Benzene, (2-methylpropyl)-
- Formula: C10H14
- Molecular weight: 134.2182
- IUPAC Standard InChIKey: KXUHSQYYJYAXGZ-UHFFFAOYSA-N
- CAS Registry Number: 538-93-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Benzene, isobutyl-; Isobutylbenzene; 2-Methyl-1-phenylpropane; (2-Methylpropyl)benzene; i-Butylbenzene; 1-Phenylisobutane; 1-Phenyl-2-methylpropane
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Kovats' RI, non-polar column, isothermal
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-1 | HP-1 | OV-101 | OV-101 | OV-101 |
Column length (m) | 25. | 25. | 50. | 50. | 85. |
Carrier gas | N2 | N2 | N2 | ||
Substrate | |||||
Column diameter (mm) | 0.20 | 0.20 | 0.25 | 0.30 | 0.28 |
Phase thickness (μm) | |||||
Temperature (C) | 60. | 60. | 100. | 100. | 100. |
I | 990. | 990. | 1002. | 1003. | 1002. |
Reference | Zhang, Li, et al., 1992 | Zhang, Li, et al., 1992 | Dimov and Mekenyan, 1989 | Engewald, Topalova, et al., 1987 | Boneva, Papazova, et al., 1983 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | OV-101 | OV-101 | OV-101 | DB-1 | DB-1 |
Column length (m) | 85. | 85. | 85. | 60. | 60. |
Carrier gas | N2 | N2 | N2 | ||
Substrate | |||||
Column diameter (mm) | 0.28 | 0.28 | 0.28 | 0.264 | 0.259 |
Phase thickness (μm) | 1. | ||||
Temperature (C) | 100. | 110. | 90. | 60. | 60. |
I | 1002. | 1004. | 999. | 990.5 | 990.9 |
Reference | Boneva, Papazova, et al., 1983 | Boneva, Papazova, et al., 1983 | Boneva, Papazova, et al., 1983 | Lubeck and Sutton, 1983 | Lubeck and Sutton, 1983 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Packed | Capillary |
---|---|---|---|---|---|
Active phase | SE-30 | Squalane | Squalane | Squalane | Squalane |
Column length (m) | 15. | 50. | 50. | 1. | 50. |
Carrier gas | N2 | N2 | N2 | He | N2 |
Substrate | Chromaton N-AW-HMDS | ||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | ||
Phase thickness (μm) | |||||
Temperature (C) | 70. | 86. | 96. | 100. | 86. |
I | 994.3 | 985.5 | 988.3 | 989. | 985.2 |
Reference | Tóth, 1983 | Macák, Nabivach, et al., 1982 | Macák, Nabivach, et al., 1982 | Nabivach and Kirilenko, 1980 | Nabivach and Kirilenko, 1979 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | Squalane | Squalane | Squalane | Squalane | Squalane |
Column length (m) | 50. | 50. | 100. | 120. | 120. |
Carrier gas | N2 | N2 | He | He | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.23 | 0.25 | 0.25 | |
Phase thickness (μm) | |||||
Temperature (C) | 86. | 96. | 100. | 100. | 100. |
I | 985.5 | 988.3 | 991. | 986.7 | 986.7 |
Reference | Nabivach and Kirilenko, 1979 | Nabivach, Bur'yan, et al., 1978 | Engewald and Wennrich, 1976 | Lulova, Leont'eva, et al., 1976 | Lulova, Leont'eva, et al., 1976 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Packed |
---|---|---|---|---|---|
Active phase | Squalane | SE-30 | SE-30 | Squalane | Apiezon L |
Column length (m) | 100. | 25.5 | 25.5 | 10.5 | 10. |
Carrier gas | H2 | He | He | He | |
Substrate | Chromosorb P | ||||
Column diameter (mm) | 0.25 | 0.5 | 0.5 | 0.25 | |
Phase thickness (μm) | |||||
Temperature (C) | 80. | 65. | 65. | 100. | 100. |
I | 982.35 | 993.1 | 993.1 | 989.8 | 1014. |
Reference | Soják and Rijks, 1976 | Svob, Deur-Siftar, et al., 1974 | Svob and Deur-Siftar, 1974 | Svob and Deur-Siftar, 1974 | Bonastre and Grenier, 1967 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Packed | Packed | Packed | Packed |
---|---|---|---|---|
Active phase | Apiezon L | Squalane | Squalane | Methyl Silicone |
Column length (m) | 10. | 6. | 6. | |
Carrier gas | ||||
Substrate | Chromosorb P | Chromosorb P | Chromosorb P | |
Column diameter (mm) | ||||
Phase thickness (μm) | ||||
Temperature (C) | 80. | 120. | 140. | 130. |
I | 1010. | 985. | 995. | 1012. |
Reference | Bonastre and Grenier, 1967 | Bonastre and Grenier, 1967 | Bonastre and Grenier, 1967 | Antheaume and Guiochon, 1965 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Kovats' RI, non-polar column, isothermal, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Zhang, Li, et al., 1992
Zhang, M.J.; Li, S.D.; Chen, B.J.,
Compositional studies of high-temperature coal tar by GC/FTIR analysis of light oil fractions,
Chromatographia, 1992, 33, 3/4, 138-146, https://doi.org/10.1007/BF02275894
. [all data]
Dimov and Mekenyan, 1989
Dimov, N.; Mekenyan, Ov.,
Quantitative Relationships Between the Structure of Alkylbenzenes and Their Gas Chromatographic Retention on Stationary Phasses with Different Polarity,
J. Chromatogr., 1989, 471, 227-236, https://doi.org/10.1016/S0021-9673(00)94170-0
. [all data]
Engewald, Topalova, et al., 1987
Engewald, W.; Topalova, I.; Petsev, N.; Dimitrov, Chr.,
Structure-Retention Correlations of Hydrocarbons in GLC and GSC. Alkenylbenzenes,
Chromatographia, 1987, 23, 8, 561-565, https://doi.org/10.1007/BF02324864
. [all data]
Boneva, Papazova, et al., 1983
Boneva, St.; Papazova, D.; Dimov, N.,
Retention Indices of aromatic hydrocarbons on glass and metal capillary columns with stationary phase OV-101,
Jahrb. Chem. Tech. Hochschule Burgas, 1983, 18, 143-148. [all data]
Lubeck and Sutton, 1983
Lubeck, A.J.; Sutton, DL.,
Kovats retention indices of selected hydrocarbons through C10 on bonded phase fused silica capillaries,
J. Hi. Res. Chromatogr. Chromatogr. Comm., 1983, 6, 6, 328-332, https://doi.org/10.1002/jhrc.1240060612
. [all data]
Tóth, 1983
Tóth, T.,
Use of capillary gas chromatography in collecting retention and chemical information for the analysis of complex petrochemical mixtures,
J. Chromatogr., 1983, 279, 157-165, https://doi.org/10.1016/S0021-9673(01)93614-3
. [all data]
Macák, Nabivach, et al., 1982
Macák, J.; Nabivach, V.; Buryan, P.; Sindler, S.,
Dependence of retention indices of alkylbenzenes on their molecular structure,
J. Chromatogr., 1982, 234, 2, 285-302, https://doi.org/10.1016/S0021-9673(00)81867-1
. [all data]
Nabivach and Kirilenko, 1980
Nabivach, V.M.; Kirilenko, A.V.,
Relationship between the gas chromatographic behaviour and the molecular structure of hydrocarbon samples and various stationary phases. Part II. Correlation between the retention index, physicochemical properties and molecular structure,
Chromatographia, 1980, 13, 2, 93-100, https://doi.org/10.1007/BF02263060
. [all data]
Nabivach and Kirilenko, 1979
Nabivach, V.M.; Kirilenko, A.V.,
The use of retention indices for identifying the components of crude benzene,
Solid Fuel Chem. (Engl. Transl.), 1979, 13, 3, 82-87. [all data]
Nabivach, Bur'yan, et al., 1978
Nabivach, V.M.; Bur'yan, P.; Matsak, I.,
Retention indices of aromatic hydrocarbons on a squalane capillary column,
Zh. Anal. Khim., 1978, 33, 7, 1108-1113. [all data]
Engewald and Wennrich, 1976
Engewald, W.; Wennrich, L.,
Molekülstruktur und Retentionsverhalten. VIII. Zum Retentionsverhalten höherer Alkylbenzole bei der Gas-Verteilungs-Chromatographie,
Chromatographia, 1976, 9, 11, 540-547, https://doi.org/10.1007/BF02275960
. [all data]
Lulova, Leont'eva, et al., 1976
Lulova, N.I.; Leont'eva, S.A.; Timofeeva, A.N.,
Gas-chromatographic method of determination of individual hydrocarbons in catalytic cracking gasolines
in Proceedings of All-Union Research Institute on Oil Processes. Vol.18, All-Union Research Institute on Oil Processes, Moscow, 1976, 30-53. [all data]
Soják and Rijks, 1976
Soják, L.; Rijks, J.A.,
Capillary gas chromatography of alkylbenzenes. I. Some problems encountered with the precision of the retention indcies of alkylbenzenes,
J. Chromatogr., 1976, 119, 505-521, https://doi.org/10.1016/S0021-9673(00)86812-0
. [all data]
Svob, Deur-Siftar, et al., 1974
Svob, V.; Deur-Siftar, D.; Cramers, C.A.,
Mechanisms of the thermal degradation of alkylbenzenes,
J. Chromatogr., 1974, 91, 659-675, https://doi.org/10.1016/S0021-9673(01)97946-4
. [all data]
Svob and Deur-Siftar, 1974
Svob, V.; Deur-Siftar, D.,
Kovats Retention Indices in the Identification of Alkylbenzene Degradation Products,
J. Chromatogr., 1974, 91, 677-689, https://doi.org/10.1016/S0021-9673(01)97947-6
. [all data]
Bonastre and Grenier, 1967
Bonastre, J.; Grenier, P.,
Contribution à l'étude de la polarité des phases stationnaires en chromatographie gas-liquide. I. Calcul des coefficients d'activité relatifs et des indices de rétention de quelques hydrocarbures aromatiques,
Bull. Soc. Chim. Fr., 1967, 4, 1395-1405. [all data]
Antheaume and Guiochon, 1965
Antheaume, J.; Guiochon, G.,
Application de la chromatographie en phase gazeuse à l'étude de la composition des fractions moyennes d'un brut pétrolier,
Bull. Soc. Chim. Fr., 1965, 2, 298-307. [all data]
Notes
Go To: Top, Kovats' RI, non-polar column, isothermal, References
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