919-3925, https://doi.org/10.1021/jf950701t
. [all data]
Chisholm, Guiher, et al., 1995
Chisholm, M.G.; Guiher, L.A.; Zaczkiewicz, S.M.,
Aroma characteristics of aged Vidal blanc wine,
Am. J. Enol. Vitic, 1995, 46, 1, 56-62. [all data]
Milo and Grosch, 1995
Milo, C.; Grosch, W.,
Detection of odor defects in boiled cod and trout by gas chromatography-olfactometry of headspace samples,
J. Agric. Food Chem., 1995, 43, 2, 459-462, https://doi.org/10.1021/jf00050a038
. [all data]
Tamura, Nakamoto, et al., 1995
Tamura, H.; Nakamoto, H.; Yang, R.-H.; Sugisawa, H.,
Characteristic aroma compounds in green algae (Ulva pertusa) volatiles,
Nippon Shokuhin Kagaku Kogaku Kaishi, 1995, 42, 11, 887-891, https://doi.org/10.3136/nskkk.42.887
. [all data]
Sugisawa, Nakamura, et al., 1990
Sugisawa, H.; Nakamura, K.; Tamura, H.,
The aroma profile of the volatile in marine green algae (Ulva pertusa),
Food Reviews International, 1990, 6, 4, 573-589, https://doi.org/10.1080/87559129009540893
. [all data]
Habu, Flath, et al., 1985
Habu, T.; Flath, R.A.; Mon, T.R.; Morton, J.F.,
Volatile components of Rooibos tea (Aspalathus linearis),
J. Agric. Food Chem., 1985, 33, 2, 249-254, https://doi.org/10.1021/jf00062a024
. [all data]
Stern, Flath, et al., 1985
Stern, D.J.; Flath, R.A.; Mon, T.R.; Teranishi, R.; Lundin, R.E.; Benson, M.E.,
Crude oleic acid volatiles,
J. Agric. Food Chem., 1985, 33, 2, 180-184, https://doi.org/10.1021/jf00062a005
. [all data]
Flath, Mon, et al., 1983
Flath, R.A.; Mon, T.R.; Lorenz, G.; Whitten, C.J.; Mackley, J.W.,
Volatile components of Acacia sp. blossoms,
J. Agric. Food Chem., 1983, 31, 6, 1167-1170, https://doi.org/10.1021/jf00120a008
. [all data]
Notes
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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