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Dimethylzinc

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
9.00 ± 0.02PIDistefano and Dibeler, 1970RDSH
8.86 ± 0.15EIWinters and Kiser, 1967RDSH
9.4PECreber and Bancroft, 1980Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH3+15.1 ± 0.5?EIWinters and Kiser, 1967RDSH
CH3Zn+10.22 ± 0.02CH3PIDistefano and Dibeler, 1970RDSH
CH3Zn+11.2 ± 0.2CH3EIWinters and Kiser, 1967RDSH
ZnH+13.9 ± 0.4?EIWinters and Kiser, 1967RDSH
Zn+13.13 ± 0.022CH3PIDistefano and Dibeler, 1970RDSH
Zn+13.4 ± 0.32CH3EIWinters and Kiser, 1967RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Distefano and Dibeler, 1970
Distefano, G.; Dibeler, V.H., Photoionization study of the dimethyl compounds of zinc, cadmium, and mercury, Intern. J. Mass Spectrom. Ion Phys., 1970, 4, 59. [all data]

Winters and Kiser, 1967
Winters, R.E.; Kiser, R.W., Ionization and fragmentation of dimethylzinc, trimethylaluminum, and trimethylantimony, J. Organometal. Chem., 1967, 10, 7. [all data]

Creber and Bancroft, 1980
Creber, D.K.; Bancroft, G.M., Photoelectron studies of dialkyl group 2B compounds: Ligand field splittings intensity variations with photon energy, Inorg. Chem., 1980, 19, 643. [all data]


Notes

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