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N-Isovaleroylglycine, TMS derivative


Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5OV-1SE-52CP Sil 5 CBUltra-2
Column length (m) 30.10.25. 25.
Carrier gas HeHeHeN2He
Substrate      
Column diameter (mm) 0.250.220.32 0.31
Phase thickness (mum) 1.0.170.52 0.52
Tstart (C) 100.70.70.60.50.
Tend (C) 290.270.270.280.300.
Heat rate (K/min) 4.5.5.6.5.
Initial hold (min) 4.  0.5 
Final hold (min) 10.  5. 
I 1488.1495.1502.1462.1502.
ReferenceKimura, Yamamoto, et al., 1999Lefevere, Verhaeghe, et al., 1989Lefevere, Verhaeghe, et al., 1989Wurth, Kumps, et al., 1989Tuchman, Bowers, et al., 1984
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPacked
Active phase OV-1OV-1
Column length (m) 2.1.8
Carrier gas N2N2
Substrate Anakrom100-120 mesh
Column diameter (mm)   
Phase thickness (mum)   
Tstart (C) 80.70.
Tend (C)  290.
Heat rate (K/min) 4.28.
Initial hold (min)  0.5
Final hold (min)   
I 1464.1464.
ReferenceRamsdell and Tanaka, 1980Tanaka, Hine, et al., 1980
Comment MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kimura, Yamamoto, et al., 1999
Kimura, M.; Yamamoto, T.; Yamaguchi, S., Automated metabolic profiling and interpretation of GC/MS data for organic acidemia screening: a personal computer-based system, Tohoku J. Exp. Med., 1999, 188, 4, 317-334, https://doi.org/10.1620/tjem.188.317 . [all data]

Lefevere, Verhaeghe, et al., 1989
Lefevere, M.F.; Verhaeghe, B.J.; Declerck, D.H.; Van Bocxlaer, J.F.; De Leenheer, A.P.; De Sagher, R.M., Metabolic Profiling of Urinary Organic Acids by Single and Multicolumn Capillary Gas Chromatography, J. Chromatogr. Sci., 1989, 27, 1, 23-29, https://doi.org/10.1093/chromsci/27.1.23 . [all data]

Wurth, Kumps, et al., 1989
Wurth, C.; Kumps, A.; Mardens, Y., Urinary organic acids: Retention indices on two capillary gas chromatography columns, J. Chromatogr., 1989, 491, 186-192, https://doi.org/10.1016/S0378-4347(00)82831-5 . [all data]

Tuchman, Bowers, et al., 1984
Tuchman, M.; Bowers, L.D.; Fregien, K.D.; Crippin, P.J.; Krivit, W., Capillary Gas Chromatographic Separation of Urinary Organic Acids. Retention Indices of 101 Urinary Acids on a 5% Phenylmethyl Silicone Capillary Column, J. Chromatogr. Sci., 1984, 22, 5, 198-202, https://doi.org/10.1093/chromsci/22.5.198 . [all data]

Ramsdell and Tanaka, 1980
Ramsdell, H.S.; Tanaka, K., Gas chromatographic retention indices of twenty metabolically important acylglycines as trimethylsilyl derivatives, J. Chromatogr., 1980, 181, 1, 90-94, https://doi.org/10.1016/S0378-4347(00)81273-6 . [all data]

Tanaka, Hine, et al., 1980
Tanaka, K.; Hine, D.G.; West-Dull, A.; Lynn, T.B., Gas-chromatographic method of analysis for urinary organic acids. I. Retention indices of 155 metabolically important compounds, Clin. Chem., 1980, 26, 13, 1839-1846. [all data]


Notes

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