Tetradecanoic acid

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Normal alkane RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-1DB-5VF-5 MSVF-5 MSHP-5 MS
Column length (m) 60.25.60.60.30.
Carrier gas HeliumHeliumHeliumHeliumHelium
Substrate      
Column diameter (mm) 0.220.200.320.320.25
Phase thickness (μm) 0.250.330.250.250.25
Tstart (C) 60.50.30.30.40.
Tend (C) 230.240.260.260.260.
Heat rate (K/min) 2.20.2.2.4.
Initial hold (min)  1.   
Final hold (min) 5. 28.28.5.
I 1761.1751.1762.1763.1766.
ReferenceBendiabdellah, El Amine Dib, et al., 2012Cais-Sokolinska, Majcher, et al., 2011Leffingwell and Alford, 2011Leffingwell and Alford, 2011Miyazawa, Marumoto, et al., 2011
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP-Sil 5 CBMethylsiloxane + 5 % Ph-groupsZB-5RTX-1HP-5 MS
Column length (m) 30.30.30.60.30.
Carrier gas NitrogenHeliumNitrogenHeliumHelium
Substrate      
Column diameter (mm) 0.250.250.250.220.25
Phase thickness (μm) 0.260.250.250.250.25
Tstart (C) 45.60.40.60.70.
Tend (C) 280.230.200.230.290.
Heat rate (K/min) 3.7.5.2.5.
Initial hold (min)  2.5.  
Final hold (min) 22.20. 30.10.
I 1744.1774.1767.1761.1765.
ReferenceMothana, Hasson, et al., 2011Nadim, Malik, et al., 2011Vazques, Aimar, et al., 2011Dib, Djabou, et al., 2010Radulovic, Blagojevic, et al., 2010
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5 MSDB-1HP-5 MSHP-5 MS
Column length (m) 30.30.30.30.30.
Carrier gas HydrogenHeliumHeliumHeliumHelium
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 70.70.50.35.70.
Tend (C) 290.290.220.195.290.
Heat rate (K/min) 5.5.4.2.5.
Initial hold (min)   2.5. 
Final hold (min)  10.2.30.10.
I 1763.1763.1746.1761.1762.
ReferenceRadulovic, Dordevic, et al., 2010Radulovic, Dordevic, et al., 2010, 2Xu, Tang, et al., 2010Kim and Chung, 2009Radulovic, Blagojevic, et al., 2009
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-1HP-5 MSHP-5 MSHP-5HP-5MS
Column length (m) 25.30.30.30.30.
Carrier gas  HeliumHeliumHeHe
Substrate      
Column diameter (mm) 0.320.250.250.250.25
Phase thickness (μm) 0.170.250.25 0.25
Tstart (C) 50.50.50.70.60.
Tend (C) 260.280.230.240.250.
Heat rate (K/min) 1.4.4.5.2.
Initial hold (min) 5. 4. 8.
Final hold (min) 5. 10. 15.
I 1747.1763.1780.1765.1771.
ReferenceWetwiayaklung, Thavanapong, et al., 2009Zhao, Zeng, et al., 2009Forero, Quijano, et al., 2008Asekun, Olusegun, et al., 2007Ferhat, Tigrine-Kordjani, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5DB-5DB-5DB-5DB-1
Column length (m) 25.30.30.30.60.
Carrier gas HeliumHeHeHe 
Substrate      
Column diameter (mm) 0.320.250.250.250.25
Phase thickness (μm) 0.520.250.250.250.25
Tstart (C) 40.60.60.60.60.
Tend (C) 280.320.240.240.250.
Heat rate (K/min) 4.10.5.5.5.
Initial hold (min)   2.2. 
Final hold (min)  4.  10.
I 1762.1748.1742.1742.1741.
ReferencePavlovic, Petrovic, et al., 2007Smelcerovic, Spiteller, et al., 2007Gohari, Hadjiakhoondi, et al., 2006Gohari A.R., Hadjiakhoondi A., et al., 2006Hadian, Sonboli, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5PE-5SPB-5HP-5DB-5
Column length (m) 30.50.30.30.30.
Carrier gas HeHeHeliumH2He
Substrate      
Column diameter (mm) 0.250.320.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.100.60.50.40.
Tend (C) 220.280.250.280.260.
Heat rate (K/min) 4.3.4.4.2.
Initial hold (min)  1.2.2.5.
Final hold (min)   20.10.20.
I 1771.1765.1769.1782.1769.
ReferenceMorteza-Semnani, Akbarzadeh, et al., 2006Pandey-Rai S., Mallavarapu G.R., et al., 2006Pino, Marquez, et al., 2006Pino, Sauri-Duch, et al., 2006Senatore, Landolfi, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5 MSHP-5MSHP-5HP-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeliumHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.32
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.60.60.60.60.
Tend (C) 250.250.280.250.260.
Heat rate (K/min) 4.2.3.10.5.
Initial hold (min) 2.8. 2.2.
Final hold (min) 10.15. 10.14.
I 1769.1771.1750.1765.1764.
ReferenceShen X., Gao Y., et al., 2006Tigrine-Kordiani, Meklati, et al., 2006Tzakou, Said, et al., 2006Wang, Yang, et al., 2006Yayli, Gülec, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5BPX5HP-5DB-5SPB-5
Column length (m) 30.25.60.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.320.200.320.250.25
Phase thickness (μm) 0.250.130.250.250.25
Tstart (C) 60.50.30.60.60.
Tend (C) 260.230.260.240.250.
Heat rate (K/min) 5.3.2.3.4.
Initial hold (min) 2.2.2. 2.
Final hold (min) 14. 28. 20.
I 1769.1765.1768.01757.1782.
ReferenceYayli, Gülec, et al., 2006Boustie, Rapior, et al., 2005Leffingwell and Alford, 2005Miyazawa, Nishiguchi, et al., 2005Pino, Marbot, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5BP-1HP-5HP-5HP-5
Column length (m) 30.30.30.30.30.
Carrier gas HeN2HeliumHeliumHelium
Substrate      
Column diameter (mm) 0.250.320.320.320.32
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.60.40.40.40.
Tend (C) 260.220.250.250.250.
Heat rate (K/min) 2.5.5.5.5.
Initial hold (min) 5. 2.2.2.
Final hold (min) 20.15.5.5.5.
I 1769.1760.1769.1770.1771.
ReferenceSenatore, Apostolides Arnold, et al., 2005Srivastava, Srivastava, et al., 2005N/AN/AN/A
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5SE-30DB-5SPB-5
Column length (m) 30.30.50.30.30.
Carrier gas HeH2HeHeHelium
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.60.70.60.60.
Tend (C) 250.280.240.220.250.
Heat rate (K/min) 2.4.4.4.4.
Initial hold (min) 5.10. 5.2.
Final hold (min) 20.40.  20.
I 1768.1773.1795.1777.1780.
ReferenceSenatore, Rigano, et al., 2004Pino, Marbot, et al., 2003Iñigo, Palá-Paúl, et al., 2002Morteza-Semnani, Saeedi, et al., 2002Pino, Marbot, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Optima-1Optima-1HP-5DB-1OV-101
Column length (m) 25.25.30.25.50.
Carrier gas HeHeH2HeNitrogen
Substrate      
Column diameter (mm) 0.200.200.250.250.25
Phase thickness (μm) 0.250.250.250.13 
Tstart (C) 50.50.40.60.40.
Tend (C) 250.250.280.200.200.
Heat rate (K/min) 3.3.3.4.2.
Initial hold (min) 3.3.10.2.10.
Final hold (min)   10.  
I 1770.1765.1776.1783.1741.
ReferenceBrun, Bessière, et al., 2001de Beck, Bessière, et al., 2000Bicalho, Pereira, et al., 2000Rapior, Konska, et al., 2000Tamura, Boonbumrung, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSMethyl SiliconeHP-1Optima 1Ultra-2
Column length (m) 30.50.25.25.50.
Carrier gas HeH2H2HeliumHe
Substrate      
Column diameter (mm) 0.250.250.320.200.32
Phase thickness (μm) 0.250.50.170.250.52
Tstart (C) 40.40.40.50.40.
Tend (C) 280.260.260.200.250.
Heat rate (K/min) 10.4.3.3.4.
Initial hold (min) 1.0.55. 3.
Final hold (min) 20.   30.
I 1768.1755.1751.1783.1786.
ReferenceTkachev, Dobrotvorsky, et al., 2000Vendramini and Trugo, 2000Lopes, Koketsu, et al., 1999Fons, Rapior, et al., 1998King, Matthews, et al., 1995
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Cross-Linked MethylsiliconeDB-5Ultra-1DB-1DB-1
Column length (m) 25.60.25.60.60.
Carrier gas He HeHeHe
Substrate      
Column diameter (mm) 0.320.250.320.250.25
Phase thickness (μm)  0.250.250.250.25
Tstart (C) 35.40.80.50.50.
Tend (C) 225.250.260.240.240.
Heat rate (K/min) 4.2.3.3.3.
Initial hold (min) 3.5.   
Final hold (min)      
I 1747.1770.1764.1748.1748.
ReferenceBravo and Hotchkiss, 1993Lee, Macku, et al., 1991Okumura, 1991Shiota, 1991Shiota, 1991
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillary
Active phase OV-101OV-101SE-54
Column length (m) 50.50.25.
Carrier gas NitrogenNitrogenN2
Substrate    
Column diameter (mm) 0.250.250.25
Phase thickness (μm)    
Tstart (C) 70.80.60.
Tend (C) 200.200.260.
Heat rate (K/min) 2.2.6.
Initial hold (min)   2.
Final hold (min)    
I 1760.1760.1773.
ReferenceSugisawa, Nakamura, et al., 1990Sugisawa, Nakamura, et al., 1990Bestmann, Classen, et al., 1988
Comment MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Tigrine-Kordiani, Meklati, et al., 2006
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Boustie, Rapior, et al., 2005
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Miyazawa, Nishiguchi, et al., 2005
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Notes

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