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Trimyristin

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DH - Eugene S. Domalski and Elizabeth D. Hearing
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
liquid297.80cal/mol*KN/ACharbonnet and Singleton, 1947For c,«beta». Extrapolation below 90 K, 381.2 J/mol*K.; DH
Quantity Value Units Method Reference Comment
Deltacsolid-6607.00 ± 0.44kcal/molCcbFreedman, Bagby, et al., 1989Corresponding «DELTA»fsolid = -562.85 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
354.0333.Phillips and Mattamal, 1976T = 333 to 433 K.; DH
371.70331.5Charbonnet and Singleton, 1947T = 89 to 365 K. Value is unsmoothed experimental datum. Data for c,«alpha», 192 to 247 K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Charbonnet and Singleton, 1947
Charbonnet, G.H.; Singleton, W.S., Thermal properties of fats and oils. VI. Heat capacity, heats of fusion and transition, and entropy of trilaurin, trimyristin, tripalmitin, and tristearin, J. Am. Oil Chem. Soc., 1947, 24, 140-142. [all data]

Freedman, Bagby, et al., 1989
Freedman, B.; Bagby, M.O.; Khoury, H., Correlation of heats of combustion with empirical formulas for fatty alcohols, J. Am. Oil Chem. Soc., 1989, 66, 595-596. [all data]

Phillips and Mattamal, 1976
Phillips, J.C.; Mattamal, M.M., Correlation of liquid heat capacities for carboxylic esters, J. Chem. Eng. Data, 1976, 21, 228-232. [all data]


Notes

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