Tricyclo[2.2.1.0(2,6)]heptane, 1,7,7-trimethyl-


Normal alkane RI, polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-InnowaxBP-20Supelcowax-10RTX-WaxHP-Innowax
Column length (m) 60. 30.60.30.
Carrier gas HeliumNitrogenHeliumHeliumNitrogen
Substrate      
Column diameter (mm) 0.25 0.200.220.25
Phase thickness (μm) 0.25 0.200.250.52
Tstart (C) 60.60.70.60.35.
Tend (C) 220.200.220.230.205.
Heat rate (K/min) 5.5.3.2.3.
Initial hold (min) 1.   10.
Final hold (min) 5. 15.30.10.
I 1018.1011.1016.1005.1014.
ReferenceFeng, Cui, et al., 2011Mishra, Chaudhary, et al., 2010Neves, Rosa, et al., 2010Museli, Pau, et al., 2009Wannes, Mhamdi, et al., 2009
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-InnowaxTC-FFAPTC-FFAPSupelcowax-10Supelcowax-10
Column length (m) 30.  30.30.
Carrier gas N2HeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.20.25
Phase thickness (μm) 0.250.250.250.20.25
Tstart (C) 50.60.60.70.50.
Tend (C) 240.220.220.220.250.
Heat rate (K/min) 5.3.3.3.2.
Initial hold (min) 1.    
Final hold (min) 4.30.30.15. 
I 1015.1021.1019.1030.1020.
ReferenceCheraif, Ben Jannet, et al., 2007Kurose, Okamura, et al., 2007Kurose, Okamura, et al., 2007Pinto, Salgueiro, et al., 2007Raal, Orav, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax-10Supelcowax 10HP-WaxHP-20MDB-Innowax
Column length (m) 30.30.30.30.60.
Carrier gas HeHeliumNitrogenN2Helium
Substrate      
Column diameter (mm) 0.250.200.250.250.25
Phase thickness (μm) 0.250.200.250.250.25
Tstart (C) 40.70.50.50.60.
Tend (C) 250.220.280.250.240.
Heat rate (K/min) 3.3.5.5.3.
Initial hold (min) 5.    
Final hold (min) 10.15.5.10.20.
I 1001.1030.1014.1014.1009.
ReferenceVichi, Riu-Aumatell, et al., 2007Cavaleiro, Pinto, et al., 2006Marzouk, Mansour, et al., 2006Marzouk, Neffati, et al., 2006Mendivil, Rodrigues, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase NB-20MSupelcowax-10StabilwaxSupelcowax-10NB-20M
Column length (m) 30.30.30.30.50.
Carrier gas HeHeH2 He
Substrate      
Column diameter (mm) 0.20.250.320.250.2
Phase thickness (μm) 0.250.250.50.250.25
Tstart (C) 50.50.40.40.50.
Tend (C) 250.250.280.210.250.
Heat rate (K/min) 2.4.6.2.2.
Initial hold (min)  1.5.2. 
Final hold (min)  10.5.33. 
I 1010.1002.1008.995.1017.
ReferenceOrav, Raal, et al., 2006Wong, Sivasothy, et al., 2006Jirovetz, Buchbauer, et al., 2005Stevanovic, Garneau, et al., 2005Raal, Arak, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-WaxCP-Wax 52CBBP-20DB-WaxDB-Wax
Column length (m) 50.50.25.60.60.
Carrier gas N2HeNitrogenHeHe
Substrate      
Column diameter (mm) 0.250.300.500.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 75.40.60.40.60.
Tend (C) 220.220.200.200.240.
Heat rate (K/min) 3.3.5.2.4.
Initial hold (min) 4.5. 2. 
Final hold (min)      
I 1029.1005.1003.1009.1013.
ReferencePriestap, van Baren, et al., 2002Chagonda, Makanda, et al., 2000Mallavarapu, Rao, et al., 2000Umano, Hagi, et al., 2000Ngassoum, Yonkeu, et al., 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-InnowaxPEG-20MPEG-20MSupelcowax-10Supelcowax-10
Column length (m) 60.50.60.  
Carrier gas HeHeHe  
Substrate      
Column diameter (mm) 0.250.250.32  
Phase thickness (μm) 0.25 0.25  
Tstart (C) 50.70.70.40.40.
Tend (C) 220.250.180.210.210.
Heat rate (K/min) 5.2.2.2.2.
Initial hold (min) 5. 7.2.2.
Final hold (min)    120.120.
I 1015.1017.1020.1004.1004.
ReferenceStashenko, Cervantes, et al., 1998Orav, Kailas, et al., 1996Orav, Kuningas, et al., 1995Collin, Deslauriers, et al., 1993Collin, Deslauriers, et al., 1993
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type Capillary
Active phase Carbowax 20M
Column length (m) 45.
Carrier gas Hydrogen
Substrate  
Column diameter (mm) 0.32
Phase thickness (μm) 1.0
Tstart (C) 60.
Tend (C) 200.
Heat rate (K/min) 2.
Initial hold (min) 5.
Final hold (min)  
I 1020.
ReferenceKollmannsberger, Nitz, et al., 1992
Comment MSDC-RI

References

Go To: Top, Normal alkane RI, polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Feng, Cui, et al., 2011
Feng, T.; Cui, J.-J.; Xiao, Z.-B.; Tian, H.-X.; Yi, F.-P.; Ma, X., Chemical composition od essential oil from the peel of Chinese Torreya grandis Frt, Org. Chem. International, 2011, 2011, 1-5, https://doi.org/10.1155/2011/187372 . [all data]

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Wannes, Mhamdi, et al., 2009
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Cheraif, Ben Jannet, et al., 2007
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Kurose, Okamura, et al., 2007
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Pinto, Salgueiro, et al., 2007
Pinto, E.; Salgueiro, L.R.; Cavaleiro, C.; Palmeira, A.; Goncalves, M.J., In vitro susceptibility of some species of yeasts and filamentous fungi to essential oils of Salvia of?cinalis, Ind. Crops Prod., 2007, 26, 2, 135-141, https://doi.org/10.1016/j.indcrop.2007.02.004 . [all data]

Raal, Orav, et al., 2007
Raal, A.; Orav, A.; Arak, E.; Kailas, T.; Müürisepp, M., Variation in the composition of the essential oil of Valeriana officinalis L. roots from Estonia, Proc. Est. Acad. Sci. Chem., 2007, 56, 2, 67-74. [all data]

Vichi, Riu-Aumatell, et al., 2007
Vichi, S.; Riu-Aumatell, M.; Mora-Pons, M.; Guadayol, J.M.; Buxaderas, S.; López-Tamames, E., Analytical, Nutritional and Clinical Methods. HS-SPME coupled to GC/MS for quality control of Juniperus communis L. berries used for gin aromatization, Food Chem., 2007, 105, 4, 1748-1754, https://doi.org/10.1016/j.foodchem.2007.03.026 . [all data]

Cavaleiro, Pinto, et al., 2006
Cavaleiro, C.; Pinto, E.; Gonsales, M.J.; Salguero, L., Antifungal activity of Juniperus essential oils agains dermatophyte, Asrgillus and Candida strains, J. Appl. Microbiol., 2006, 100, 6, 1333-1338, https://doi.org/10.1111/j.1365-2672.2006.02862.x . [all data]

Marzouk, Mansour, et al., 2006
Marzouk, Z.; Mansour, H.B.; Chraief, I.; Mosrati, R.; Cheriaa, J.; Neffati, A.; Marzouk, B.; Sfari, M.; Boukef, K.; Barillies, D.; Ghedira, L.C., Chemical composition, antibacterial and antimutagenic activities of four populations of Rosmarinus officinalis L. oils from Tunisia, J. Food Agriculture Environment, 2006, 4, 2, 89-94. [all data]

Marzouk, Neffati, et al., 2006
Marzouk, Z.; Neffati, A.; Marzouk, B.; Chraief, I.; Fathia, K.; Ghedira, L.C.; Boukef, K., Chemical composition and antibacterial and antimutagenic activity of Tunisian Rosmarinus officinalis L. oil from Kasrine, Journal of Food, Agriculture Environment, 2006, 4, 34, 61-65. [all data]

Mendivil, Rodrigues, et al., 2006
Mendivil, E.A.S.; Rodrigues, J.F.; Espinosa, M.E.; Fajardo, J.A.G.; Vosques, E.N.O., Chemical Composition and Fungicidal Activity of the Essential Oil of Thymus vulgaris against Alternaria citri, e-Gnosis, 2006, 4, 1-7, retrieved from http://www.e-gnosis.udg.mx. [all data]

Orav, Raal, et al., 2006
Orav, A.; Raal, A.; Arak, E.; Müürisepp, M.; Kailas, T., Composition of the essential oil of Artemisia absinthium L. of different geographical origin, Proc. Est. Acad. Sci. Chem., 2006, 55, 3, 155-165. [all data]

Wong, Sivasothy, et al., 2006
Wong, K.C.; Sivasothy, Y.; Boey, P.L., Essential oil of Elettariopsis elan C.K. Lim, Flavour Fragr. J., 2006, 21, 3, 562-564, https://doi.org/10.1002/ffj.1654 . [all data]

Jirovetz, Buchbauer, et al., 2005
Jirovetz, L.; Buchbauer, G.; Ngassoum, M.B.; Parmentier, M., Chemical composition and olfactory characterization of essential oils of fruits and seeds of African pear (Dacryodes edulis (G. Don) H. J. Lam) from Cameroon, Flavour Fragr. J., 2005, 20, 2, 215-218, https://doi.org/10.1002/ffj.1324 . [all data]

Stevanovic, Garneau, et al., 2005
Stevanovic, T.; Garneau, F.-X.; Jean, F.-I.; Gagnon, H.; Vilotic, D.; Petrovic, S.; Ruzic, N.; Pichette, A., The essential oil composition of Pinus mugo Turra from Serbia, Flavour Fragr. J., 2005, 20, 1, 96-97, https://doi.org/10.1002/ffj.1390 . [all data]

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Priestap, van Baren, et al., 2002
Priestap, H.A.; van Baren, C.M.; Lira, P.D.L.; Prado, H.J.; Neugebauer, M.; Mayer, R.; Bandoni, A.L., Essential oils from aerial parts of Aristolochia gibertii Hook., Flavour Fragr. J., 2002, 17, 1, 69-71, https://doi.org/10.1002/ffj.1044 . [all data]

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Mallavarapu, Rao, et al., 2000
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Orav, Kuningas, et al., 1995
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Kollmannsberger, Nitz, et al., 1992
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Notes

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