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Benzene, 1,2-dinitro-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tfus387.7KN/AHwang, Tamura, et al., 1990Uncertainty assigned by TRC = 0.1 K; TRC
Tfus390.05KN/ABooss and Hauschildt, 1972Uncertainty assigned by TRC = 0.2 K; TRC
Tfus390.KN/AWhite, Biggs, et al., 1940Uncertainty assigned by TRC = 2. K; TRC
Tfus390.1KN/AAndrews, Lynn, et al., 1926Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Deltasub95.5 ± 0.9kJ/molGSVerevkin, 1997Based on data from 323. - 353. K.; AC
Deltasub87.9 ± 2.1kJ/molTEFerro, Piacente, et al., 1976Based on data from 343. - 397. K.; AC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
592.21.03Aldrich Chemical Company Inc., 1990BS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
60.0469.AStephenson and Malanowski, 1987Based on data from 454. - 593. K. See also Dykyj, 1972.; AC

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
93.1 ± 0.9338.GSVerevkin, 1997Based on data from 323. - 353. K.; AC
82.9358.N/AStephenson and Malanowski, 1987Based on data from 343. - 387. K.; AC
87. ± 1.333.VWolf and Weghofer, 1938ALS
86.6 ± 1.2309.N/ATrieschmann, 1935Based on data from 328. - 338. K. See also Wolf and Weghofer, 1938, 2 and Jones, 1960.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
22.84396.1Domalski and Hearing, 1996AC
22.750390.05Booss and Hauschildt, 1972DH
22.840396.1Andrews, Lynn, et al., 1926, 2DH

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
58.3390.05Booss and Hauschildt, 1972DH
58.6396.1Andrews, Lynn, et al., 1926, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hwang, Tamura, et al., 1990
Hwang, D.-R.; Tamura, M.; Yoshida, T.; Tanaka, N.; Hosoya, F., Estimation of «DELTA»H°f of nitro derivatives of benzene and toluene using AM1 and DSC, J. Energ. Mater., 1990, 8, 85-98. [all data]

Booss and Hauschildt, 1972
Booss, H.J.; Hauschildt, K.R., Die Schmelzenthalpie des Benzils und 4-Nitrophenols, Z. Anal. Chem., 1972, 261(1), 32. [all data]

White, Biggs, et al., 1940
White, A.H.; Biggs, B.S.; Morgan, S.O., Dielectric Evidence for Molecular Rotation in the Crystals of Certain Benzene Derivatives, J. Am. Chem. Soc., 1940, 62, 16-25. [all data]

Andrews, Lynn, et al., 1926
Andrews, D.H.; Lynn, G.; Johnston, J., The Heat Capacities and Heat of Crystallization of Some Isomeric Aromatic Compounds, J. Am. Chem. Soc., 1926, 48, 1274. [all data]

Verevkin, 1997
Verevkin, Sergey P., Thermochemistry of nitro compounds. Experimental standard enthalpies of formation and improved group-additivity values, Thermochimica Acta, 1997, 307, 1, 17-25, https://doi.org/10.1016/S0040-6031(97)00359-6 . [all data]

Ferro, Piacente, et al., 1976
Ferro, D.; Piacente, V.; Gigli, R.; D'Ascenzo, G., Determination of the vapour pressures of o-, m-, and p-dinitrobenzene by the torsion-effusion method, The Journal of Chemical Thermodynamics, 1976, 8, 12, 1137-1143, https://doi.org/10.1016/0021-9614(76)90120-8 . [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Dykyj, 1972
Dykyj, J., Petrochemia, 1972, 12, 1, 13. [all data]

Wolf and Weghofer, 1938
Wolf, K.L.; Weghofer, H., Uber sublimationswarmen, Z. Phys. Chem., 1938, 39, 194-208. [all data]

Trieschmann, 1935
Trieschmann, H.G., , Ph.D. Dissertation, Inst. Fur Phys. Chem. and Electrochem. der Universitat Kiel, Germany, 1935. [all data]

Wolf and Weghofer, 1938, 2
Wolf, K.L.; Weghofer, H.Z., Z. Phys. Chem. Abt. B, 1938, 39, 194. [all data]

Jones, 1960
Jones, A.H., Sublimation Pressure Data for Organic Compounds., J. Chem. Eng. Data, 1960, 5, 2, 196-200, https://doi.org/10.1021/je60006a019 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Andrews, Lynn, et al., 1926, 2
Andrews, D.H.; Lynn, G.; Johnston, J., The heat capacities and heat of crystallization of some isomeric aromatic compounds, J. Am. Chem. Soc., 1926, 48, 1274-1287. [all data]


Notes

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