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trinitromethane

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafliquid-68.0 ± 3.1kJ/molCcrCarpenter, Zimmer, et al., 1970 
Deltafliquid-32.1kJ/molCcbCurrie, 1950 
Deltafliquid-77.95kJ/molCcbHolcomb and Dorsey, 1949 
Quantity Value Units Method Reference Comment
Deltacliquid-504.30kJ/molCcbCurrie, 1950 
Deltacliquid-458.48kJ/molCcbHolcomb and Dorsey, 1949 
Quantity Value Units Method Reference Comment
Deltafsolid-48. ± 2.kJ/molCcbMirishnichenko, Lebedev, et al., 1967Heat of combustion corrected for constant pressure
Quantity Value Units Method Reference Comment
Deltacsolid-488. ± 13.kJ/molCcbMirishnichenko, Lebedev, et al., 1967Heat of combustion corrected for constant pressure
Deltacsolid-520.9kJ/molCcbYoung, Keith, et al., 1956 

Phase change data

Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus292.KN/ALewis and Smyth, 1939Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Deltavap54.8kJ/molVCarpenter, Zimmer, et al., 1970ALS
Quantity Value Units Method Reference Comment
Deltasub45.2 ± 2.1kJ/molN/AMiroshnichenko and Vorob'eva, 1999AC
Deltasub46.0 ± 0.42kJ/molVMirishnichenko, Lebedev, et al., 1967Heat of combustion corrected for constant pressure; ALS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
32.6303.AStephenson and Malanowski, 1987Based on data from 290. - 317. K. See also Miroshnichenko, Lebedev, et al., 1967.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias and Joel F. Liebman

Ionization energy determinations

IE (eV) Method Reference Comment
12.23PEKoo, Chin, et al., 1990Vertical value

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Carpenter, Zimmer, et al., 1970
Carpenter, G.A.; Zimmer, M.F.; Baroody, E.E.; Robb, R.A., Enthalpy of formation of bromotrinitromethane, J. Chem. Eng. Data, 1970, 15, 553-556. [all data]

Currie, 1950
Currie, R.M., Heats of combustion of some nitroalcohols, Thesis for Purdue University, 1950, 1-84. [all data]

Holcomb and Dorsey, 1949
Holcomb, D.E.; Dorsey, C.L., Jr., Thermodynamic properties of nitroparaffins, Ind. Eng. Chem., 1949, 41, 2788-2792. [all data]

Mirishnichenko, Lebedev, et al., 1967
Mirishnichenko, E.A.; Lebedev, Yu.A.; Shevelev, S.A.; Gulevskaya, V.I.; Fainzil'berg, A.A.; Apin, A.Ya., Thermochemistry of trinitromethane, Zh. Fiz. Khim., 1967, 41, 1477-1479. [all data]

Young, Keith, et al., 1956
Young, J.A.; Keith, J.E.; Stehle, P.; Dzombak, W.C.; Hunt, H., Heats of combustion of some organic nitrogen compounds, Ind. Eng. Chem., 1956, 48, 1375-1378. [all data]

Lewis and Smyth, 1939
Lewis, G.L.; Smyth, C.P., The Dipole Moments and Structures of Ozone, Silicobromoform and Dichlorogermane, J. Am. Chem. Soc., 1939, 61, 3067-3070. [all data]

Miroshnichenko and Vorob'eva, 1999
Miroshnichenko, E.O.; Vorob'eva, V.P., Thermochemical characteristics of nitroalkanes, Zh. Fiz. Khim., 1999, 73, 3, 419. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Miroshnichenko, Lebedev, et al., 1967
Miroshnichenko, E.A.; Lebedev, Yu.A.; Shevelev, S.A.; Gulivskaya, V.I.; Fainzil'berg, A.A.; Apin, A.Ya., Zh. Fiz. Khim., 1967, 41, 6, 1477. [all data]

Koo, Chin, et al., 1990
Koo, L.K.; Chin, W.S.; Mok, C.Y.; Huang, H.H., A study of the pyrolysis of trinitro- and tetranitromethane by photoelectron spectroscopy, Bull. Singapore Natl. Inst. Chem., 1990, 18, 121. [all data]


Notes

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