(E)-(±)-2-methyl-5-(1-methylvinyl)cyclohex-2-en-1-one oxime

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tfus365.10KN/AMeijer, Blok, et al., 1977Uncertainty assigned by TRC = 0.2 K; adiabatic calorimeter; TRC
Tfus360.KN/ATammann, 1914Uncertainty assigned by TRC = 1. K; TRC

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
24. ± 1.334.HASChickos, Garin, et al., 1981Based on data from 324. - 343. K.; AC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Method Reference Comment
4.0679365.1N/AMeijer, Blok, et al., 1977, 2DH
4.070365.1DTAChickos, Garin, et al., 1981AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
11.1365.1Meijer, Blok, et al., 1977, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meijer, Blok, et al., 1977
Meijer, E.L.; Blok, J.G.; Kroon, J.; Oonk, H.A.J., The carvoxime system. IV. Heat capacities and enthalpies of melting of DL-carvoxime, L-carvoxime and standard n-heptane, Thermochim. Acta, 1977, 20, 325-34. [all data]

Tammann, 1914
Tammann, G., Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1914, 87, 357. [all data]

Chickos, Garin, et al., 1981
Chickos, J.S.; Garin, D.L.; Hitt, M.; Schilling, G., Some solid state properties of enantiomers and their racemates, Tetrahedron, 1981, 37, 12, 2255-2259, https://doi.org/10.1016/S0040-4020(01)97981-5 . [all data]

Meijer, Blok, et al., 1977, 2
Meijer, E.L.; Blok, J.G.; Kroon, J.; Oonk, H.A.J., The carvoxime system. IV. Heat capacities and enthalpies of melting of DL-carvoxime, L-carvoxime and standard n-heptane, Thermochim. Acta, 1977, 20, 325-334. [all data]


Notes

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