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2-Norbornene

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid29.7 ± 1.7kJ/molCcbHall, Smith, et al., 1973ALS
Quantity Value Units Method Reference Comment
Deltacliquid-4213. ± 2.kJ/molCcbHall, Smith, et al., 1973Corresponding «DELTA»fliquid = 29.7 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
Deltafsolid44.4 ± 2.0kJ/molCcrSteele, Chirico, et al., 1996Hfusion=3.2±0.2 kJ/mol; ALS
Deltafsolid53.5 ± 3.2kJ/molCcbSteele, 1978ALS
Deltafsolid41.4 ± 1.4kJ/molCcbKozina, Bychikhina, et al., 1976ALS
Quantity Value Units Method Reference Comment
Deltacsolid-4228.2 ± 2.0kJ/molCcrSteele, Chirico, et al., 1996Hfusion=3.2±0.2 kJ/mol; Corresponding «DELTA»fsolid = 44.44 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-4237.2 ± 3.2kJ/molCcbSteele, 1978Corresponding «DELTA»fsolid = 53.5 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-4225.1 ± 1.3kJ/molCcbKozina, Bychikhina, et al., 1976Corresponding «DELTA»fsolid = 41.4 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
129.9298.15Steele, 1978DH
129.9297.Hall, Smith, et al., 1973DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hall, Smith, et al., 1973
Hall, H.K., Jr.; Smith, C.D.; Baldt, J.H., Enthalpies of formation of norticyclene, norbornene, norbornadiene, and quadricyclane, J. Am. Chem. Soc., 1973, 95, 3197-3201. [all data]

Steele, Chirico, et al., 1996
Steele, W.V.; Chirico, R.D.; Knipmeyer, S.E.; Nguyen, A.; Smith, N.K., Thermodynamic properties and ideal-gas enthalpies of formation for butyl vinyl ether, 1,2-dimethoxyethane, methyl glycolate, bicyclo[2.2.1]hept-2-ene, 5-vinylbicyclo[2.2.1]hept-2-ene, trans-azobenzene, butyl acrylate, di-tert-butyl ether, and hexane-1,6-diol, J. Chem. Eng. Data, 1996, 41, 1285-1302. [all data]

Steele, 1978
Steele, W.V., The standard enthalpies of formation of a series of C7, bridged-ring hydrocarbons: norbornane, norbornene, nortricyclene, norbornadiene, and quadricyclane, J. Chem. Thermodyn., 1978, 10, 919-927. [all data]

Kozina, Bychikhina, et al., 1976
Kozina, M.P.; Bychikhina, L.V.; Gal'chenko, G.L.; Mil'vitskaya, E.M.; Ordubadi, M.; Plate, A.F., Enthalpies of nortricyclene and norbornene formation, Dokl. Akad. Nauk SSSR, 1976, 226, 1105-1108. [all data]


Notes

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