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Kovats' RI, non-polar column, isothermal

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-1HP-1OV-101OV-101OV-101
Column length (m) 25.25.50.50.278.
Carrier gas N2N2 HeH2
Substrate      
Column diameter (mm) 0.200.200.250.200.25
Phase thickness (mum)      
Temperature (C) 100.100.100.100.100.
I 1029.1029.1031.1029.1028.
ReferenceZhang, Li, et al., 1992Zhang, Li, et al., 1992Dimov and Mekenyan, 1989Matisová, Kovacicová, et al., 1989Matisová, Rukríglová, et al., 1988
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101OV-101OV-101SqualaneSE-30
Column length (m) 278.278.278.50.15.
Carrier gas H2H2H2N2N2
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (mum)      
Temperature (C) 100.100.100.70.70.
I 1028.1029.1030.1011.1020.6
ReferenceMatisová, Rukríglová, et al., 1988Matisová, Rukríglová, et al., 1988Matisová, Rukríglová, et al., 1988Udarov, Manukov, et al., 1987Tóth, 1983
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101OV-101OV-101SqualaneSqualane
Column length (m) 50.50.50.50.50.
Carrier gas N2N2N2N2N2
Substrate      
Column diameter (mm) 0.300.300.300.250.25
Phase thickness (mum)      
Temperature (C) 100.120.140.86.96.
I 1032.1028.1045.1013.51015.8
ReferenceGerasimenko and Nabivach, 1982Gerasimenko and Nabivach, 1982Gerasimenko and Nabivach, 1982Macák, Nabivach, et al., 1982Macák, Nabivach, et al., 1982
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101OV-101OV-101SE-30Squalane
Column length (m) 50.50.50. 45.7
Carrier gas N2N2N2  
Substrate      
Column diameter (mm) 0.30.30.3 0.25
Phase thickness (mum)      
Temperature (C) 100.120.140.65.80.
I 1032.31038.41044.91016.91010.4
ReferenceGerasimenko, Kirilenko, et al., 1981Gerasimenko, Kirilenko, et al., 1981Gerasimenko, Kirilenko, et al., 1981Kuchhal, Kumar, et al., 1980Kuchhal, Kumar, et al., 1980
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryPackedCapillary
Active phase SqualaneSqualaneSqualaneSE-30Squalane
Column length (m) 50.50.100.6.150.
Carrier gas   H2N2H2
Substrate    Chrom W 
Column diameter (mm) 0.250.250.25 0.2
Phase thickness (mum)      
Temperature (C) 86.96.80.110.100.
I 1013.51015.81010.421033.1018.
ReferenceNabivach, Bur'yan, et al., 1978Nabivach, Bur'yan, et al., 1978Soják and Rijks, 1976Mitra, Mohan, et al., 1974Mitra, Mohan, et al., 1974, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillary
Active phase SE-30SqualaneSqualaneSqualane
Column length (m) 25.510.545.200.
Carrier gas HeHeN2N2
Substrate     
Column diameter (mm) 0.50.250.20.2
Phase thickness (mum)     
Temperature (C) 65.100.92.115.
I 1016.91016.41015.1024.7
ReferenceSvob and Deur-Siftar, 1974Svob and Deur-Siftar, 1974Krupcík, Liska, et al., 1970Krupcík, Liska, et al., 1970
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Kovats' RI, non-polar column, isothermal, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zhang, Li, et al., 1992
Zhang, M.J.; Li, S.D.; Chen, B.J., Compositional studies of high-temperature coal tar by GC/FTIR analysis of light oil fractions, Chromatographia, 1992, 33, 3/4, 138-146, https://doi.org/10.1007/BF02275894 . [all data]

Dimov and Mekenyan, 1989
Dimov, N.; Mekenyan, Ov., Quantitative Relationships Between the Structure of Alkylbenzenes and Their Gas Chromatographic Retention on Stationary Phasses with Different Polarity, J. Chromatogr., 1989, 471, 227-236, https://doi.org/10.1016/S0021-9673(00)94170-0 . [all data]

Matisová, Kovacicová, et al., 1989
Matisová, E.; Kovacicová, E.; Ha, P.T.; Kolek, E.; Engewald, W., Identification of alkylbenzenes up to C12 by capillary gas chromatography-mass spectrometry. II. Retention indices on OV-101 columns and retention-molecular structure correlations, J. Chromatogr., 1989, 475, 2, 113-123, https://doi.org/10.1016/S0021-9673(01)89667-9 . [all data]

Matisová, Rukríglová, et al., 1988
Matisová, E.; Rukríglová, M.; Krupcík, J.; Kovacicová, E.; Holotík, S., Identification of alkylbenzenes up to C12 by capillary gas chromatography and combined gas chromatography-mass spectrometry. I. OV-101 as stationary phase, J. Chromatogr., 1988, 455, 301-309, https://doi.org/10.1016/S0021-9673(01)82129-4 . [all data]

Udarov, Manukov, et al., 1987
Udarov, B.G.; Manukov, E.N.; Vyglazov, O.G.; Chuiko, V.A.; Izotova, L.V., Gas-chromatographic analysis of alkylated derivatives of carane and of cyclohelptane in capillary columns, Chem. Nat. Compd. (Engl. Transl.), 1987, 22, 4, 398-403, https://doi.org/10.1007/BF00579809 . [all data]

Tóth, 1983
Tóth, T., Use of capillary gas chromatography in collecting retention and chemical information for the analysis of complex petrochemical mixtures, J. Chromatogr., 1983, 279, 157-165, https://doi.org/10.1016/S0021-9673(01)93614-3 . [all data]

Gerasimenko and Nabivach, 1982
Gerasimenko, V.A.; Nabivach, V.M., Relationship between molecular structure and gas chromatographic retention of alkylbenzenes C8-C1 2 on polydimethylsiloxane, Zh. Anal. Khim., 1982, 37, 110-116. [all data]

Macák, Nabivach, et al., 1982
Macák, J.; Nabivach, V.; Buryan, P.; Sindler, S., Dependence of retention indices of alkylbenzenes on their molecular structure, J. Chromatogr., 1982, 234, 2, 285-302, https://doi.org/10.1016/S0021-9673(00)81867-1 . [all data]

Gerasimenko, Kirilenko, et al., 1981
Gerasimenko, V.A.; Kirilenko, A.V.; Nabivach, V.M., Capillary gas chromatography of aromatic compounds found in coal tar fractions, J. Chromatogr., 1981, 208, 1, 9-16, https://doi.org/10.1016/S0021-9673(00)87953-4 . [all data]

Kuchhal, Kumar, et al., 1980
Kuchhal, R.K.; Kumar, B.; Kumar, P.; Gupta, P.L., Determination of the isomeric distribution and associated impurities in commercial diethylbenzenes by capillary gas chromatography, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1980, 3, 10, 497-502, https://doi.org/10.1002/jhrc.1240031003 . [all data]

Nabivach, Bur'yan, et al., 1978
Nabivach, V.M.; Bur'yan, P.; Matsak, I., Retention indices of aromatic hydrocarbons on a squalane capillary column, Zh. Anal. Khim., 1978, 33, 7, 1108-1113. [all data]

Soják and Rijks, 1976
Soják, L.; Rijks, J.A., Capillary gas chromatography of alkylbenzenes. I. Some problems encountered with the precision of the retention indcies of alkylbenzenes, J. Chromatogr., 1976, 119, 505-521, https://doi.org/10.1016/S0021-9673(00)86812-0 . [all data]

Mitra, Mohan, et al., 1974
Mitra, G.D.; Mohan, G.; Sinha, A., Advances in the utilization of the retention index system for characterizing hydrocarbons in complex mixtures by gas chromatography, J. Chromatogr., 1974, 99, 215-230, https://doi.org/10.1016/S0021-9673(00)90857-4 . [all data]

Mitra, Mohan, et al., 1974, 2
Mitra, G.D.; Mohan, G.; Sinha, A., Gas chromatographic analysis of complex hydrocarbon mixtures, J. Chromatogr. A, 1974, 91, 633-648, https://doi.org/10.1016/S0021-9673(01)97944-0 . [all data]

Svob and Deur-Siftar, 1974
Svob, V.; Deur-Siftar, D., Kovats Retention Indices in the Identification of Alkylbenzene Degradation Products, J. Chromatogr., 1974, 91, 677-689, https://doi.org/10.1016/S0021-9673(01)97947-6 . [all data]

Krupcík, Liska, et al., 1970
Krupcík, J.; Liska, O.; Soják, L., The applicability of the linear free energy relationships for the identification of some alkyl aromatic hydrocarbons by open tubular column gas chromatography, J. Chromatogr., 1970, 51, 119-127, https://doi.org/10.1016/S0021-9673(01)96846-3 . [all data]


Notes

Go To: Top, Kovats' RI, non-polar column, isothermal, References