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CF3 anion


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Clustering reactions

(CF3- bullet 4294967295Methylene, difluoro-) + Methylene, difluoro- = CF3-

By formula: (CF3- bullet 4294967295CF2) + CF2 = CF3-

Quantity Value Units Method Reference Comment
Deltar49.8 ± 2.4kcal/molN/ADeyerl, Alconcel, et al., 2001gas phase; Adiabatic EA, from vibrational structure of spectrum; B
Deltar50.9 ± 2.9kcal/molN/ABartmess, Scott, et al., 1979gas phase; Paulino and Squires, 1991 suggests that this acidity may be too weak by ca. 5 kcal/mol. However, G2 calcn(JEB) give «DELTA»Hacid=379.9, «DELTA»Gacid=372.0; value altered from reference due to change in acidity scale; B
Deltar55.9 ± 2.7kcal/molCIDTPaulino and Squires, 1991gas phase; Neutral heat is based on a fluoroform acidity that may be too weak by up to 5 kcal/mol; B

CF3- + Tetrafluoromethane = (CF3- bullet Tetrafluoromethane)

By formula: CF3- + CF4 = (CF3- bullet CF4)

Quantity Value Units Method Reference Comment
Deltar3.6kcal/molPHPMSHiraoka, Nasu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KPHPMSHiraoka, Nasu, et al., 1995gas phase; M

(CF3- bullet Tetrafluoromethane) + Tetrafluoromethane = (CF3- bullet 2Tetrafluoromethane)

By formula: (CF3- bullet CF4) + CF4 = (CF3- bullet 2CF4)

Quantity Value Units Method Reference Comment
Deltar3.4kcal/molPHPMSHiraoka, Nasu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KPHPMSHiraoka, Nasu, et al., 1995gas phase; M

(CF3- bullet 2Tetrafluoromethane) + Tetrafluoromethane = (CF3- bullet 3Tetrafluoromethane)

By formula: (CF3- bullet 2CF4) + CF4 = (CF3- bullet 3CF4)

Quantity Value Units Method Reference Comment
Deltar3.4kcal/molPHPMSHiraoka, Nasu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KPHPMSHiraoka, Nasu, et al., 1995gas phase; M

(CF3- bullet 3Tetrafluoromethane) + Tetrafluoromethane = (CF3- bullet 4Tetrafluoromethane)

By formula: (CF3- bullet 3CF4) + CF4 = (CF3- bullet 4CF4)

Quantity Value Units Method Reference Comment
Deltar3.4kcal/molPHPMSHiraoka, Nasu, et al., 1995gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KN/AHiraoka, Nasu, et al., 1995gas phase; Entropy change calculated or estimated; M

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Deyerl, Alconcel, et al., 2001
Deyerl, H.J.; Alconcel, L.S.; Continetti, R.E., Photodetachment imaging studies of the electron affinity of CF3, J. Phys. Chem. A, 2001, 105, 3, 552-557, https://doi.org/10.1021/jp003137k . [all data]

Bartmess, Scott, et al., 1979
Bartmess, J.E.; Scott, J.A.; McIver, R.T., Jr., The gas phase acidity scale from methanol to phenol, J. Am. Chem. Soc., 1979, 101, 6047. [all data]

Paulino and Squires, 1991
Paulino, J.A.; Squires, R.R., Carbene Thermochemistry from Collision-Induced Dissociation Threshold Energy Measurements - The Heats of Formation of X1A1 CF2 and X1A1 CCl2, J. Am. Chem. Soc., 1991, 113, 15, 5573, https://doi.org/10.1021/ja00015a009 . [all data]

Hiraoka, Nasu, et al., 1995
Hiraoka, K.; Nasu, M.; Fujimaki, S.; Ignacio, E.W.; Yamabe, S., Weak Ion-Molecule Complexes of F-(CF4)n and CF3-(CF4)n, Chem Phys. Let., 1995, 245, 1, 14, https://doi.org/10.1016/0009-2614(95)00980-I . [all data]


Notes

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