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n-Propyl chloride

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

Bromine anion + n-Propyl chloride = (Bromine anion bullet n-Propyl chloride)

By formula: Br- + C3H7Cl = (Br- bullet C3H7Cl)

Quantity Value Units Method Reference Comment
Deltar50.6 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar24.9 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

n-Propyl chloride = Propane, 2-chloro-

By formula: C3H7Cl = C3H7Cl

Quantity Value Units Method Reference Comment
Deltar-12.7 ± 0.8kJ/molEqkKabo and Andreevskii, 1965gas phase; Correction by Andreevskii, 1972; ALS

Hydrogen + n-Propyl chloride = Propane + Hydrogen chloride

By formula: H2 + C3H7Cl = C3H8 + HCl

Quantity Value Units Method Reference Comment
Deltar-65.81 ± 0.67kJ/molChydDavies, Lacher, et al., 1965gas phase; ALS

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Li, Ross, et al., 1996
Li, C.; Ross, P.; Szulejko, J.; McMahon, T.B., High-Pressure Mass Spectrometric Investigations of the Potential Energy Surfaces of Gas-Phase Sn2 Reactions., J. Am. Chem. Soc., 1996, 118, 39, 9360, https://doi.org/10.1021/ja960565o . [all data]

Kabo and Andreevskii, 1965
Kabo, G. Ya; Andreevskii, D.N., Thermodynamics of monochloropropane isomerization, Neftekhimiya, 1965, 5, 132-135. [all data]

Andreevskii, 1972
Andreevskii, D.N., Thermochemistry of organic halogeno-compounds, Russ. J. Phys. Chem. (Engl. Transl.), 1972, 46, 819-820. [all data]

Davies, Lacher, et al., 1965
Davies, J.; Lacher, J.R.; Park, J.D., Reaction heats of organic compounds. Part 4.-Heats of hydrogenation of n- and iso-Propyl bromides and chlorides, Trans. Faraday Soc., 1965, 61, 2413-2416. [all data]


Notes

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