Tricyclo[2.2.1.0(2,6)]heptane, 1,7,7-trimethyl-
- Formula: C10H16
- Molecular weight: 136.2340
- IUPAC Standard InChIKey: RRBYUSWBLVXTQN-UHFFFAOYSA-N
- CAS Registry Number: 508-32-7
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Species with the same structure:
- Other names: Tricyclene; 1,7,7-Trimethyltricyclo[2.2.1.0,2,6]heptane; Cyclene; NSC 86978; 1,7,7-Trimethyl-tricyclo[2.2.1.0*2,6*]heptane; α-Tricyclene; Tricyclo[2.2.1.02,6]heptane, 1,7,7-trimethyl-; 1,7,7-Trimethyltricyclo[2.2.1(2.6)]heptane; 1,7,7-trimethyltricyclo[2.2.1.02,6]heptane
- Information on this page:
- Other data available:
- Data at other public NIST sites:
- Options:
Normal alkane RI, polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-Innowax | BP-20 | Supelcowax-10 | RTX-Wax | HP-Innowax |
Column length (m) | 60. | 30. | 60. | 30. | |
Carrier gas | Helium | Nitrogen | Helium | Helium | Nitrogen |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.20 | 0.22 | 0.25 | |
Phase thickness (μm) | 0.25 | 0.20 | 0.25 | 0.52 | |
Tstart (C) | 60. | 60. | 70. | 60. | 35. |
Tend (C) | 220. | 200. | 220. | 230. | 205. |
Heat rate (K/min) | 5. | 5. | 3. | 2. | 3. |
Initial hold (min) | 1. | 10. | |||
Final hold (min) | 5. | 15. | 30. | 10. | |
I | 1018. | 1011. | 1016. | 1005. | 1014. |
Reference | Feng, Cui, et al., 2011 | Mishra, Chaudhary, et al., 2010 | Neves, Rosa, et al., 2010 | Museli, Pau, et al., 2009 | Wannes, Mhamdi, et al., 2009 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-Innowax | TC-FFAP | TC-FFAP | Supelcowax-10 | Supelcowax-10 |
Column length (m) | 30. | 30. | 30. | ||
Carrier gas | N2 | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.2 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.2 | 0.25 |
Tstart (C) | 50. | 60. | 60. | 70. | 50. |
Tend (C) | 240. | 220. | 220. | 220. | 250. |
Heat rate (K/min) | 5. | 3. | 3. | 3. | 2. |
Initial hold (min) | 1. | ||||
Final hold (min) | 4. | 30. | 30. | 15. | |
I | 1015. | 1021. | 1019. | 1030. | 1020. |
Reference | Cheraif, Ben Jannet, et al., 2007 | Kurose, Okamura, et al., 2007 | Kurose, Okamura, et al., 2007 | Pinto, Salgueiro, et al., 2007 | Raal, Orav, et al., 2007 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | Supelcowax-10 | Supelcowax 10 | HP-Wax | HP-20M | DB-Innowax |
Column length (m) | 30. | 30. | 30. | 30. | 60. |
Carrier gas | He | Helium | Nitrogen | N2 | Helium |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.20 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.20 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 40. | 70. | 50. | 50. | 60. |
Tend (C) | 250. | 220. | 280. | 250. | 240. |
Heat rate (K/min) | 3. | 3. | 5. | 5. | 3. |
Initial hold (min) | 5. | ||||
Final hold (min) | 10. | 15. | 5. | 10. | 20. |
I | 1001. | 1030. | 1014. | 1014. | 1009. |
Reference | Vichi, Riu-Aumatell, et al., 2007 | Cavaleiro, Pinto, et al., 2006 | Marzouk, Mansour, et al., 2006 | Marzouk, Neffati, et al., 2006 | Mendivil, Rodrigues, et al., 2006 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | NB-20M | Supelcowax-10 | Stabilwax | Supelcowax-10 | NB-20M |
Column length (m) | 30. | 30. | 30. | 30. | 50. |
Carrier gas | He | He | H2 | He | |
Substrate | |||||
Column diameter (mm) | 0.2 | 0.25 | 0.32 | 0.25 | 0.2 |
Phase thickness (μm) | 0.25 | 0.25 | 0.5 | 0.25 | 0.25 |
Tstart (C) | 50. | 50. | 40. | 40. | 50. |
Tend (C) | 250. | 250. | 280. | 210. | 250. |
Heat rate (K/min) | 2. | 4. | 6. | 2. | 2. |
Initial hold (min) | 1. | 5. | 2. | ||
Final hold (min) | 10. | 5. | 33. | ||
I | 1010. | 1002. | 1008. | 995. | 1017. |
Reference | Orav, Raal, et al., 2006 | Wong, Sivasothy, et al., 2006 | Jirovetz, Buchbauer, et al., 2005 | Stevanovic, Garneau, et al., 2005 | Raal, Arak, et al., 2004 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-Wax | CP-Wax 52CB | BP-20 | DB-Wax | DB-Wax |
Column length (m) | 50. | 50. | 25. | 60. | 60. |
Carrier gas | N2 | He | Nitrogen | He | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.30 | 0.50 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 75. | 40. | 60. | 40. | 60. |
Tend (C) | 220. | 220. | 200. | 200. | 240. |
Heat rate (K/min) | 3. | 3. | 5. | 2. | 4. |
Initial hold (min) | 4. | 5. | 2. | ||
Final hold (min) | |||||
I | 1029. | 1005. | 1003. | 1009. | 1013. |
Reference | Priestap, van Baren, et al., 2002 | Chagonda, Makanda, et al., 2000 | Mallavarapu, Rao, et al., 2000 | Umano, Hagi, et al., 2000 | Ngassoum, Yonkeu, et al., 1999 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-Innowax | PEG-20M | PEG-20M | Supelcowax-10 | Supelcowax-10 |
Column length (m) | 60. | 50. | 60. | ||
Carrier gas | He | He | He | ||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.32 | ||
Phase thickness (μm) | 0.25 | 0.25 | |||
Tstart (C) | 50. | 70. | 70. | 40. | 40. |
Tend (C) | 220. | 250. | 180. | 210. | 210. |
Heat rate (K/min) | 5. | 2. | 2. | 2. | 2. |
Initial hold (min) | 5. | 7. | 2. | 2. | |
Final hold (min) | 120. | 120. | |||
I | 1015. | 1017. | 1020. | 1004. | 1004. |
Reference | Stashenko, Cervantes, et al., 1998 | Orav, Kailas, et al., 1996 | Orav, Kuningas, et al., 1995 | Collin, Deslauriers, et al., 1993 | Collin, Deslauriers, et al., 1993 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary |
---|---|
Active phase | Carbowax 20M |
Column length (m) | 45. |
Carrier gas | Hydrogen |
Substrate | |
Column diameter (mm) | 0.32 |
Phase thickness (μm) | 1.0 |
Tstart (C) | 60. |
Tend (C) | 200. |
Heat rate (K/min) | 2. |
Initial hold (min) | 5. |
Final hold (min) | |
I | 1020. |
Reference | Kollmannsberger, Nitz, et al., 1992 |
Comment | MSDC-RI |
References
Go To: Top, Normal alkane RI, polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Feng, Cui, et al., 2011
Feng, T.; Cui, J.-J.; Xiao, Z.-B.; Tian, H.-X.; Yi, F.-P.; Ma, X.,
Chemical composition od essential oil from the peel of Chinese Torreya grandis Frt,
Org. Chem. International, 2011, 2011, 1-5, https://doi.org/10.1155/2011/187372
. [all data]
Mishra, Chaudhary, et al., 2010
Mishra, R.K.; Chaudhary, S.; Pandey, R.; Gupta, S.; Mallavarapu, G.R.; Kumar, S.,
Analysis of linalool content in the inflorescence (flower) essential oil and leaf oil of Lippia alba cultivar Kavach,
J. Essen. Oil Res., 2010, 22, 1, 3-7, https://doi.org/10.1080/10412905.2010.9700253
. [all data]
Neves, Rosa, et al., 2010
Neves, A.; Rosa, S.; Goncalves, J.; Rufino, A.; Judas, F.; Salgueiro, L.; Lopes, M.C.; Cavaleiro, C.; Mendes, A.F.,
Screening of five essential oils for identification of potential inhibitors of IL-1-unduced Nf-kB activation and NO production in human clondrocytes: characterization of the inhibitory activity of alpha-pinene,
Plante Med., 2010, 76, 03, 303-308, https://doi.org/10.1055/s-0029-1186085
. [all data]
Museli, Pau, et al., 2009
Museli, A.; Pau, M.; Desjobert, J.-M.; Foddai, M.; Usai, M.; Costa, J.,
Volatile constituents of Achllea ligustica All. by HS-SPME/GC/GC-MS. Comparison with essential oils obtained by hydrodistillation from Corsica and Sardinia,
Chromatographia, 2009, 69, 5/6, 575-585, https://doi.org/10.1365/s10337-008-0939-1
. [all data]
Wannes, Mhamdi, et al., 2009
Wannes, W.A.; Mhamdi, B.; Marzouk, B.,
GC comparative analysis of least essential oils from two Myrtle varieties at different phenological stages,
Chromatographia, 2009, 69, 1/2, 145-150, https://doi.org/10.1365/s10337-008-0818-9
. [all data]
Cheraif, Ben Jannet, et al., 2007
Cheraif, I.; Ben Jannet, H.; Hammami, M.; Khouja, M.L.; Mighri, Z.,
Chemical composition and antimicrobial activity of essential oils of Cupressus arizonica Greene,
Biochem. Syst. Ecol., 2007, 35, 12, 813-820, https://doi.org/10.1016/j.bse.2007.05.009
. [all data]
Kurose, Okamura, et al., 2007
Kurose, K.; Okamura, D.; Yatagai, M.,
Composition of the essential oils from the leaves of nine Pinus species and the cones of three of Pinus species,
Flavour Fragr. J., 2007, 22, 1, 10-20, https://doi.org/10.1002/ffj.1609
. [all data]
Pinto, Salgueiro, et al., 2007
Pinto, E.; Salgueiro, L.R.; Cavaleiro, C.; Palmeira, A.; Goncalves, M.J.,
In vitro susceptibility of some species of yeasts and filamentous fungi to essential oils of Salvia of?cinalis,
Ind. Crops Prod., 2007, 26, 2, 135-141, https://doi.org/10.1016/j.indcrop.2007.02.004
. [all data]
Raal, Orav, et al., 2007
Raal, A.; Orav, A.; Arak, E.; Kailas, T.; Müürisepp, M.,
Variation in the composition of the essential oil of Valeriana officinalis L. roots from Estonia,
Proc. Est. Acad. Sci. Chem., 2007, 56, 2, 67-74. [all data]
Vichi, Riu-Aumatell, et al., 2007
Vichi, S.; Riu-Aumatell, M.; Mora-Pons, M.; Guadayol, J.M.; Buxaderas, S.; López-Tamames, E.,
Analytical, Nutritional and Clinical Methods. HS-SPME coupled to GC/MS for quality control of Juniperus communis L. berries used for gin aromatization,
Food Chem., 2007, 105, 4, 1748-1754, https://doi.org/10.1016/j.foodchem.2007.03.026
. [all data]
Cavaleiro, Pinto, et al., 2006
Cavaleiro, C.; Pinto, E.; Gonsales, M.J.; Salguero, L.,
Antifungal activity of Juniperus essential oils agains dermatophyte, Asrgillus and Candida strains,
J. Appl. Microbiol., 2006, 100, 6, 1333-1338, https://doi.org/10.1111/j.1365-2672.2006.02862.x
. [all data]
Marzouk, Mansour, et al., 2006
Marzouk, Z.; Mansour, H.B.; Chraief, I.; Mosrati, R.; Cheriaa, J.; Neffati, A.; Marzouk, B.; Sfari, M.; Boukef, K.; Barillies, D.; Ghedira, L.C.,
Chemical composition, antibacterial and antimutagenic activities of four populations of Rosmarinus officinalis L. oils from Tunisia,
J. Food Agriculture Environment, 2006, 4, 2, 89-94. [all data]
Marzouk, Neffati, et al., 2006
Marzouk, Z.; Neffati, A.; Marzouk, B.; Chraief, I.; Fathia, K.; Ghedira, L.C.; Boukef, K.,
Chemical composition and antibacterial and antimutagenic activity of Tunisian Rosmarinus officinalis L. oil from Kasrine,
Journal of Food, Agriculture Environment, 2006, 4, 34, 61-65. [all data]
Mendivil, Rodrigues, et al., 2006
Mendivil, E.A.S.; Rodrigues, J.F.; Espinosa, M.E.; Fajardo, J.A.G.; Vosques, E.N.O.,
Chemical Composition and Fungicidal Activity of the Essential Oil of Thymus vulgaris against Alternaria citri,
e-Gnosis, 2006, 4, 1-7, retrieved from http://www.e-gnosis.udg.mx. [all data]
Orav, Raal, et al., 2006
Orav, A.; Raal, A.; Arak, E.; Müürisepp, M.; Kailas, T.,
Composition of the essential oil of Artemisia absinthium L. of different geographical origin,
Proc. Est. Acad. Sci. Chem., 2006, 55, 3, 155-165. [all data]
Wong, Sivasothy, et al., 2006
Wong, K.C.; Sivasothy, Y.; Boey, P.L.,
Essential oil of Elettariopsis elan C.K. Lim,
Flavour Fragr. J., 2006, 21, 3, 562-564, https://doi.org/10.1002/ffj.1654
. [all data]
Jirovetz, Buchbauer, et al., 2005
Jirovetz, L.; Buchbauer, G.; Ngassoum, M.B.; Parmentier, M.,
Chemical composition and olfactory characterization of essential oils of fruits and seeds of African pear (Dacryodes edulis (G. Don) H. J. Lam) from Cameroon,
Flavour Fragr. J., 2005, 20, 2, 215-218, https://doi.org/10.1002/ffj.1324
. [all data]
Stevanovic, Garneau, et al., 2005
Stevanovic, T.; Garneau, F.-X.; Jean, F.-I.; Gagnon, H.; Vilotic, D.; Petrovic, S.; Ruzic, N.; Pichette, A.,
The essential oil composition of Pinus mugo Turra from Serbia,
Flavour Fragr. J., 2005, 20, 1, 96-97, https://doi.org/10.1002/ffj.1390
. [all data]
Raal, Arak, et al., 2004
Raal, A.; Arak, E.; Orav, A.,
Chemical composition of coriander seed essential oil and their conformity with EP standards,
Agraarteadus, 2004, 15, 4, 234-239. [all data]
Priestap, van Baren, et al., 2002
Priestap, H.A.; van Baren, C.M.; Lira, P.D.L.; Prado, H.J.; Neugebauer, M.; Mayer, R.; Bandoni, A.L.,
Essential oils from aerial parts of Aristolochia gibertii Hook.,
Flavour Fragr. J., 2002, 17, 1, 69-71, https://doi.org/10.1002/ffj.1044
. [all data]
Chagonda, Makanda, et al., 2000
Chagonda, L.S.; Makanda, C.; Chalchat, J.-C.,
The essential oils of wild and cultivated Cymbopogon validus (Stapf) Stapf ex Burtt Davy and Elionurus muticus (Spreng.) Kunth from Zimbabwe,
Flavour Fragr. J., 2000, 15, 2, 100-104, https://doi.org/10.1002/(SICI)1099-1026(200003/04)15:2<100::AID-FFJ874>3.0.CO;2-Y
. [all data]
Mallavarapu, Rao, et al., 2000
Mallavarapu, G.R.; Rao, L.; Ramesh, S.,
Volatile constituents of the leaf and fruit oils of Murraya koenigii Spreng.,
L. Ess. Oil Res., 2000, 12, 6, 766-768, https://doi.org/10.1080/10412905.2000.9712211
. [all data]
Umano, Hagi, et al., 2000
Umano, K.; Hagi, Y.; Nakahara, K.; Shoji, A.; Shibamoto, T.,
Volatile chemicals identified in extracts from leaves of Japanese mugwort (Artemisia princeps Pamp.),
J. Agric. Food Chem., 2000, 48, 8, 3463-3469, https://doi.org/10.1021/jf0001738
. [all data]
Ngassoum, Yonkeu, et al., 1999
Ngassoum, M.B.; Yonkeu, S.; Jirovetz, L.; Buchbauer, G.; Schmaus, G.; Hammerschmidt, F.-J.H.,
Chemical composition of essential oils of Lantana camara leaves and flowers from Cameroon and Madagascar,
Flavour Fragr. J., 1999, 14, 4, 245-250, https://doi.org/10.1002/(SICI)1099-1026(199907/08)14:4<245::AID-FFJ819>3.0.CO;2-X
. [all data]
Stashenko, Cervantes, et al., 1998
Stashenko, E.E.; Cervantes, M.; Combariza, Y.; Martínez, J.R.,
HRGC-FID-MSD Analysis of the Secondary Metabolites Obtained by Different Extraction Methods from Lepechinia schiedeana, and Evaluation of its Antioxidant Activity in vitro
in 20th International Symposium on Capillary Chromatography, 1998, 1-11. [all data]
Orav, Kailas, et al., 1996
Orav, A.; Kailas, T.; Liiv, M.,
Analysis of terpenoic composition of conifer needle oils by steam distillation/extraction, gas chromatography and gas chromatography-mass spectrometry,
Chromatographia, 1996, 43, 3/4, 215-219, https://doi.org/10.1007/BF02292955
. [all data]
Orav, Kuningas, et al., 1995
Orav, A.; Kuningas, K.; Kailas, T.,
Computerized capillary gas chromatographic identification and determination of Siberian fir oil constituents,
J. Chromatogr. A, 1995, 697, 1-2, 495-499, https://doi.org/10.1016/0021-9673(94)01059-N
. [all data]
Collin, Deslauriers, et al., 1993
Collin, G.J.; Deslauriers, H.; Pageau, N.; Gagnon, M.,
Essential oil of Tansy (Tanacetum vulgare L.) of Canadian origin,
J. Essent. Oil Res., 1993, 5, 6, 629-638, https://doi.org/10.1080/10412905.1993.9698296
. [all data]
Kollmannsberger, Nitz, et al., 1992
Kollmannsberger, H.; Nitz, S.; Drawert, F.,
UBer die Aromastoffzusammensetzung von Hochdruckextrakten. I. Pfeffer (Piper nigrum, Var. muntok),
Z. Lebensm. Unters Forsch., 1992, 194, 6, 545-551, https://doi.org/10.1007/BF01185481
. [all data]
Notes
Go To: Top, Normal alkane RI, polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.