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dimethylcadmium

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas123. ± 12.kJ/molReviewMartinho Simões 
Deltafgas102.2 ± 4.2kJ/molReviewMartinho Simões 
Deltafgas104.8 ± 1.3kJ/molReviewMartinho SimõesSelected data.

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid65.1 ± 4.2kJ/molReviewMartinho SimõesMS
Deltafliquid67.7 ± 1.3kJ/molReviewMartinho SimõesSelected data.; MS
Quantity Value Units Method Reference Comment
liquid201.88J/mol*KN/AN/ADH
Quantity Value Units Method Reference Comment
Deltafsolid86. ± 12.kJ/molReviewMartinho SimõesMS
Quantity Value Units Method Reference Comment
Deltacsolid-1989. ± 12.kJ/molCC-SBLong and Norrish, 1949Please also see Cox and Pilcher, 1970.; MS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
132.01298.15N/AT = 15 to 300 K.; DH

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C2H6Cd (g) = CH3Cd (g) + Methane (g)

By formula: C2H6Cd (g) = CH3Cd (g) + CH4 (g)

Quantity Value Units Method Reference Comment
Deltar234.3 ± 6.3kJ/molKinGJackson, 1989 
Deltar243. - 255.kJ/molN/ASmith and Patrick, 1983 
Deltar251. ± 17.kJ/molN/AMcMillen and Golden, 1982 

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Long and Norrish, 1949
Long, L.H.; Norrish, R.G.W., Phil. Trans. Roy. Soc. (London), 1949, A241, 587. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Jackson, 1989
Jackson, R.L., Chem. Phys. Lett., 1989, 163, 315. [all data]

Smith and Patrick, 1983
Smith, G.P.; Patrick, R., Int. J. Chem. Kinet., 1983, 15, 167. [all data]

McMillen and Golden, 1982
McMillen, D.F.; Golden, D.M., Hydrocarbon bond dissociation energies, Ann. Rev. Phys. Chem., 1982, 33, 493. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References