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meso-2,3-Butanediol

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil456.7KN/AAldrich Chemical Company Inc., 1990BS
Tboil457.KN/AOthmer, Shlechter, et al., 1945Uncertainty assigned by TRC = 4. K; TRC
Quantity Value Units Method Reference Comment
Tfus306.65KN/AFishbein, 1957Uncertainty assigned by TRC = 1.5 K; TRC
Tfus308.15KN/AKnowlton, Schieltz, et al., 1946Uncertainty assigned by TRC = 4. K; approximate, read from a graph; TRC
Tfus307.65KN/ALucas and Gould, 1941Uncertainty assigned by TRC = 0.2 K; TRC
Tfus307.55KN/AWilson and Lucas, 1936Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Deltavap15.9 ± 0.1kcal/molCErmelinda Eusébio, Lopes Jesus, et al., 2003AC

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Reference Comment
13.0433.Knowlton, Schieltz, et al., 1946, 2Based on data from 413. - 453. K.; AC

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Reference Comment
2.58306.6Ermelinda Eusébio, Lopes Jesus, et al., 2003AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Othmer, Shlechter, et al., 1945
Othmer, D.F.; Shlechter, N.; Koszalka, W.A., Composition of vapours from boiling binary solutions - systems used in butadiene manufacture from butylene glycol., Ind. Eng. Chem., 1945, 37, 895. [all data]

Fishbein, 1957
Fishbein, L., The Reaction of dl- and meso-2,3-dibromobutane with Silver nitrate in Acetonitrile. Failure of the Nitrate Ester Grouping to Exhibit the Neighboring Group Effect, J. Am. Chem. Soc., 1957, 79, 2959. [all data]

Knowlton, Schieltz, et al., 1946
Knowlton, J.W.; Schieltz, N.C.; Macmillan, D., Physical Chemistry of the 2,3-Butanediols, J. Am. Chem. Soc., 1946, 68, 208-10. [all data]

Lucas and Gould, 1941
Lucas, H.J.; Gould, C.W., The Conversion of 3-CHloro-2-butanols to the 2,3-Dichlorobutanes; Evidence for a Cyclic Chloronium Intermediate, J. Am. Chem. Soc., 1941, 63, 2541-2551. [all data]

Wilson and Lucas, 1936
Wilson, C.E.; Lucas, H.J., Stereochemical Relationships of the Isomeric 2,3-Butanediols and Related Compounds; Evidence of Walden Inversion, J. Am. Chem. Soc., 1936, 58, 2396. [all data]

Ermelinda Eusébio, Lopes Jesus, et al., 2003
Ermelinda Eusébio, M.; Lopes Jesus, A.J.; Cruz, Mafalda S.C.; Leitão, M. Luisa P.; Simões Redinha, J., Enthalpy of vaporisation of butanediol isomers, The Journal of Chemical Thermodynamics, 2003, 35, 1, 123-129, https://doi.org/10.1016/S0021-9614(02)00306-3 . [all data]

Knowlton, Schieltz, et al., 1946, 2
Knowlton, J.W.; Schieltz, N.C.; Macmillan, D., Physical chemical properties of the 2,3-butanediols, J. Am. Chem. Soc., 1946, 68, 208-210. [all data]


Notes

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