dimethylcadmium
- Formula: C2H6Cd
- Molecular weight: 142.480
- CAS Registry Number: 506-82-1
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | 123. ± 12. | kJ/mol | Review | Martinho Simões | |
| ΔfH°gas | 102.2 ± 4.2 | kJ/mol | Review | Martinho Simões | |
| ΔfH°gas | 104.8 ± 1.3 | kJ/mol | Review | Martinho Simões | Selected data. |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.56 ± 0.02 | PI | Distefano and Dibeler, 1970 | RDSH |
| 8.8 | PE | Creber and Bancroft, 1980 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| CH3Cd+ | 9.69 ± 0.02 | CH3 | PI | Distefano and Dibeler, 1970 | RDSH |
| Cd+ | 12.10 ± 0.02 | 2CH3 | PI | Distefano and Dibeler, 1970 | RDSH |
References
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Distefano and Dibeler, 1970
Distefano, G.; Dibeler, V.H.,
Photoionization study of the dimethyl compounds of zinc, cadmium, and mercury,
Intern. J. Mass Spectrom. Ion Phys., 1970, 4, 59. [all data]
Creber and Bancroft, 1980
Creber, D.K.; Bancroft, G.M.,
Photoelectron studies of dialkyl group 2B compounds: Ligand field splittings intensity variations with photon energy,
Inorg. Chem., 1980, 19, 643. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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