Borneol

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Kovats' RI, non-polar column, temperature ramp

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-5MSHP-5MSDB-5BP-1
Column length (m) 30.30.30.30.25.
Carrier gas HeHeHeHeN2
Substrate      
Column diameter (mm) 0.250.250.250.250.32
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.60.60.60.60.
Tend (C) 280.180.280. 220.
Heat rate (K/min) 5.3.2.3.5.
Initial hold (min) 3. 8.  
Final hold (min)  15.30. 13.
I 1150.1171.1166.1168.1163.
ReferenceAllegrone, Belliardo, et al., 2006Angioni, Barra, et al., 2006Hazzit, Baaliouamer, et al., 2006Lucero, Fredrickson, et al., 2006Raina, Verma, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-1DB-5DB-5HP-5MSDB-5
Column length (m) 30.30.30.30.30.
Carrier gas N2HeHeHeHelium
Substrate      
Column diameter (mm) 0.320.260.260.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.50.60.
Tend (C) 220.246.246.250.255.
Heat rate (K/min) 5.3.3.3.3.
Initial hold (min)    10. 
Final hold (min) 3.  5. 
I 1149.1169.1165.1165.1168.
ReferenceSrivastava, Srivastava, et al., 2006Adams, Morris, et al., 2005Adams and Nguyen, 2005Asuming, Beauchamp, et al., 2005Medina, Lucero, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5MSDB-5HP-5CP Sil 5 CB
Column length (m)  30.30.30.25.
Carrier gas  HeH2HeH2
Substrate      
Column diameter (mm)  0.250.250.250.25
Phase thickness (μm)  0.250.250.250.15
Tstart (C) 60.60.40.60.50.
Tend (C) 240.180.280.260.230.
Heat rate (K/min) 3.3.4.3.3.
Initial hold (min)  15.   
Final hold (min)   30.  
I 1165.1172.1177.1168.1151.
ReferenceShatar S., 2005Angioni, Barra, et al., 2004Avato, Raffo, et al., 2004Lopes, Strobl, et al., 2004Ogunwande, Olawore, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP Sil 8 CBDB-5HP-5MSHP-5DB-5
Column length (m) 30.50.30.30.30.
Carrier gas H2HeHeHeHe
Substrate      
Column diameter (mm) 0.250.320.250.250.25
Phase thickness (μm) 0.250.250.251.0.25
Tstart (C) 50.50.50.40.60.
Tend (C) 220.280.280.250. 
Heat rate (K/min) 3.5.4.5.3.
Initial hold (min) 2.2.2.1. 
Final hold (min)  10.10.  
I 1162.1177.1168.1188.1167.
ReferenceSchwob, Bessiere, et al., 2004Baranauskiene, Venskutonis, et al., 2003Baranauskiene, Venskutonis, et al., 2003, 2Bouzouita, Kachouri, et al., 2003Lucero, Estell, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP Sil 5 CBHP-5BP-1SE-30HP-5
Column length (m) 25.30.25.30.30.
Carrier gas H2HeN2HeHe
Substrate      
Column diameter (mm) 0.250.250.550.250.25
Phase thickness (μm) 0.150.250.25 0.25
Tstart (C) 50.60.60.60.60.
Tend (C) 230.280.220.240.200.
Heat rate (K/min) 3.3.5.4.4.
Initial hold (min)     1.
Final hold (min)   15. 15.
I 1151.1162.1172.1146.1166.
ReferenceOgunwande, Olawore, et al., 2003Özcan, Tzakou, et al., 2003Srivastava, Ahmad, et al., 2003Juliani, Koroch, et al., 2002Juliani and Simon, 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP Sil 5 CBSE-30BP-1BP-1HP-5MS
Column length (m) 25.25.60.25.30.
Carrier gas HeHeN2N2He
Substrate      
Column diameter (mm) 0.250.220.320.550.25
Phase thickness (μm)  0.250.250.250.25
Tstart (C) 50.70.60.60.50.
Tend (C) 230.220.220.220.250.
Heat rate (K/min) 3.4.5.5.3.
Initial hold (min)      
Final hold (min)    15. 
I 1151.1154.1163.1157.1165.
ReferenceKasali, Adio, et al., 2002Palá-Paúl, Velasco-Negueruela, et al., 2002Raina, Lal, et al., 2002Raina, Srivastava, et al., 2002Salido, Altarejos, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-1SSP-1DB-1DB-1BP-1
Column length (m) 30.30.28.50.25.
Carrier gas N2HeHeN2N2
Substrate      
Column diameter (mm) 0.320.320.250.250.55
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.50.50.80.60.
Tend (C) 220.250.270.225.220.
Heat rate (K/min) 5.2.4.54.5.
Initial hold (min)  2.1.  
Final hold (min) 13.5.  15.
I 1152.1140.1166.1147.1149.
ReferenceShawl, Srivastava, et al., 2002Nagarajan, Rao, et al., 2001Nagalakshmi, Thangadurai, et al., 2001Palá-Paúl, Velasco-Negueruela, et al., 2001Raina, Srivastava, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1HP-5SE-54DB-5SE-54
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHe 
Substrate      
Column diameter (mm) 0.250.250.260.260.26
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.60.60.60.60.
Tend (C) 260.280.246.240.246.
Heat rate (K/min) 2.3.3.3.3.
Initial hold (min) 5.    
Final hold (min) 20.    
I 1142.1162.1165.1165.1165.
ReferenceSenatore and Rigano, 2001Tzakou and Couladis, 2001Adams, 2000Adams, 2000, 2Adams, 2000, 3
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5Methyl SiliconeHP-5MSDB-5DB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHe He
Substrate      
Column diameter (mm) 0.260.320.250.320.26
Phase thickness (μm) 0.250.250.25 0.25
Tstart (C) 60.60.60.50.60.
Tend (C) 246.225.280.250.246.
Heat rate (K/min) 3.2.3.3.3.
Initial hold (min)  2. 5. 
Final hold (min)  5.   
I 1165.1150.1168.1169.1165.
ReferenceAdams, 2000, 4Jayaprakasha, Rao, et al., 2000Roussis, Tsoukatou, et al., 2000Tzakou, Harvala, et al., 2000Adams, 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP Sil 5 CBHP-5Methyl SiliconeBPX-5SPB-1
Column length (m) 25.30.25.50.30.
Carrier gas HeHeN2N2He
Substrate      
Column diameter (mm) 0.250.250.50.220.32
Phase thickness (μm)  0.25 0.250.25
Tstart (C) 60.60.60.60.60.
Tend (C) 280.280.220.185.250.
Heat rate (K/min) 5.4.5.2.5.
Initial hold (min)    10.2.
Final hold (min)     5.
I 1156.1163.1155.1164.1167.
ReferenceKaul, Gujral, et al., 1999Sajjadi and Ghassemi, 1999Mallavarapu, Rao, et al., 1998Fournier, Hadjiakhoondi, et al., 1997Jayaprakasha, Jaganmohan Rao, et al., 1997
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillary
Active phase DB-5SE-30OV-101
Column length (m) 30.25.25.
Carrier gas HeN2N2
Substrate    
Column diameter (mm) 0.250.20.25
Phase thickness (μm) 0.25  
Tstart (C) 60.60.50.
Tend (C) 240.180.200.
Heat rate (K/min) 3.3.5.
Initial hold (min)  10. 
Final hold (min)  1. 
I 1165.1154.1159.
ReferenceTellez, Estell, et al., 1997Jantan, Ali, et al., 1995Menut, Molangui, et al., 1995
Comment MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Kovats' RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Allegrone, Belliardo, et al., 2006
Allegrone, G.; Belliardo, F.; Cabella, P., Comparison of volatile concentrations in hand-squeezed juices of four different lemon varieties, J. Agric. Food Chem., 2006, 54, 5, 1844-1848, https://doi.org/10.1021/jf051206s . [all data]

Angioni, Barra, et al., 2006
Angioni, A.; Barra, A.; Coroneo, V.; Dessi, S.; Cabras, P., Chemical composition, seasonal variability, and antifungal activity of Lavandula stoechas L. ssp. stoechas essential oils from stem/leaves and flowers, J. Agric. Food Chem., 2006, 54, 12, 4364-4370, https://doi.org/10.1021/jf0603329 . [all data]

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Hazzit, M.; Baaliouamer, A.; Faleiro, M.L.; Miguel, M.G., Composition of the Essential Oils of Thymus and Origanum Species from Algeria and Their Antioxidant and Antimicrobial Activities, J. Agric. Food Chem., 2006, 54, 17, 6314-6321, https://doi.org/10.1021/jf0606104 . [all data]

Lucero, Fredrickson, et al., 2006
Lucero, M.E.; Fredrickson, E.L.; Estell, R.E.; Morrison, A.A.; Richman, D.B., Volatile Composition of Gutierrezia sarothrae (Broom Snakeweed) as Determined by Steam Distillation and Solid Phase Microextraction, J. Essent. Oil Res., 2006, 18, 2, 121-125, https://doi.org/10.1080/10412905.2006.9699039 . [all data]

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Raina, V.K.; Verma, S.C.; Dhawan, S.; Khan, M.; Ramesh, S.; Singh, S.C.; Yadav, A.; Srivastava, S.K., Essential oil composition of Murraya exotica from the plains of northern India, Flavour Fragr. J., 2006, 21, 1, 140-142, https://doi.org/10.1002/ffj.1547 . [all data]

Srivastava, Srivastava, et al., 2006
Srivastava, A.K.; Srivastava, S.K.; Syamsundar, K.V., Volatile composition of Curcuma angustifolia Roxb. rhizome from central and southern India, Flavour Fragr. J., 2006, 21, 3, 423-426, https://doi.org/10.1002/ffj.1680 . [all data]

Adams, Morris, et al., 2005
Adams, R.P.; Morris, J.A.; Pandey, R.N.; Schwarzbach, A.E., Cryptic speciation between Juniperus deltoides and Juniperus oxycedrus (Cupressaceae) in the Mediterranean, Biochem. Syst. Ecol., 2005, 33, 8, 771-787, https://doi.org/10.1016/j.bse.2005.01.001 . [all data]

Adams and Nguyen, 2005
Adams, R.P.; Nguyen, S., Infra-specific variation in Juniperus deppeana and F. Sperryi in the Davis Mountains of Texas: variation in leaf essential oils and random amplified polymorphic DNAS (RAPDS), Phytologia, 2005, 87, 2, 96-108. [all data]

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Asuming, W.A.; Beauchamp, P.S.; Descalzo, J.T.; Dev, B.C.; Dev, V.; Frost, S.; Ma, C.W., Essential oil composition of four Lomatium Raf. species and their chemotaxonomy, Biochem. Syst. Ecol., 2005, 33, 1, 17-26, https://doi.org/10.1016/j.bse.2004.06.005 . [all data]

Medina, Lucero, et al., 2005
Medina, A.L.; Lucero, M.E.; Holguin, F.O.; Estell, R.E.; Posakony, J.J.; Simon, J.; O'Connell, M.A., Composition and antimicrobial activity of Anemopsis californica leaf oil, J. Agric. Food Chem., 2005, 53, 22, 8694-8698, https://doi.org/10.1021/jf0511244 . [all data]

Shatar S., 2005
Shatar S., Essential oil of Ferula ferulaoides from Western Mongolia, Chem. Nat. Compd. (Engl. Transl.), 2005, 41, 5, 607-608, https://doi.org/10.1007/s10600-005-0222-8 . [all data]

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Angioni, A.; Barra, A.; Cereti, E.; Barile, D.; Coïsson, J.D.; Arlorio, M.; Dessi, S.; Coroneo, V.; Cabras, P., Chemical composition, plant genetic differences, antimicrobial and antifungal activity investigation of the essential oil of Rosmarinus officinalis L., J. Agric. Food Chem., 2004, 52, 11, 3530-3535, https://doi.org/10.1021/jf049913t . [all data]

Avato, Raffo, et al., 2004
Avato, P.; Raffo, F.; Aldouri, N.A.; Vartanian, S.T., Essential oils of varthemia iphionoides from Jordan, Flavour Fragr. J., 2004, 19, 6, 559-561, https://doi.org/10.1002/ffj.1351 . [all data]

Lopes, Strobl, et al., 2004
Lopes, D.; Strobl, H.; Kolodziejczyk, P., 14-Methylpentadecano-15-lactone (Muscolide): a new macrocyclic lactone from the oil of Angelica archangelica L., Chemistry and Biodiversity, 2004, 1, 12, 1880-1887, https://doi.org/10.1002/cbdv.200490144 . [all data]

Ogunwande, Olawore, et al., 2004
Ogunwande, I.A.; Olawore, N.O.; Adeleke, K.A.; Ekundayo, O.; König, W.A., Rare terpenoid esters from Hyparrhenia rufa (Nees) Stapf. growing wild in Nigeria, Flavour Fragr. J., 2004, 19, 3, 239-243, https://doi.org/10.1002/ffj.1295 . [all data]

Schwob, Bessiere, et al., 2004
Schwob, I.; Bessiere, J.-M.; Masotti, V.; Viano, J., Changes in essential oil composition in Saint John's wort (Hypericum perforatum L.) aerial parts during its phenological cycle, Biochem. Syst. Ecol., 2004, 32, 8, 735-745, https://doi.org/10.1016/j.bse.2003.12.005 . [all data]

Baranauskiene, Venskutonis, et al., 2003
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Baranauskiene, Venskutonis, et al., 2003, 2
Baranauskiene, R.; Venskutonis, P.R.; Viskelis, P.; Dambrauskiene, E., Influence of nitrogen fertilizers on the yield and composition of thyme (Thymus vulgaris), J. Agric. Food Chem., 2003, 51, 26, 7751-7758, https://doi.org/10.1021/jf0303316 . [all data]

Bouzouita, Kachouri, et al., 2003
Bouzouita, N.; Kachouri, F.; Hamdi, M.; Chaabouni, M.M., Antimicrobial activity of essential oils from Tunisian aromatic plants, Flavour Fragr. J., 2003, 18, 5, 380-383, https://doi.org/10.1002/ffj.1200 . [all data]

Lucero, Estell, et al., 2003
Lucero, M.E.; Estell, R.E.; Frederickson, E.L., The essential oil composition of Psorothamnus scoparius (A. Gray) Rydb., J. Essent. Oil Res., 2003, 15, 2, 108-111, https://doi.org/10.1080/10412905.2003.9712083 . [all data]

Ogunwande, Olawore, et al., 2003
Ogunwande, I.A.; Olawore, N.O.; Kasali, A.A.; König, W.A., Chemical composition of the leaf volatile oils of Callitris intratropica R.T. Baker H.G. Smith from Nigeria, Flavour Fragr. J., 2003, 18, 5, 387-389, https://doi.org/10.1002/ffj.1214 . [all data]

Özcan, Tzakou, et al., 2003
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Srivastava, Ahmad, et al., 2003
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Kasali, Adio, et al., 2002
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Palá-Paúl, Velasco-Negueruela, et al., 2002
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Raina, Lal, et al., 2002
Raina, V.K.; Lal, R.K.; Tripathi, S.; Khan, M.; Syamasundar, K.V.; Srivastava, S.K., Erratum. Essential oil composition of genetically diverse stocks of Murraya koenigii from India, Flavour Fragr. J., 2002, 17, 5, 404, https://doi.org/10.1002/ffj.1139 . [all data]

Raina, Srivastava, et al., 2002
Raina, V.K.; Srivastava, S.K.; Jain, N.; Ahmad, A.; Syamasundar, K.V.; Aggarwal, K.K., Essential oil composition of Curcuma longa L. cv. Roma from the plains of northern India, Flavour Fragr. J., 2002, 17, 2, 99-102, https://doi.org/10.1002/ffj.1053 . [all data]

Salido, Altarejos, et al., 2002
Salido, S.; Altarejos, J.; Nogueras, M.; Sánchez, A.; Pannecouque, C.; Witvrouw, M.; De Clercq, E., Chemical studies of essential oils of Juniperus oxycedrus ssp. badia, J. Ethnopharmacol., 2002, 81, 1, 129-134, https://doi.org/10.1016/S0378-8741(02)00045-4 . [all data]

Shawl, Srivastava, et al., 2002
Shawl, A.S.; Srivastava, S.K.; Syamasundar, K.V.; Tripathi, S.; Raina, V.K., Essential oil composition of Achillea millefolium L. growing wild in Kashmir, India, Flavour Fragr. J., 2002, 17, 3, 165-168, https://doi.org/10.1002/ffj.1074 . [all data]

Nagarajan, Rao, et al., 2001
Nagarajan, S.; Rao, L.J.M.; Gurudutt, K.N., Chemical composition of the volatiles of Hemidesmus indicus R. Br., Flavour Fragr. J., 2001, 16, 3, 212-214, https://doi.org/10.1002/ffj.985 . [all data]

Nagalakshmi, Thangadurai, et al., 2001
Nagalakshmi, M.A.H.; Thangadurai, D.; Anuradha, T.; Pullaiah, T., Essential oil constituents of Melia dubia, a wild relative of Azadirachta indica growing in the Eastern Ghats of Peninsular India, Flavour Fragr. J., 2001, 16, 4, 241-244, https://doi.org/10.1002/ffj.986 . [all data]

Palá-Paúl, Velasco-Negueruela, et al., 2001
Palá-Paúl, J.; Velasco-Negueruela, A.; Pérez-Alonso, M.J.; Sanz, J., Analysis of the volatile components of Argyranthemum adauctum (Link.) Humphries by gas chromatography-mass spectrometry, J. Chromatogr. A, 2001, 923, 1-2, 295-298, https://doi.org/10.1016/S0021-9673(01)01003-2 . [all data]

Raina, Srivastava, et al., 2001
Raina, V.K.; Srivastava, S.K.; Aggarwal, K.K.; Ramesh, S.; Kumar, S., Essential oil composition of Cinnamomum zeylanicum Blume leaves from Little Andaman, India, Flavour Fragr. J., 2001, 16, 5, 374-376, https://doi.org/10.1002/ffj.1016 . [all data]

Senatore and Rigano, 2001
Senatore, F.; Rigano, D., Essential oil of two Lippia spp. (Verbenaceae) growing wild in Guatemala, Flavour Fragr. J., 2001, 16, 3, 169-171, https://doi.org/10.1002/ffj.972 . [all data]

Tzakou and Couladis, 2001
Tzakou, O.; Couladis, M., The essential oil of Micromeria graeca (L.) Bentham et Reichenb. growing in Greece, Flavour Fragr. J., 2001, 16, 2, 107-109, https://doi.org/10.1002/ffj.955 . [all data]

Adams, 2000
Adams, R.P., Systematics of smooth leaf margin Juniperus of the western hemisphere based on leaf essential oils and RAPD DNA fingerprinting, Biochem. Syst. Ecol., 2000, 28, 2, 149-162, https://doi.org/10.1016/S0305-1978(99)00047-2 . [all data]

Adams, 2000, 2
Adams, R.P., Systematics of Juniperus section Juniperus based on leaf essential oils and random amplified polymorphic DNAs (RAPDs), Biochem. Syst. Ecol., 2000, 28, 6, 515-528, https://doi.org/10.1016/S0305-1978(99)00089-7 . [all data]

Adams, 2000, 3
Adams, R.P., Systematics of the one seeded Juniperus of the eastern hemisphere based on leaf essential oils and random amplified polymorphic DNAs (RAPDs), Biochem. Syst. Ecol., 2000, 28, 6, 529-543, https://doi.org/10.1016/S0305-1978(99)00096-4 . [all data]

Adams, 2000, 4
Adams, R.P., The serrate leaf margined Juniperus (Section Sabina) of the western hemisphere: systematics and evolution based on leaf essential oils and Random Amplified Polymorphic DNAs (RAPDs), Biochem. Syst. Ecol., 2000, 28, 10, 975-989, https://doi.org/10.1016/S0305-1978(00)00022-3 . [all data]

Jayaprakasha, Rao, et al., 2000
Jayaprakasha, G.K.; Rao, L.J.M.; Sakariah, K.K., Chemical composition of the flower oil of Cinnamomum zeylanicum blume, J. Agric. Food Chem., 2000, 48, 9, 4294-4295, https://doi.org/10.1021/jf991395c . [all data]

Roussis, Tsoukatou, et al., 2000
Roussis, V.; Tsoukatou, M.; Petrakis, P.V.; Chinou, I.; Skoula, M.; Harborne, J.B., Volatile constituents of four Helichrysum species growing in Greece, Biochem. Syst. Ecol., 2000, 28, 2, 163-175, https://doi.org/10.1016/S0305-1978(99)00046-0 . [all data]

Tzakou, Harvala, et al., 2000
Tzakou, O.; Harvala, C.; Galati, E.M.; Sanogo, R., Essential oil composition of Nepeta argolica Borey et Chaub. subsp. argolica, Flavour Fragr. J., 2000, 15, 2, 115-118, https://doi.org/10.1002/(SICI)1099-1026(200003/04)15:2<115::AID-FFJ877>3.0.CO;2-9 . [all data]

Adams, 1999
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Kaul, Gujral, et al., 1999
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Notes

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