SiH2 radical anion


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Td = 9070 ± 160 gas Kasdan, Herbst, et al., 1975

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1b2 1,3 Stretch 1823 Ne IR Andrews and Wang, 2002
a1 2 Bend 1200 ± 160 gas PE Kasdan, Herbst, et al., 1975

Additional references: Jacox, 1994, page 21

Notes

dPhotodissociation threshold

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kasdan, Herbst, et al., 1975
Kasdan, A.; Herbst, E.; Lineberger, W.C., Laser photoelectron spectrometry of the negative ions of silicon and its hydrides, J. Chem. Phys., 1975, 62, 541. [all data]

Andrews and Wang, 2002
Andrews, L.; Wang, X., Infrared Spectra of the Novel Si, J. Phys. Chem. A, 2002, 106, 34, 7696, https://doi.org/10.1021/jp0204814 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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