CH3HgH


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 CH3 stretch 2921.2 w Ar IR Legay-Sommaire and Legay, 1994
Greene, Andrews, et al., 1995
2 HgH stretch 1954.9 vs Ar IR Legay-Sommaire and Legay, 1994
Greene, Andrews, et al., 1995
2 HgH stretch 1953.8 N2 IR Legay-Sommaire and Legay, 1996
3 CH3 deform. 1191.7 w Ar IR Legay-Sommaire and Legay, 1994
Greene, Andrews, et al., 1995
4 HgC stretch 534.0 w Ar IR Legay-Sommaire and Legay, 1994
Greene, Andrews, et al., 1995
4 HgC stretch 530.3 N2 IR Legay-Sommaire and Legay, 1996
e 5 CH3 stretch 2990.6 m T Ar IR Legay-Sommaire and Legay, 1994
6 CH3 deform. 1425.0 w Ar IR Legay-Sommaire and Legay, 1994
Greene, Andrews, et al., 1995
7 CH3 rock 779.8 m Ar IR Legay-Sommaire and Legay, 1994
Greene, Andrews, et al., 1995
7 CH3 rock 777.9 Ar IR Legay-Sommaire and Legay, 1994
Greene, Andrews, et al., 1995
7 CH3 rock 778.4 N2 IR Legay-Sommaire and Legay, 1996
7 CH3 rock 777.4 N2 IR Legay-Sommaire and Legay, 1996
7 CH3 rock 774.3 N2 IR Legay-Sommaire and Legay, 1996
8 HgH bend 526.5 Ar IR Legay-Sommaire and Legay, 1994
Greene, Andrews, et al., 1995
8 HgH bend 527.2 N2 IR Legay-Sommaire and Legay, 1996
8 HgH bend 525.2 N2 IR Legay-Sommaire and Legay, 1996

Additional references: Jacox, 1998, page 309; Jacox, 2003, page 309

Notes

wWeak
mMedium
vsVery strong
TTentative assignment or approximate value

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Legay-Sommaire and Legay, 1994
Legay-Sommaire, N.; Legay, F., Photochemical formation of CH3HgH in Hg/CH4/Ar matrices studied by FTIR spectroscopy, Chem. Phys. Lett., 1994, 217, 1-2, 97, https://doi.org/10.1016/0009-2614(93)E1367-P . [all data]

Greene, Andrews, et al., 1995
Greene, T.M.; Andrews, L.; Downs, A.J., The Reaction of Zinc, Cadmium, and Mercury Atoms with Methane: Infrared Spectra of the Matrix-Isolated Methylmetal Hydrides, J. Am. Chem. Soc., 1995, 117, 31, 8180, https://doi.org/10.1021/ja00136a015 . [all data]

Legay-Sommaire and Legay, 1996
Legay-Sommaire, N.; Legay, F., Isotope effects in the photochemical formation of HHgCH3 and DHgCD3 in nitrogen and methane matrices, Chem. Phys., 1996, 211, 1-3, 367, https://doi.org/10.1016/0301-0104(96)00190-5 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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