PtCO

Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 15530 ± 120 T gas Chatterjee, Akin, et al., 2003

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 10040 ± 150 T gas Chatterjee, Akin, et al., 2003

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 5820 ± 150 T gas Chatterjee, Akin, et al., 2003

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σ+ 1 CO stretch 2065.5 Ne IR Liang, Zhou, et al., 2000
1 CO stretch 2051.9 Ar IR Kundig, McIntosh, et al., 1973
Manceron, Tremblay, et al., 2000
Π 2 Bend 916.8 Ar IR Manceron, Tremblay, et al., 2000
Σ+ 3 PtC stretch 550 ± 140 gas PE Chatterjee, Akin, et al., 2003
3 PtC stretch 580.8 Ar IR Manceron, Tremblay, et al., 2000

Additional references: Jacox, 1998, page 167; Jacox, 2003, page 67; Evans and Gerry, 2001

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chatterjee, Akin, et al., 2003
Chatterjee, B.; Akin, F.A.; Jarrold, C.C.; Raghavachari, K., A comparison of stable carbonyls formed in the gas-phase reaction between group 10 atomic anions and methanol or methoxy radicals: Anion photoelectron spectroscopy and density functional theory calculations on HNiCO[sup -], PdCO[sup -], and PtCO[sup -], J. Chem. Phys., 2003, 119, 20, 10591, https://doi.org/10.1063/1.1619131 . [all data]

Liang, Zhou, et al., 2000
Liang, B.; Zhou, M.; Andrews, L., Reactions of Laser-Ablated Ni, Pd, and Pt Atoms with Carbon Monoxide: Matrix Infrared Spectra and Density Functional Calculations on M(CO), J. Phys. Chem. A, 2000, 104, 17, 3905, https://doi.org/10.1021/jp993646q . [all data]

Kundig, McIntosh, et al., 1973
Kundig, E.P.; McIntosh, D.; Moskovits, M.; Ozin, G.A., Binary carbonyls of platinum, Pt(CO)n (where n = 1-4). Comparative study of the chemical and physical properties of M(CO)n (where M = nickel, palladium, or platinum; n = 1-4), J. Am. Chem. Soc., 1973, 95, 22, 7234, https://doi.org/10.1021/ja00803a009 . [all data]

Manceron, Tremblay, et al., 2000
Manceron, L.; Tremblay, B.; Alikhani, M.E., Vibrational Spectra of PtCO and Pt(CO), J. Phys. Chem. A, 2000, 104, 16, 3750, https://doi.org/10.1021/jp9938819 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Evans and Gerry, 2001
Evans, C.J.; Gerry, M.C.L., Pure Rotational Spectrum and Structure of Platinum Monocarbonyl, PtCO, J. Phys. Chem. A, 2001, 105, 42, 9659, https://doi.org/10.1021/jp012215g . [all data]

Notes

Go To: Top, Vibrational and/or electronic energy levels, References