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2-Propenoic acid, 2-[(trimethylsilyl)oxy]-, trimethylsilyl ester


Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryPacked
Active phase CP Sil 5 CBOV-1SE-52OV-1
Column length (m) 25.10.25.2.
Carrier gas  HeHeHe
Substrate    Chromosorb W HP (80-100 mesh)
Column diameter (mm) 0.150.220.32 
Phase thickness (mum) 0.120.170.52 
Tstart (C) 90.70.70.100.
Tend (C) 270.270.270.325.
Heat rate (K/min) 10.5.5.10.
Initial hold (min) 1.   
Final hold (min) 7.   
I 1100.1085.1090.1091.
ReferenceHalket, Przyborowska, et al., 1999Lefevere, Verhaeghe, et al., 1989Lefevere, Verhaeghe, et al., 1989Butts, 1972
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Halket, Przyborowska, et al., 1999
Halket, J.N.; Przyborowska, A.; Stein, S.E.; Mallard, W.G.; Down, S.; Chalmers, R., Deconvolution gas chromatography / mass spectrometry of urinary organic acids - potential for pattern recognition and automated identification of metabolic disorders, Rapid Commun. Mass spectrom., 1999, 13, 4, 279-284, https://doi.org/10.1002/(SICI)1097-0231(19990228)13:4<279::AID-RCM478>3.0.CO;2-I . [all data]

Lefevere, Verhaeghe, et al., 1989
Lefevere, M.F.; Verhaeghe, B.J.; Declerck, D.H.; Van Bocxlaer, J.F.; De Leenheer, A.P.; De Sagher, R.M., Metabolic Profiling of Urinary Organic Acids by Single and Multicolumn Capillary Gas Chromatography, J. Chromatogr. Sci., 1989, 27, 1, 23-29, https://doi.org/10.1093/chromsci/27.1.23 . [all data]

Butts, 1972
Butts, W.C., Two-Column Gas Chromatography of Trimethylsilyl Derivatives of Biochemically Significant Compounds, Anal. Biochemistry, 1972, 46, 1, 187-199, https://doi.org/10.1016/0003-2697(72)90411-3 . [all data]


Notes

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