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Furan, 2-methyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil337. ± 1.KAVGN/AAverage of 10 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple181.9KN/ACarlson and Westrum, 1965Uncertainty assigned by TRC = 0.1 K; TRC
Ttriple181.90KN/ACarlson, 1962Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Tc528.KN/AKobe, Ravicz, et al., 1956Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Pc47.20barN/AKobe, Ravicz, et al., 1956Uncertainty assigned by TRC = 1.034 bar; TRC
Quantity Value Units Method Reference Comment
Vc0.247l/molN/AKobe, Ravicz, et al., 1956Uncertainty assigned by TRC = 0.005 l/mol; TRC
Quantity Value Units Method Reference Comment
Deltavap32.2kJ/molN/AMoiseev and Antonova, 1970Based on data from 215. - 360. K.; AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
32.4304.N/ALoras, Aucejo, et al., 2002Based on data from 289. - 337. K.; AC
34.4266.AStephenson and Malanowski, 1987Based on data from 251. - 338. K.; AC
31.5324.N/AKrevor and Prausnitz, 1986Based on data from 309. - 339. K.; AC
32.5295.N/ADykyj, 1972Based on data from 288. - 303. K.; AC
30.9348.N/AEon, Pommier, et al., 1971Based on data from 333. - 373. K. See also Boublik, Fried, et al., 1984.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
333.4 - 373.54.815281643.0823.234Eon, Pommier, et al., 1971Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
8.552181.90Carlson and Westrum, 1965, 2DH
8.55181.9Carlson and Westrum, 1965, 2AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
47.01181.90Carlson and Westrum, 1965, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Carlson and Westrum, 1965
Carlson, H.G.; Westrum, E.F., Jr., 2-Methylfuran-Heat Capacity and Thermodynamic Properties from 5°to 310° K., J. Chem. Eng. Data, 1965, 10, 2, 134, https://doi.org/10.1021/je60025a018 . [all data]

Carlson, 1962
Carlson, , Ph.D. Thesis, Univ. Mich., Ann Arbor, MI, 1962. [all data]

Kobe, Ravicz, et al., 1956
Kobe, K.A.; Ravicz, A.E.; Vohra, S.P., Critical Properties and Vapor Pressures of Some Ethers and Heterocyclic Compounds, J. Chem. Eng. Data, 1956, 1, 50. [all data]

Moiseev and Antonova, 1970
Moiseev, V.D.; Antonova, N.D., Zh. Fiz. Khim., 1970, 44, 11, 2912. [all data]

Loras, Aucejo, et al., 2002
Loras, Sonia; Aucejo, Antonio; Montón, Juan B.; Wisniak, Jaime; Segura, Hugo, Phase Equilibria for 1,1,1,2,3,4,4,5,5,5-Decafluoropentane + 2-Methylfuran, 2-Methylfuran + Oxolane, and 1,1,1,2,3,4,4,5,5,5- Decafluoropentane + 2-Methylfuran + Oxolane at 35 kPa, J. Chem. Eng. Data, 2002, 47, 5, 1256-1262, https://doi.org/10.1021/je0255325 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Krevor and Prausnitz, 1986
Krevor, David H.; Prausnitz, John M., Vapor-liquid equilibria for model mixtures of coal-derived liquids. 1. Binary systems with 2-methylfuran, J. Chem. Eng. Data, 1986, 31, 3, 349-353, https://doi.org/10.1021/je00045a027 . [all data]

Dykyj, 1972
Dykyj, J., Petrochemia, 1972, 12, 1, 13. [all data]

Eon, Pommier, et al., 1971
Eon, C.; Pommier, C.; Guiochon, G., Vapor pressures and second virial coefficients of some five-membered heterocyclic derivatives, J. Chem. Eng. Data, 1971, 16, 4, 408-410, https://doi.org/10.1021/je60051a008 . [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

Carlson and Westrum, 1965, 2
Carlson, H.G.; Westrum, E.F., Jr., 2-Methylfuran. Heat capacity and thermodynamic properties from 5 to 310 K, J. Chem. Eng. Data, 1965, 10, 134-135. [all data]


Notes

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