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Butanamide

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil489.2KN/AWeast and Grasselli, 1989BS
Quantity Value Units Method Reference Comment
Tfus388.8KN/ADavies, Jones, et al., 1959Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Deltasub82. ± 4.0kJ/molTEBrunetti, Gatta, et al., 2000Based on data from 288. - 354. K.; AC
Deltasub82. ± 4.0kJ/molTEBrunetti, Gatta, et al., 2000Based on data from 298. - 347. K.; AC
Deltasub86.36 ± 0.42kJ/molVBarnes and Pilcher, 1975ALS
Deltasub85.4 ± 1.7kJ/molMELebedeva and Katin, 1973Based on data from 292. - 304. K. See also Pedley and Rylance, 1977.; AC
Deltasub85. ± 2.kJ/molVLebedeva and Katin, 1973, 2ALS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
64.412.AStephenson and Malanowski, 1987Based on data from 397. - 504. K.; AC

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
87.363.N/AJones, 1960Based on data from 353. - 373. K.; AC
86.4 ± 0.4359.GSDavies, Jones, et al., 1959Based on data from 336. - 382. K.; AC
87.0 ± 0.8320.MEDavies, Jones, et al., 1959Based on data from 298. - 341. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
19.2387.3Abate, Badea, et al., 2008AC
19.2387.3Brunetti, Gatta, et al., 2000AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Davies, Jones, et al., 1959
Davies, M.; Jones, A.H.; Thomas, G.H., The lattice energies of the straight-chain primary amides, Trans. Faraday Soc., 1959, 55, 1100. [all data]

Brunetti, Gatta, et al., 2000
Brunetti, Bruno; Gatta, Giuseppe Della; Piacente, Vincenzo, Enthalpies and Entropies of Sublimation of Some Primary Alkylamides, J. Chem. Eng. Data, 2000, 45, 2, 237-241, https://doi.org/10.1021/je9902701 . [all data]

Barnes and Pilcher, 1975
Barnes, D.S.; Pilcher, G., Enthalpies of combustion of ethanamide, propanamide, and butanamide, J. Chem. Thermodyn., 1975, 7, 377-382. [all data]

Lebedeva and Katin, 1973
Lebedeva, N.D.; Katin, Y.A., Russ. J. Appl. Chem., 1973, 46, 2131. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., , Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brighton, 1977. [all data]

Lebedeva and Katin, 1973, 2
Lebedeva, N.D.; Katin, Yu.A., Enthalpies of formation of monocarboxylic acid amides, J. Appl. Chem. USSR (Engl. Transl.), 1973, 46, 2131-21. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Jones, 1960
Jones, A.H., Sublimation Pressure Data for Organic Compounds., J. Chem. Eng. Data, 1960, 5, 2, 196-200, https://doi.org/10.1021/je60006a019 . [all data]

Abate, Badea, et al., 2008
Abate, Lorenzo; Badea, Elena; Blanco, Ignazio; Della Gatta, Giuseppe, Heat Capacities and Enthalpies of Solid-Solid Transitions and Fusion of a Series of Eleven Primary Alkylamides by Differential Scanning Calorimetry, J. Chem. Eng. Data, 2008, 53, 4, 959-965, https://doi.org/10.1021/je700662a . [all data]


Notes

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