Chromium, (carbonothioyl)pentacarbonyl-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
8.31 ± 0.03EIMichels, Flesch, et al., 1980 
8.16PEEnglish, Plowman, et al., 1979Vertical value
8.16PELichtenberger and Fenske, 1976Vertical value

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
COCr+14.94 ± 0.084CO+CSEIMichels, Flesch, et al., 1980 
CSCr+13.68 ± 0.045COEIMichels, Flesch, et al., 1980 
C2OSCr+12.12 ± 0.044COEIMichels, Flesch, et al., 1980 
C2O2Cr+13.52 ± 0.083CO+CSEIMichels, Flesch, et al., 1980 
C3O2SCr+11.12 ± 0.043COEIMichels, Flesch, et al., 1980 
C3O3Cr+12.06 ± 0.052CO+CSEIMichels, Flesch, et al., 1980 
C4O3SCr+10.22 ± 0.042COEIMichels, Flesch, et al., 1980 
C4O4Cr+11.12 ± 0.05CO+CSEIMichels, Flesch, et al., 1980 
C5O4SCr+9.39 ± 0.04COEIMichels, Flesch, et al., 1980 
C5O5Cr+10.58 ± 0.07CSEIMichels, Flesch, et al., 1980 
Cr+16.16 ± 0.075CO+CSEIMichels, Flesch, et al., 1980 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Michels, Flesch, et al., 1980
Michels, G.D.; Flesch, G.D.; Svec, H.J., Comparative mass spectrometry of the group 6B hexacarbonyls and pentacarbonyl thiocarbonyls, Inorg. Chem., 1980, 19, 479. [all data]

English, Plowman, et al., 1979
English, A.M.; Plowman, K.R.; Butler, I.S.; Diemann, E.; Muller, A., He(I) photoelectron spectra of pentacarbonyl(selenocarbonyl)chromium(0) related complexes, Inorg. Chim. Acta, 1979, 32, 113. [all data]

Lichtenberger and Fenske, 1976
Lichtenberger, D.L.; Fenske, R.F., Electronic structure of transition metal thiocarbonyl complexes, Inorg. Chem., 1976, 15, 2015. [all data]


Notes

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