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Homogentisic acid, 3TMS derivative


Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Van Den Dool and Kratz RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryDB-51860.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryDB-51863.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryDB-51864.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ht1863.Jaroszynska and Ligor, 200530. m/0.25 mm/0.1 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ht1867.Jaroszynska and Ligor, 200530. m/0.25 mm/0.1 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ht1867.Jaroszynska and Ligor, 200530. m/0.25 mm/0.1 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ht1867.Jaroszynska and Ligor, 200530. m/0.25 mm/0.1 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryPE-5ms1839.Jaroszynska and Ligor, 200530. m/0.25 mm/0.25 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 320. C
CapillaryDB-51855.Jaroszynska, 200330. m/0.25 mm/0.25 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 240. C
CapillaryDB-51864.Jaroszynska, 200330. m/0.25 mm/0.25 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 240. C
CapillaryDB-51852.Jaroszynska, 200330. m/0.25 mm/0.25 «mu»m, He, 7. K/min; Tstart: 50. C; Tend: 240. C
CapillaryDB-51861.Jaroszynska, 200330. m/0.25 mm/0.25 «mu»m, He, 7. K/min; Tstart: 50. C; Tend: 240. C
CapillaryCP Sil 5 CB1850.Halket, Przyborowska, et al., 199925. m/0.15 mm/0.12 «mu»m, 90. C @ 1. min, 10. K/min, 270. C @ 7. min
CapillaryDB-51850.Kimura, Yamamoto, et al., 199930. m/0.25 mm/1. «mu»m, He, 100. C @ 4. min, 4. K/min, 290. C @ 10. min
CapillaryOV-11860.Lefevere, Verhaeghe, et al., 198910. m/0.22 mm/0.17 «mu»m, He, 5. K/min; Tstart: 70. C; Tend: 270. C
CapillarySE-521859.Lefevere, Verhaeghe, et al., 198925. m/0.32 mm/0.52 «mu»m, He, 5. K/min; Tstart: 70. C; Tend: 270. C
PackedOV-11841.Butts, 1972He, Chromosorb W HP (80-100 mesh), 10. K/min; Column length: 2. m; Tstart: 100. C; Tend: 325. C

Van Den Dool and Kratz RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryVF-5MS1822.7Tret'yakov, 200730. m/0.25 mm/0.25 «mu»m, He; Program: Multi-step temperature program; T(initial)=60C; T(final)=270C
CapillaryDB-11834.Tsai, Oliphant, et al., 1985He; Program: not specified

Normal alkane RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryHP-51859.Isidorov, Kotowska, et al., 200530. m/0.25 mm/0.25 «mu»m, He; Tstart: 50. C; Tend: 300. C
CapillaryHP-51853.Isidorov, Kotowska, et al., 200530. m/0.25 mm/0.25 «mu»m, He, 5. K/min; Tstart: 50. C; Tend: 300. C
CapillaryHP-5MS1872.Lee, Yanamandra, et al., 200230. m/0.25 mm/0.25 «mu»m, He, 70. C @ 3. min, 4. K/min, 280. C @ 3. min

References

Go To: Top, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jaroszynska and Ligor, 2005
Jaroszynska, J.; Ligor, T., The identification of phenolic compounds by a gas chromatographic method on three capillary columns with the same non-polar stationary phase, Anal. Chim. Acta., 2005, 539, 1-2, 11-15, https://doi.org/10.1016/j.aca.2005.03.024 . [all data]

Jaroszynska, 2003
Jaroszynska, J., Isolation of free phenolic compounds from arboreal leaves by use of the Florisil/C18 system, Anal. Bioanal. Chem., 2003, 377, 4, 702-708, https://doi.org/10.1007/s00216-003-2155-z . [all data]

Halket, Przyborowska, et al., 1999
Halket, J.N.; Przyborowska, A.; Stein, S.E.; Mallard, W.G.; Down, S.; Chalmers, R., Deconvolution gas chromatography / mass spectrometry of urinary organic acids - potential for pattern recognition and automated identification of metabolic disorders, Rapid Commun. Mass spectrom., 1999, 13, 4, 279-284, https://doi.org/10.1002/(SICI)1097-0231(19990228)13:4<279::AID-RCM478>3.0.CO;2-I . [all data]

Kimura, Yamamoto, et al., 1999
Kimura, M.; Yamamoto, T.; Yamaguchi, S., Automated metabolic profiling and interpretation of GC/MS data for organic acidemia screening: a personal computer-based system, Tohoku J. Exp. Med., 1999, 188, 4, 317-334, https://doi.org/10.1620/tjem.188.317 . [all data]

Lefevere, Verhaeghe, et al., 1989
Lefevere, M.F.; Verhaeghe, B.J.; Declerck, D.H.; Van Bocxlaer, J.F.; De Leenheer, A.P.; De Sagher, R.M., Metabolic Profiling of Urinary Organic Acids by Single and Multicolumn Capillary Gas Chromatography, J. Chromatogr. Sci., 1989, 27, 1, 23-29, https://doi.org/10.1093/chromsci/27.1.23 . [all data]

Butts, 1972
Butts, W.C., Two-Column Gas Chromatography of Trimethylsilyl Derivatives of Biochemically Significant Compounds, Anal. Biochemistry, 1972, 46, 1, 187-199, https://doi.org/10.1016/0003-2697(72)90411-3 . [all data]

Tret'yakov, 2007
Tret'yakov, K.V., Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2007. [all data]

Tsai, Oliphant, et al., 1985
Tsai, M.Y.; Oliphant, C.; Josephson, M.W., Identification of Metabolites Diagnostic for Organic Acidurias by Simultaneous Dual-Column Capillary Gas Chromatography, J. Chromatogr., 1985, 341, 1-10, https://doi.org/10.1016/S0378-4347(00)84004-9 . [all data]

Isidorov, Kotowska, et al., 2005
Isidorov, V.A.; Kotowska, U.; Vinogorova, V.T., GC Identification of organic compounds based on partition coefficients of their TMS derivatives in a hexane-acetonitrile system and retention indices, Anal. Sci., 2005, 21, 12, 1483-1489, https://doi.org/10.2116/analsci.21.1483 . [all data]

Lee, Yanamandra, et al., 2002
Lee, B.Y.; Yanamandra, K.; Thurmon, T.F., Quantitative estimation of organic analytes with a capillary column, Am. Clin. Lab., 2002, May, 30-34. [all data]


Notes

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