Borneol

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Van Den Dool and Kratz RI, polar column, temperature ramp

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-WaxBP-20BP-20HP-InnowaxBP-20
Column length (m) 60.50.50.30.50.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.220.220.220.250.22
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.60.60.
Tend (C) 230.220.220.280.220.
Heat rate (K/min) 2.2.2.3.2.
Initial hold (min)      
Final hold (min) 30.20.20. 20.
I 1698.1707.1695.1715.1698.
ReferenceBendahou, Muselli, et al., 2008Castilho, Liu, et al., 2007Duquesnoy, Castola, et al., 2007Kundakovic, Fokialakis, et al., 2007Lesueur, de Rocca Serra, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-20MRTX-WaxDB-WaxBP-20BP-20
Column length (m) 50.60.30.50.50.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.20.220.250.220.25
Phase thickness (μm) 0.20.250.50.250.25
Tstart (C) 70.60.40.60.60.
Tend (C) 180.230.250.220.220.
Heat rate (K/min) 4.2.4.2.2.
Initial hold (min) 4. 5.  
Final hold (min) 10.30.15.20.20.
I 1651.1672.1706.1696.1691.
ReferenceMaksimovic, Vidic, et al., 2007Muselli, Rossi, et al., 2007Pozo-Bayon M.A., Ruiz-Rodriguez A., et al., 2007Boti, Bighelli, et al., 2006Bousmaha, Boti, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-WaxPolyethylene GlycolBP-20BP-20DB-Wax
Column length (m) 60.30.50.50.30.
Carrier gas HeN2HeHeHe
Substrate      
Column diameter (mm) 0.220.320.220.220.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.50.60.60.50.
Tend (C) 230.230.220.220.220.
Heat rate (K/min) 2.2.2.2.4.
Initial hold (min)  10.  4.
Final hold (min) 45.15.20.20.20.
I 1693.1702.1705.1701.1700.
ReferenceCavalli, Tomi, et al., 2006Dob, Dahmane, et al., 2006Duquesnoy, Dinh, et al., 2006Gonny, Cavaleiro, et al., 2006Osorio, Alarcon, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxRTX-WaxSupelcowax-10Supelcowax-10HP-20M
Column length (m) 60.60.30.30.50.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.320.220.20.20.2
Phase thickness (μm) 0.250.250.20.20.2
Tstart (C) 35.60.70.70.70.
Tend (C) 220.230.220.220.180.
Heat rate (K/min) 3.2.3.3.4.
Initial hold (min)     4.
Final hold (min)  35.15.15.10.
I 1705.1700.1695.1696.1653.
ReferencePala-Paul, Copeland, et al., 2006Paolini J., Desjobert J.M., et al., 2006Pinto, Pina-Vaz, et al., 2006Salgueiro L.R., Pinto E., et al., 2006Skocibusic, Bezic, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP-Wax 52CBRTX-WaxPEGRTX-WaxDB-Wax
Column length (m) 60.60.30.60.30.
Carrier gas   N2HeHe
Substrate      
Column diameter (mm) 0.250.220.320.220.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 35.60.50.60.40.
Tend (C) 203.220.220.230.200.
Heat rate (K/min) 3.2.2.2.2.
Initial hold (min) 4. 3.  
Final hold (min)  20.15.35.20.
I 1699.1672.1695.1692.1690.
ReferenceAlasalvar, Taylor, et al., 2005Cozzani, Muselli, et al., 2005Dob, Berramdane, et al., 2005Paolini, Costa, et al., 2005Seo and Baek, 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Carbowax 20MMegawaxPEG-20MDB-WaxHP-Wax
Column length (m) 60.30.30.60.30.
Carrier gas HeHeN2HeHe
Substrate      
Column diameter (mm) 0.250.250.250.320.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 45.40.50.32.60.
Tend (C) 250.220.220.220.240.
Heat rate (K/min) 2.2.4.3.3.
Initial hold (min) 0.176.8.  
Final hold (min)  10.20.  
I 1686.1674.1705.1704.1707.
ReferenceVerzera, Campisi, et al., 2005Verzera, Trozzi, et al., 2005Zhang, Xu, et al., 2005Brophy, Goldsack, et al., 2004Flamini, Bader, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-WaxBP-20HP-20MBP-20DB-Wax
Column length (m) 30.50.50.50.30.
Carrier gas N2 HeHeHe
Substrate      
Column diameter (mm) 0.250.220.20.220.25
Phase thickness (μm) 0.250.250.20.250.25
Tstart (C) 60.60.70.60.40.
Tend (C) 240.220.180.220.200.
Heat rate (K/min) 3.2.4.2.4.
Initial hold (min)   4. 5.
Final hold (min)  20.10.20.20.
I 1706.1698.1653.1686.1678.
ReferenceFlamini, Cioni, et al., 2004Gonny, Bradesi, et al., 2004Skocibusic and Bezic, 2004Tam, Thuam, et al., 2004Yu, Kim, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxHP-WaxRTX-WaxSupelcowaxSupelcowax
Column length (m) 30.30.60.25.25.
Carrier gas HeN2He  
Substrate      
Column diameter (mm) 0.250.250.220.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.60.60.35.35.
Tend (C) 200.220.230.225.225.
Heat rate (K/min) 4.5.2.4.4.
Initial hold (min) 5.10. 5.5.
Final hold (min) 20. 45.10.10.
I 1679.1702.1687.1721.1721.
ReferenceYu, Kim, et al., 2004, 2Bader, Caponi, et al., 2003Cavalli, Tomi, et al., 2003Chisholm, Wilson, et al., 2003Chisholm, Wilson, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-20MHP-20MHP20WaxHP-InnowaxRTX-Wax
Column length (m) 50.50.50.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.20.20.20.250.25
Phase thickness (μm) 0.20.20.20.50.25
Tstart (C) 70.70.70.60.45.
Tend (C) 180.180.180.260.250.
Heat rate (K/min) 4.5.4.3.3.
Initial hold (min) 4.4.4. 6.
Final hold (min) 10.10.10. 10.
I 1657.1653.1653.1696.1675.
ReferenceJerkovic, Mastelic, et al., 2003Radonic and Milso, 2003Skocibusic and Bezic, 2003Tzakou, Couladis, et al., 2003Mondello, Zappia, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase AT-WaxBP-20BP-20HP-InnowaxHP-Innowax
Column length (m) 60.50.50.30.30.
Carrier gas He HeHeHe
Substrate      
Column diameter (mm) 0.320.220.220.250.25
Phase thickness (μm) 0.250.250.250.500.50
Tstart (C) 65.60.60.60.60.
Tend (C) 250.220.230.260.260.
Heat rate (K/min) 2.2.2.3.3.
Initial hold (min) 10.    
Final hold (min) 60.20.35.10. 
I 1680.1691.1692.1689.1696.
ReferencePino, Marbot, et al., 2002Pintore, Usai, et al., 2002Bianchini, Tomi, et al., 2001Couladis, Baziou, et al., 2001Couladis, Tzakou, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-20MAT-WaxCP-Wax 52CBDB-WaxDB-Wax
Column length (m) 50.60.60.60.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.200.320.250.50.25
Phase thickness (μm) 0.200.250.250.320.25
Tstart (C) 70.65.45.40.40.
Tend (C) 180.250.250.290.200.
Heat rate (K/min) 4.2.2.4.2.
Initial hold (min) 4.10.0.172.5.
Final hold (min) 10.60. 5.20.
I 1653.1680.1686.1717.1693.
ReferenceMilos, Radonic, et al., 2001Pino, Marbot, et al., 2001Verzera, Campisi, et al., 2001Bartley and Jacobs, 2000Kim, Thuy, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-InnowaxInnowaxCarbowax 20MSP-1000DB-Wax
Column length (m) 60.60.25.85.60.
Carrier gas HeHeH2He 
Substrate      
Column diameter (mm) 0.250.250.250.50.25
Phase thickness (μm)  0.250.3 0.25
Tstart (C) 32.50.50.60.40.
Tend (C) 220.180.200.225.200.
Heat rate (K/min) 2.2.53.3.3.
Initial hold (min) 1.5.1. 5.
Final hold (min) 40. 20. 60.
I 1709.1715.1712.1708.1704.
ReferenceChristensen, Jakobsen, et al., 1999Stashenko, Cervantes, et al., 1999Bicchi, Rubiolo, et al., 1998Brophy, Forster, et al., 1998Cha, Kim, et al., 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-20DB-WaxDB-WaxCarbowax 20MHP-20M
Column length (m) 50.25.60.50.50.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.220.250.320.20.25
Phase thickness (μm) 0.250.250.50.2 
Tstart (C) 60.50.50.30.60.
Tend (C) 230.240.225.170.190.
Heat rate (K/min) 2.4.2.4.3.
Initial hold (min)  3. 2. 
Final hold (min) 35. 20.20. 
I 1692.1692.1697.1696.1677.
ReferenceMariotti, Tomi, et al., 1997Möllenbeck, König, et al., 1997Sagrero-Nieves, Bartley, et al., 1997Píry, Príbela, et al., 1995Chung, Eiserich, et al., 1993
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillary
Active phase HP-FFAPDB-WaxDB-WaxCarbowax 20M
Column length (m) 50.30.30.60.
Carrier gas HeHeHeHe
Substrate     
Column diameter (mm) 0.250.250.250.32
Phase thickness (μm)  0.250.25 
Tstart (C) 60.50.50.50.
Tend (C) 210.250.250.225.
Heat rate (K/min) 3.4.4.1.5
Initial hold (min)  3.3. 
Final hold (min)    80.
I 1747.1665.1666.1695.
ReferenceChung, Eiserich, et al., 1993Fröhlich, Duque, et al., 1989Fröhlich, Duque, et al., 1989Chen and Ho, 1988
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bendahou, Muselli, et al., 2008
Bendahou, M.; Muselli, A.; Grignon-Dubois, M.; Benyoucef, M.; Desjobert, J.-M.; Bernardini, A.-F.; Costa, J., Antimicrobial activity and chemical composition of Origanum glandulosum Desf. essential oil and extract obtained by microwave extraction: Comparison with hydrodistillation, Food Chem., 2008, 106, 1, 132-139, https://doi.org/10.1016/j.foodchem.2007.05.050 . [all data]

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Zhang, Xu, et al., 2005
Zhang, F.; Xu, Q.; Fu, S.; Ma, X.; Xiao, H.; Liang, X., Chemical constituents of the essential oil of Asarum forbesii Maxim (Aristolochiaceae), Flavour Fragr. J., 2005, 20, 3, 318-320, https://doi.org/10.1002/ffj.1423 . [all data]

Brophy, Goldsack, et al., 2004
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Flamini, Bader, et al., 2004
Flamini, G.; Bader, A.; Cioni, P.L.; Katbeh-Bader, A.; Morelli, I., Composition of the essential oil of leaves, galls, and ripe and unripe fruits of Jordian Pistacia palaestina Boiss., J. Agric. Food Chem., 2004, 52, 3, 572-576, https://doi.org/10.1021/jf034773t . [all data]

Flamini, Cioni, et al., 2004
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Gonny, Bradesi, et al., 2004
Gonny, M.; Bradesi, P.; Casanova, J., Identification of the components of the essential oil from wild Corsican Daucus carota L. using 13C-NMR spectroscopy, Flavour Fragr. J., 2004, 19, 5, 424-433, https://doi.org/10.1002/ffj.1330 . [all data]

Skocibusic and Bezic, 2004
Skocibusic, M.; Bezic, N., Phytochemical Analysis and In vitro Antimicrobial Activity of Two Satureja Species Essential Oils, Phytother. Res., 2004, 18, 12, 967-970, https://doi.org/10.1002/ptr.1489 . [all data]

Tam, Thuam, et al., 2004
Tam, N.T.; Thuam, D.T.; Bighelli, A.; Castola, V.; Muselli, A.; Richomme, P.; Casanova, J., Baeckea frutescens leaf oil from Vietnam: composition and chemical variability, Flavour Fragr. J., 2004, 19, 3, 217-220, https://doi.org/10.1002/ffj.1281 . [all data]

Yu, Kim, et al., 2004
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Notes

Go To: Top, Van Den Dool and Kratz RI, polar column, temperature ramp, References