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2,3-Butanediol

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil456.7KN/AAldrich Chemical Company Inc., 1990BS
Tboil455.65KN/AMellan, 1962Uncertainty assigned by TRC = 1. K; TRC
Tboil455.15KN/AWalpole, 1911Uncertainty assigned by TRC = 4. K; TRC
Tboil415.15KN/ASabatier and Mailhe, 1907Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Tfus292.15KN/AMellan, 1962Uncertainty assigned by TRC = 2. K; TRC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
62.5363.AStephenson and Malanowski, 1987Based on data from 348. - 457. K.; AC
58.4332.N/AStull, 1947Based on data from 317. - 455. K.; AC
57.9378.N/ASchierholtz and Staples, 1935Based on data from 353. - 403. K.; AC
55.7380.N/ASchierholtz and Staples, 1935Based on data from 303. - 456. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
317. - 455.6.074392616.746-24.565Stull, 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Mellan, 1962
Mellan, I., Polyhydric Alcohols, Spartan Books: Washington, DC, 1962. [all data]

Walpole, 1911
Walpole, G.S., Proc. R. Soc. London, B, 1911, 83, 272. [all data]

Sabatier and Mailhe, 1907
Sabatier, P.; Mailhe, A., The Direct Hydrogenation of Methyl Diketones, C. R. Hebd. Seances Acad. Sci., 1907, 144, 1086. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Schierholtz and Staples, 1935
Schierholtz, O.J.; Staples, M.L., Vapor Pressures of Certain Glycols, J. Am. Chem. Soc., 1935, 57, 12, 2709-2711, https://doi.org/10.1021/ja01315a106 . [all data]


Notes

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