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Benzene, (2-methylpropyl)-

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Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase PONAPONADB-1DB-5HP-5
Column length (m) 50.50.30.30.30.
Carrier gas   HeHeHe
Substrate      
Column diameter (mm) 0.20.20.250.250.25
Phase thickness (mum) 0.50.50.251.0.25
Tstart (C) 50.50.40.50.40.
Tend (C)   325.200.180.
Heat rate (K/min) 2.5.3.2.53.
Initial hold (min)      
Final hold (min)      
I 997.1001.989.51014.91009.
ReferenceVendeuvre, Bertoncini, et al., 2005Vendeuvre, Bertoncini, et al., 2005Sun and Stremple, 2003Xu, van Stee, et al., 2003Isidorov, Krajewska, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101CP Sil 8 CBPONAPONAPetrocol DH
Column length (m) 80.25.50.50.100.
Carrier gas N2   He
Substrate      
Column diameter (mm) 0.220.20.20.20.25
Phase thickness (mum)  0.250.50.50.5
Tstart (C) 30.40.35.35.30.
Tend (C) 130.200.220.220.220.
Heat rate (K/min) 1.2.1.1.1.
Initial hold (min)  8.0.50.5 
Final hold (min)   8.8. 
I 997.2998.991.3992.7994.39
ReferenceYin, Liu, et al., 2001Yassaa, Meklati, et al., 1999Martos, Saraullo, et al., 1997Martos, Saraullo, et al., 1997White, Douglas, et al., 1992
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Petrocol DHPetrocol DHUltra-1Ultra-1Ultra-1
Column length (m) 100.100.50.50.50.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.220.220.22
Phase thickness (mum) 0.50.50.330.330.33
Tstart (C) 30.30.-30.-30.-30.
Tend (C) 220.220.240.240.240.
Heat rate (K/min) 1.1.1.2.3.
Initial hold (min)      
Final hold (min)      
I 994.48994.988.86992.41994.66
ReferenceWhite, Douglas, et al., 1992White, Hackett, et al., 1992Haynes and Pitzer, 1985Haynes and Pitzer, 1985Haynes and Pitzer, 1985
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillary
Active phase Ultra-2Ultra-2Ultra-2OV-101
Column length (m) 50.50.50.108.
Carrier gas HeHeHe 
Substrate     
Column diameter (mm) 0.220.220.220.25
Phase thickness (mum) 0.330.330.330.2
Tstart (C) -30.-30.-30.35.
Tend (C) 240.240.240.200.
Heat rate (K/min) 1.2.3.1.
Initial hold (min)     
Final hold (min)     
I 1004.031007.861010.66992.
ReferenceHaynes and Pitzer, 1985Haynes and Pitzer, 1985Haynes and Pitzer, 1985Hayes and Pitzer, 1981
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Vendeuvre, Bertoncini, et al., 2005
Vendeuvre, C.; Bertoncini, F.; Thiébaut, D.; Martin, M.; Hennion, M.-C., Evluation of a retention model in comprehensive two-dimensional gas chromatography, J. Sep. Sci., 2005, 28, 11, 1129-1136, https://doi.org/10.1002/jssc.200401933 . [all data]

Sun and Stremple, 2003
Sun, G.; Stremple, P., Retention index characterization of flavor, fragrance, and many other compounds on DB-1 and DB-XLB, 2003, retrieved from http://www.chem.agilent.com/cag/cabu/pdf/b-0279.pdf. [all data]

Xu, van Stee, et al., 2003
Xu, X.; van Stee, L.L.P.; Williams, J.; Beens, J.; Adahchour, M.; Vreuls, R.J.J.; Brinkman, U.A.Th.; Lelieveld, J., Comprehensive two-dimensional gas chromatography (GC×GC) measurements of volatile organic compounds in the atmosphere, Atmos. Chem. Phys., 2003, 3, 3, 665-682, https://doi.org/10.5194/acp-3-665-2003 . [all data]

Isidorov, Krajewska, et al., 2001
Isidorov, V.A.; Krajewska, U.; Dubis, E.N.; Jdanova, M.A., Partition coefficients of alkyl aromatic hydrocarbons and esters in a hexane-acetonitrile system, J. Chromatogr. A, 2001, 923, 1-2, 127-136, https://doi.org/10.1016/S0021-9673(01)00929-3 . [all data]

Yin, Liu, et al., 2001
Yin, C.; Liu, W.; Li, Z.; Pan, Z.; Lin, T.; Zhang, M., Chemometrics to chemical modeling: structural coding in hydrocarbons and retention indices of gas chromatography, J. Sep. Sci., 2001, 24, 3, 213-220, https://doi.org/10.1002/1615-9314(20010301)24:3<213::AID-JSSC213>3.0.CO;2-4 . [all data]

Yassaa, Meklati, et al., 1999
Yassaa, N.; Meklati, B.Y.; Cecinato, A., Analysis of volatile organic compounds in the ambient air of Algiers by gas chromatography with a «beta»-cyclodextrin capillary column, J. Chromatogr. A, 1999, 846, 1-2, 287-293, https://doi.org/10.1016/S0021-9673(99)00327-1 . [all data]

Martos, Saraullo, et al., 1997
Martos, P.A.; Saraullo, A.; Pawliszyn, J., Estimation of air/coating distribution coefficients for solid phase microextraction using retention indexes from linear temperature-programmed capillary gas chromatography. Application to the sampling and analysis of total petroleum hydrocarbons in air, Anal. Chem., 1997, 69, 3, 402-408, https://doi.org/10.1021/ac960633p . [all data]

White, Douglas, et al., 1992
White, C.M.; Douglas, L.J.; Hackett, J.P.; Anderson, R.R., Characterization of synthetic gasoline from the chloromethane-zeolite reaction, Energy Fuels, 1992, 6, 1, 76-82, https://doi.org/10.1021/ef00031a012 . [all data]

White, Hackett, et al., 1992
White, C.M.; Hackett, J.; Anderson, R.R.; Kail, S.; Spock, P.S., Linear temperature programmed retention indices of gasoline range hydrocarbons and chlorinated hydrocarbons on cross-linked polydimethylsiloxane, J. Hi. Res. Chromatogr., 1992, 15, 2, 105-120, https://doi.org/10.1002/jhrc.1240150211 . [all data]

Haynes and Pitzer, 1985
Haynes, P.C., Jr.; Pitzer, E.W., Disengaging solutes in shale- and petroleum-derived jet fuels by altering GC programmed temperature rates, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1985, 8, 5, 230-242, https://doi.org/10.1002/jhrc.1240080504 . [all data]

Hayes and Pitzer, 1981
Hayes, P.C., Jr.; Pitzer, E.W., Kovats indices as a tool in characterizing hydrocarbon fuels in temperature programmed glass capillary gas chromatography. Part 1. Qualitative identification, Inhouse rpt. for Air Force Wright Aeronautical Labs., Air Force Wright Aeronautical Labs., Wright-Patterson AFB, Ohio, 1981, 75. [all data]


Notes

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References