Sulfur chloride cation

Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
S°gas,1 bar287.28J/mol*KReviewChase, 1998Data last reviewed in June, 1978

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   F
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 51230 ± 1100 gas Solouki, Rosmus, et al., 1974
Colton and Rabalais, 1974

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 42760 ± 400 gas Solouki, Rosmus, et al., 1974
Colton and Rabalais, 1974

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 37110 ± 400 gas Solouki, Rosmus, et al., 1974
Colton and Rabalais, 1974

State:   B,C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 24290 ± 400 gas Solouki, Rosmus, et al., 1974
Colton and Rabalais, 1974

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 22510 ± 400 gas Solouki, Rosmus, et al., 1974
Colton and Rabalais, 1974

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 SCl s-stretch 530 ± 40 gas PE Solouki, Rosmus, et al., 1974
Colton and Rabalais, 1974

Additional references: Jacox, 1994, page 112; Kaufel, Vahl, et al., 1981

Notes

xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Solouki, Rosmus, et al., 1974
Solouki, B.; Rosmus, P.; Bock, H., Photoelectron spectra and molecular properties. SCl2-ionization potentials and ab initio SCF calculations, Chem. Phys. Lett., 1974, 26, 20. [all data]

Colton and Rabalais, 1974
Colton, R.J.; Rabalais, J.W., Photoelectron electronic absorption spectra of SCl2, S2Cl2, S2Br2 and (CH3)2S2, J. Electron Spectrosc. Relat. Phenom., 1974, 3, 345. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Kaufel, Vahl, et al., 1981
Kaufel, R.; Vahl, G.; Minkwitz, R.; Baumgartel, H., Die photoionenspektren von SCl2, S2Cl2 und S2Br2, Z. Anorg. Allg. Chem., 1981, 481, 207. [all data]

Notes

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