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Methyl propionate

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Propane, 1,1,1-trimethoxy- + Water = Methyl propionate + 2Methyl Alcohol

By formula: C6H14O3 + H2O = C4H8O2 + 2CH4O

Quantity Value Units Method Reference Comment
Deltar-26.12 ± 0.067kJ/molCmWiberg, Martin, et al., 1985liquid phase; solvent: Aqueous dioxane
Deltar-51.76 ± 0.54kJ/molEqkGuthrie and Cullimore, 1980liquid phase
Deltar-26.28 ± 0.071kJ/molCmWiberg, 1980liquid phase; solvent: Water; Hydrolysis

2Hydrogen + 2-Propynoic acid, methyl ester = Methyl propionate

By formula: 2H2 + C4H4O2 = C4H8O2

Quantity Value Units Method Reference Comment
Deltar-331. ± 4.6kJ/molChydFlitcroft and Skinner, 1958liquid phase; solvent: Ethanol

Methyl propionate + Water = Methyl Alcohol + Propanoic acid

By formula: C4H8O2 + H2O = CH4O + C3H6O2

Quantity Value Units Method Reference Comment
Deltar-60.17 ± 0.92kJ/molEqkGuthrie and Cullimore, 1980liquid phase

Hydrogen + 2-Propenoic acid, methyl ester = Methyl propionate

By formula: H2 + C4H6O2 = C4H8O2

Quantity Value Units Method Reference Comment
Deltar-501.2kJ/molChydVeselova and Sul'man, 1980liquid phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wiberg, Martin, et al., 1985
Wiberg, K.B.; Martin, E.J.; Squires, R.R., Thermochemical studies of carbonyl compounds. 3. Enthalpies of hydrolysis of ortho esters, J. Org. Chem., 1985, 50, 4717-4720. [all data]

Guthrie and Cullimore, 1980
Guthrie, J.P.; Cullimore, P.A., Effect of the acyl substituent on the equilibrium constant for hydration of esters, Can. J. Chem., 1980, 58, 1281-1294. [all data]

Wiberg, 1980
Wiberg, K.B., Energies of organic compounds, Rept. DOE-E(11-1)4060 Prepared for US Dept. of Energy by Yale Univ., New Haven, CT. Avail. NTIS, 1980, 1-24. [all data]

Flitcroft and Skinner, 1958
Flitcroft, T.L.; Skinner, H.A., Heats of hydrogenation Part 2.-Acetylene derivatives, Trans. Faraday Soc., 1958, 54, 47-53. [all data]

Veselova and Sul'man, 1980
Veselova, M.E.; Sul'man, E.M., Effect of the chemical structure of «alpha»,«beta»-unsaturated esters and ketones on the selectivity of their hydrogenation, Svoistva Veshchestv i Stroenie Molekul, Kalinin, 1980, 140-143. [all data]


Notes

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