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Benzene, 1,2,3,5-tetramethyl-

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Kovats' RI, non-polar column, isothermal

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5OV-1CP Sil 2HP-1
Column length (m) 60.60.50.100.25.
Carrier gas     N2
Substrate      
Column diameter (mm) 0.250.250.250.250.20
Phase thickness (mum) 0.250.25 0.25 
Temperature (C) 100.120.100.80.60.
I 1129.01137.01113.51121.31096.
ReferencePérez-Parajón, Santiuste, et al., 2004Pérez-Parajón, Santiuste, et al., 2004Zhu, Zhang, et al., 1999Estel, Mohnke, et al., 1995Zhang, Li, et al., 1992
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-1HP-1HP-1OV-101OV-101
Column length (m) 25.25.25.50.278.
Carrier gas N2N2N2HeH2
Substrate      
Column diameter (mm) 0.200.200.200.200.25
Phase thickness (mum)      
Temperature (C) 60.100.100.100.100.
I 1096.1109.1109.1109.1109.
ReferenceZhang, Li, et al., 1992Zhang, Li, et al., 1992Zhang, Li, et al., 1992Matisová, Kovacicová, et al., 1989Matisová, Rukríglová, et al., 1988
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101SE-30SE-30OV-101OV-101
Column length (m) 278.15.100.50.50.
Carrier gas H2N2 N2N2
Substrate      
Column diameter (mm) 0.250.250.50.300.30
Phase thickness (mum)      
Temperature (C) 100.70.80.100.120.
I 1110.1099.51104.1110.1118.
ReferenceMatisová, Rukríglová, et al., 1988Tóth, 1983Bredael, 1982Gerasimenko and Nabivach, 1982Gerasimenko and Nabivach, 1982
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101SqualaneSqualaneOV-101OV-101
Column length (m) 50.50.50.50.50.
Carrier gas N2N2N2N2N2
Substrate      
Column diameter (mm) 0.300.250.250.30.3
Phase thickness (mum)      
Temperature (C) 140.86.96.100.120.
I 1125.1108.41111.41110.51117.5
ReferenceGerasimenko and Nabivach, 1982Macák, Nabivach, et al., 1982Macák, Nabivach, et al., 1982Gerasimenko, Kirilenko, et al., 1981Gerasimenko, Kirilenko, et al., 1981
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryPackedCapillaryCapillaryCapillary
Active phase OV-101SqualaneSqualaneSqualaneSqualane
Column length (m) 50.1.50.50.100.
Carrier gas N2He  N2
Substrate  Chromaton N-AW-HMDS   
Column diameter (mm) 0.3 0.250.250.23
Phase thickness (mum)      
Temperature (C) 140.100.86.96.100.
I 1125.01108.1108.41111.41113.
ReferenceGerasimenko, Kirilenko, et al., 1981Nabivach and Kirilenko, 1980Nabivach, Bur'yan, et al., 1978Nabivach, Bur'yan, et al., 1978Engewald and Wennrich, 1976
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryPackedPackedPackedCapillary
Active phase SqualaneSE-30SE-30SE-30SE-30
Column length (m) 100.6.16.16.16.1
Carrier gas H2N2N2N2H2
Substrate  Chrom WChrom WChrom W 
Column diameter (mm) 0.25   3.18
Phase thickness (mum)      
Temperature (C) 80.120.130.140.130.
I 1105.051137.1140.1145.1139.
ReferenceSoják and Rijks, 1976Mitra, Mohan, et al., 1974Mitra, Mohan, et al., 1974Mitra, Mohan, et al., 1974Mitra, Mohan, et al., 1974, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryPacked
Active phase SE-30SE-30SE-30SE-30Apiezon L
Column length (m) 6.16.16.125.52.3
Carrier gas H2H2H2HeN2
Substrate     DCMS-treated Chromosorb W
Column diameter (mm) 3.183.183.180.5 
Phase thickness (mum)      
Temperature (C) 140.150.160.65.100.
I 1144.1149.1150.1097.71151.
ReferenceMitra, Mohan, et al., 1974, 2Mitra, Mohan, et al., 1974, 2Mitra, Mohan, et al., 1974, 2Svob and Deur-Siftar, 1974Brown, Chapman, et al., 1968
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type Packed
Active phase Methyl Silicone
Column length (m)  
Carrier gas  
Substrate  
Column diameter (mm)  
Phase thickness (mum)  
Temperature (C) 130.
I 1123.
ReferenceAntheaume and Guiochon, 1965
Comment MSDC-RI

References

Go To: Top, Kovats' RI, non-polar column, isothermal, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pérez-Parajón, Santiuste, et al., 2004
Pérez-Parajón, J.M.; Santiuste, J.M.; Takács, J.M., Sensitivity of the methylbenzenes and chlorobenzenes retention index to column temperature, stationary phase polarity, and number and chemical nature of substituents, J. Chromatogr. A, 2004, 1048, 2, 223-232, https://doi.org/10.1016/j.chroma.2004.07.028 . [all data]

Zhu, Zhang, et al., 1999
Zhu, X.; Zhang, L.; Chen, J.; Wang, L.; Che, X., The application quantitative structure-retention relationship of GC to aid MS qualitative analysis, Chin. J. Chromatogr., 1999, 17, 4, 351-353. [all data]

Estel, Mohnke, et al., 1995
Estel, D.; Mohnke; Biermans; Rotzsche, The analysis of C4-C11 hydrocarbons in naphtha and reformate with a new apolar fused silica column, J. Hi. Res. Chromatogr., 1995, 18, 7, 403-412, https://doi.org/10.1002/jhrc.1240180703 . [all data]

Zhang, Li, et al., 1992
Zhang, M.J.; Li, S.D.; Chen, B.J., Compositional studies of high-temperature coal tar by GC/FTIR analysis of light oil fractions, Chromatographia, 1992, 33, 3/4, 138-146, https://doi.org/10.1007/BF02275894 . [all data]

Matisová, Kovacicová, et al., 1989
Matisová, E.; Kovacicová, E.; Ha, P.T.; Kolek, E.; Engewald, W., Identification of alkylbenzenes up to C12 by capillary gas chromatography-mass spectrometry. II. Retention indices on OV-101 columns and retention-molecular structure correlations, J. Chromatogr., 1989, 475, 2, 113-123, https://doi.org/10.1016/S0021-9673(01)89667-9 . [all data]

Matisová, Rukríglová, et al., 1988
Matisová, E.; Rukríglová, M.; Krupcík, J.; Kovacicová, E.; Holotík, S., Identification of alkylbenzenes up to C12 by capillary gas chromatography and combined gas chromatography-mass spectrometry. I. OV-101 as stationary phase, J. Chromatogr., 1988, 455, 301-309, https://doi.org/10.1016/S0021-9673(01)82129-4 . [all data]

Tóth, 1983
Tóth, T., Use of capillary gas chromatography in collecting retention and chemical information for the analysis of complex petrochemical mixtures, J. Chromatogr., 1983, 279, 157-165, https://doi.org/10.1016/S0021-9673(01)93614-3 . [all data]

Bredael, 1982
Bredael, P., Retention indices of hydrocarbons on SE-30, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1982, 5, 6, 325-328, https://doi.org/10.1002/jhrc.1240050610 . [all data]

Gerasimenko and Nabivach, 1982
Gerasimenko, V.A.; Nabivach, V.M., Relationship between molecular structure and gas chromatographic retention of alkylbenzenes C8-C1 2 on polydimethylsiloxane, Zh. Anal. Khim., 1982, 37, 110-116. [all data]

Macák, Nabivach, et al., 1982
Macák, J.; Nabivach, V.; Buryan, P.; Sindler, S., Dependence of retention indices of alkylbenzenes on their molecular structure, J. Chromatogr., 1982, 234, 2, 285-302, https://doi.org/10.1016/S0021-9673(00)81867-1 . [all data]

Gerasimenko, Kirilenko, et al., 1981
Gerasimenko, V.A.; Kirilenko, A.V.; Nabivach, V.M., Capillary gas chromatography of aromatic compounds found in coal tar fractions, J. Chromatogr., 1981, 208, 1, 9-16, https://doi.org/10.1016/S0021-9673(00)87953-4 . [all data]

Nabivach and Kirilenko, 1980
Nabivach, V.M.; Kirilenko, A.V., Relationship between the gas chromatographic behaviour and the molecular structure of hydrocarbon samples and various stationary phases. Part II. Correlation between the retention index, physicochemical properties and molecular structure, Chromatographia, 1980, 13, 2, 93-100, https://doi.org/10.1007/BF02263060 . [all data]

Nabivach, Bur'yan, et al., 1978
Nabivach, V.M.; Bur'yan, P.; Matsak, I., Retention indices of aromatic hydrocarbons on a squalane capillary column, Zh. Anal. Khim., 1978, 33, 7, 1108-1113. [all data]

Engewald and Wennrich, 1976
Engewald, W.; Wennrich, L., Molekülstruktur und Retentionsverhalten. VIII. Zum Retentionsverhalten höherer Alkylbenzole bei der Gas-Verteilungs-Chromatographie, Chromatographia, 1976, 9, 11, 540-547, https://doi.org/10.1007/BF02275960 . [all data]

Soják and Rijks, 1976
Soják, L.; Rijks, J.A., Capillary gas chromatography of alkylbenzenes. I. Some problems encountered with the precision of the retention indcies of alkylbenzenes, J. Chromatogr., 1976, 119, 505-521, https://doi.org/10.1016/S0021-9673(00)86812-0 . [all data]

Mitra, Mohan, et al., 1974
Mitra, G.D.; Mohan, G.; Sinha, A., Advances in the utilization of the retention index system for characterizing hydrocarbons in complex mixtures by gas chromatography, J. Chromatogr., 1974, 99, 215-230, https://doi.org/10.1016/S0021-9673(00)90857-4 . [all data]

Mitra, Mohan, et al., 1974, 2
Mitra, G.D.; Mohan, G.; Sinha, A., Gas chromatographic analysis of complex hydrocarbon mixtures, J. Chromatogr. A, 1974, 91, 633-648, https://doi.org/10.1016/S0021-9673(01)97944-0 . [all data]

Svob and Deur-Siftar, 1974
Svob, V.; Deur-Siftar, D., Kovats Retention Indices in the Identification of Alkylbenzene Degradation Products, J. Chromatogr., 1974, 91, 677-689, https://doi.org/10.1016/S0021-9673(01)97947-6 . [all data]

Brown, Chapman, et al., 1968
Brown, I.; Chapman, I.L.; Nicholson, G.J., Gas chromatography of polar solutes in electron acceptor stationary phases, Aust. J. Chem., 1968, 21, 5, 1125-1141, https://doi.org/10.1071/CH9681125 . [all data]

Antheaume and Guiochon, 1965
Antheaume, J.; Guiochon, G., Application de la chromatographie en phase gazeuse à l'étude de la composition des fractions moyennes d'un brut pétrolier, Bull. Soc. Chim. Fr., 1965, 2, 298-307. [all data]


Notes

Go To: Top, Kovats' RI, non-polar column, isothermal, References