2-Oxepanone

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-458. ± 2.kJ/molCmWiberg and Waldron, 1991Heat of reduction; ALS
Quantity Value Units Method Reference Comment
liquid235.7J/mol*KN/ALebedev and Yevstropov, 1983DH
liquid235.6J/mol*KN/ALebedev, Yevstropov, et al., 1978DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
196.8298.15Lebedev and Yevstropov, 1983T = 13.8 to 340 K.; DH
196.8298.15Lebedev, Yevstropov, et al., 1978T = 13.8 to 350 K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wiberg and Waldron, 1991
Wiberg, K.B.; Waldron, R.F., Lactones. 2. Enthalpies of hydrolysis, reduction, and formation of the C4-C13 monocyclic lactones. strain energies and conformations, J. Am. Chem. Soc., 1991, 113, 7697-7705. [all data]

Lebedev and Yevstropov, 1983
Lebedev, B.V.; Yevstropov, A.A., Thermodynamics of «beta»-propiolactone, t-butyrolactone, d-valerolactone, and e-caprolactone from 13.8 to 340 K, J. Chem. Thermodynam., 1983, 15, 115-128. [all data]

Lebedev, Yevstropov, et al., 1978
Lebedev, B.V.; Yevstropov, A.A.; Lebedev, N.K.; Karpova, Ye.A.; Lyudvig, Ye.B.; Belen'kaya, B.G., The thermodynamics of e-caprolactone, its polymer and of e-caprolactone polymerization in the 0-350°K range, Vysokomol. Soedin., 1978, A20, 1974-1980. [all data]


Notes

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