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Diazene, dimethyl-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C2H6N2+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
8.30PEFrost, Lee, et al., 1976LLK
8.7 ± 0.2EIPrasil and Forst, 1968RDSH
8.7 ± 0.1EIGowenlock, Majer, et al., 1962RDSH
9.0PERao, 1975Vertical value; LLK
8.95 ± 0.05PEKoenig, Balle, et al., 1975Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH2N+14.7 ± 0.3?EIPrasil and Forst, 1968RDSH
CH3+11.5 ± 0.1?EIGowenlock, Majer, et al., 1962RDSH
CH3N2+9.2CH3EIFoster and Beauchamp, 1972LLK
CH3N2+9.5 ± 0.3CH3EIPrasil and Forst, 1968RDSH
CH3N2+9.0 ± 0.1CH3EIGowenlock, Majer, et al., 1962RDSH
C2H4+12.9 ± 0.3?EIPrasil and Forst, 1968RDSH
N2+16.3 ± 0.3?EIPrasil and Forst, 1968RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Frost, Lee, et al., 1976
Frost, D.C.; Lee, S.T.; McDowell, C.A.; Westwood, N.P.C., The photoelectron spectra of diazene, diazene-d2, trans-methyldiazene, J. Chem. Phys., 1976, 64, 4719. [all data]

Prasil and Forst, 1968
Prasil, Z.; Forst, W., Mass spectrometry of azomethane, J. Am. Chem. Soc., 1968, 90, 3344. [all data]

Gowenlock, Majer, et al., 1962
Gowenlock, B.G.; Majer, J.R.; Snelling, D.R., Bond dissociation energies in some azo compounds, J. Chem. Soc. Faraday Trans., 1962, 58, 670. [all data]

Rao, 1975
Rao, C.N.R., Lone-pair ionization bands of chromophores in the photoelectron spectra of organic molecules, Indian J. Chem., 1975, 13, 950. [all data]

Koenig, Balle, et al., 1975
Koenig, T.; Balle, T.; Snell, W., Helium(I) photoelectron spectra of organic radicals, J. Am. Chem. Soc., 1975, 97, 662. [all data]

Foster and Beauchamp, 1972
Foster, M.S.; Beauchamp, J.L., Gas-phase ion chemistry of azomethane by ion cyclotron resonance spectroscopy, J. Am. Chem. Soc., 1972, 94, 2425. [all data]


Notes

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