β-Bisabolene
- Formula: C15H24
- Molecular weight: 204.3511
- IUPAC Standard InChIKey: XZRVRYFILCSYSP-HNNXBMFYSA-N
- CAS Registry Number: 495-61-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: Cyclohexene, 1-methyl-4-(5-methyl-1-methylene-4-hexenyl)-, (S)-; 1,5-Heptadiene, 6-methyl-2-(4-methyl-3-cyclohexen-1-yl)-, (S)-(-)-; l-β-Bisabolene; (+,-)-β-Bisabolene; 1-Methyl-4-(5-methyl-1-methylene-4-hexenyl)-1-cyclohexene-, (4S)-; beta-Bisabolene; (-)-β-bisabolene; 1-Methyl-4-(5-methyl-1-methylene-4-hexenyl)-(S)-cyclohexene; (S)-1-Methyl-4-(6-methylhepta-1,5-dien-2-yl)cyclohex-1-ene; Cyclohexene, 1-methyl-4-(5-methyl-1-methylene-4-hexen-1-yl)-, (4S)-
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Options:
Kovats' RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-1 | HP-5MS | DB-5 | BP-1 | DB-5 |
Column length (m) | 30. | 30. | 30. | 30. | 30. |
Carrier gas | He | He | He | N2 | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.32 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 50. | 60. | 60. | 60. | 40. |
Tend (C) | 280. | 280. | 220. | 210. | |
Heat rate (K/min) | 5. | 2. | 3. | 5. | 2. |
Initial hold (min) | 3. | 8. | 2. | ||
Final hold (min) | 30. | 3. | 33. | ||
I | 1503. | 1506. | 1509. | 1503. | 1512. |
Reference | Allegrone, Belliardo, et al., 2006 | Hazzit, Baaliouamer, et al., 2006 | Lucero, Fredrickson, et al., 2006 | Srivastava, Srivastava, et al., 2006 | Sylvestre, Pichette, et al., 2006 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-5MS | HP-5MS | DB-5 | SPB-1 | HP-5MS |
Column length (m) | 30. | 30. | 30. | 30. | |
Carrier gas | He | He | He | He | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.32 | 0.25 | |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Tstart (C) | 50. | 50. | 60. | 50. | 60. |
Tend (C) | 240. | 250. | 240. | 250. | 200. |
Heat rate (K/min) | 3. | 3. | 3. | 2. | 4. |
Initial hold (min) | 10. | 2. | 1. | ||
Final hold (min) | 5. | 5. | 15. | ||
I | 1547. | 1511. | 1509. | 1490. | 1506. |
Reference | Tepe, Askin Akpulat, et al., 2006 | Asuming, Beauchamp, et al., 2005 | Shatar S., 2005 | Behera, Nagarajan, et al., 2004 | Juliani, Zygadlo, et al., 2004 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-5 | DB-5 | DB-5 | HP-5MS | HP-5MS |
Column length (m) | 30. | 25. | 50. | 30. | 30. |
Carrier gas | He | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.32 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Tstart (C) | 60. | 40. | 50. | 50. | 60. |
Tend (C) | 260. | 280. | 280. | 280. | 280. |
Heat rate (K/min) | 3. | 3. | 5. | 4. | 3. |
Initial hold (min) | 5. | 2. | 2. | ||
Final hold (min) | 5. | 10. | 10. | ||
I | 1509. | 1506. | 1525. | 1517. | 1489. |
Reference | Lopes, Strobl, et al., 2004 | Amparo Blázquez, Pérez, et al., 2003 | Baranauskiene, Venskutonis, et al., 2003 | Baranauskiene, Venskutonis, et al., 2003, 2 | Gkinis, Tzakou, et al., 2003 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | CP Sil 5 CB | BP-1 | SPB-1 | HP-5 | DB-1 |
Column length (m) | 25. | 25. | 30. | 30. | 25. |
Carrier gas | He | N2 | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.32 | 0.32 | 0.25 | 0.2 |
Phase thickness (μm) | 0.15 | 0.25 | 0.25 | 0.25 | |
Tstart (C) | 50. | 60. | 60. | 60. | 60. |
Tend (C) | 230. | 220. | 225. | 200. | 220. |
Heat rate (K/min) | 3. | 5. | 2. | 4. | 3. |
Initial hold (min) | 3. | 1. | |||
Final hold (min) | 15. | 5. | 15. | ||
I | 1505. | 1507. | 1476. | 1509. | 1506. |
Reference | Ogunwande, Olawore, et al., 2003 | Raina, Srivastava, et al., 2003 | Jayaprakasha, Jena, et al., 2002 | Juliani and Simon, 2002 | Mevy, Bessiere, et al., 2002 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | BP-1 | BP-1 | HP-5MS | BP-1 | HP-1 |
Column length (m) | 25. | 25. | 30. | 30. | 25. |
Carrier gas | N2 | N2 | He | N2 | He |
Substrate | |||||
Column diameter (mm) | 0.32 | 0.55 | 0.25 | 0.32 | 0.2 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 60. | 60. | 50. | 60. | 100. |
Tend (C) | 220. | 220. | 250. | 220. | 220. |
Heat rate (K/min) | 5. | 5. | 3. | 5. | 4. |
Initial hold (min) | |||||
Final hold (min) | 15. | 15. | 13. | ||
I | 1505. | 1501. | 1508. | 1510. | 1508. |
Reference | Raina, Srivastava, et al., 2002 | Raina, Srivastava, et al., 2002, 2 | Salido, Altarejos, et al., 2002 | Shawl, Srivastava, et al., 2002 | Rajeswara Rao, 2001 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-5 | SE-54 | DB-5 | SE-30 | OV-101 |
Column length (m) | 30. | 30. | 30. | 25. | 25. |
Carrier gas | He | He | He | ||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.26 | 0.26 | 0.2 | 0.32 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | ||
Tstart (C) | 60. | 60. | 60. | 60. | 50. |
Tend (C) | 280. | 246. | 246. | 180. | 200. |
Heat rate (K/min) | 3. | 3. | 3. | 3. | 5. |
Initial hold (min) | 10. | ||||
Final hold (min) | |||||
I | 1509. | 1509. | 1509. | 1503. | 1491. |
Reference | Tzakou and Couladis, 2001 | Adams, 2000 | Adams, 1999 | Jantan I. and Ahmad A.S., 1999 | Kuiate, Zollo, et al., 1999 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-5 | HP-5MS | Methyl Silicone | Methyl Silicone | CP Sil 5 CB |
Column length (m) | 30. | 30. | 30. | 25. | 30. |
Carrier gas | He | He | He | N2 | Ar |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.32 | 0.32 | 0.5 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Tstart (C) | 60. | 70. | 60. | 60. | 60. |
Tend (C) | 280. | 250. | 250. | 220. | 220. |
Heat rate (K/min) | 4. | 3. | 2. | 5. | 3. |
Initial hold (min) | 5. | 2. | |||
Final hold (min) | 5. | ||||
I | 1507. | 1500. | 1497. | 1507. | 1500. |
Reference | Sajjadi and Ghassemi, 1999 | Siani, Ramos, et al., 1999 | Adegoke, Rao, et al., 1998 | Mallavarapu, Rao, et al., 1998 | Szafranek, Malinski, et al., 1998 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|
Active phase | CP Sil 8 CB | SE-30 | DB-1 | BP-1 |
Column length (m) | 25. | 25. | 28. | 50. |
Carrier gas | Ar | N2 | He | H2 |
Substrate | ||||
Column diameter (mm) | 0.15 | 0.2 | 0.25 | 0.33 |
Phase thickness (μm) | 0.12 | 0.25 | ||
Tstart (C) | 60. | 60. | 50. | 65. |
Tend (C) | 220. | 180. | 270. | 220. |
Heat rate (K/min) | 3. | 3. | 4. | 5. |
Initial hold (min) | 10. | 1. | 2. | |
Final hold (min) | 1. | |||
I | 1507. | 1498. | 1498. | 1506. |
Reference | Szafranek, Malinski, et al., 1998 | Jantan, Ahmad, et al., 1996 | Saad, El-Sharkawy, et al., 1995 | Ekundayo, Laakso, et al., 1988 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Kovats' RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Allegrone, Belliardo, et al., 2006
Allegrone, G.; Belliardo, F.; Cabella, P.,
Comparison of volatile concentrations in hand-squeezed juices of four different lemon varieties,
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Hazzit, Baaliouamer, et al., 2006
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Composition of the Essential Oils of Thymus and Origanum Species from Algeria and Their Antioxidant and Antimicrobial Activities,
J. Agric. Food Chem., 2006, 54, 17, 6314-6321, https://doi.org/10.1021/jf0606104
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Lucero, Fredrickson, et al., 2006
Lucero, M.E.; Fredrickson, E.L.; Estell, R.E.; Morrison, A.A.; Richman, D.B.,
Volatile Composition of Gutierrezia sarothrae (Broom Snakeweed) as Determined by Steam Distillation and Solid Phase Microextraction,
J. Essent. Oil Res., 2006, 18, 2, 121-125, https://doi.org/10.1080/10412905.2006.9699039
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Srivastava, Srivastava, et al., 2006
Srivastava, A.K.; Srivastava, S.K.; Syamsundar, K.V.,
Volatile composition of Curcuma angustifolia Roxb. rhizome from central and southern India,
Flavour Fragr. J., 2006, 21, 3, 423-426, https://doi.org/10.1002/ffj.1680
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Sylvestre, Pichette, et al., 2006
Sylvestre, M.; Pichette, A.; Longtin, A.; Nagau, F.; Legault, J.,
Essential oil analysis and anticancer activity of leaf essential oil of Croton flavens L. from Guadeloupe,
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Tepe, Askin Akpulat, et al., 2006
Tepe, B.; Askin Akpulat, H.; Sokmen, M.; Daferera, D.; Yumrutas, O.; Aydin, E.; Polissiou, M.; Sokmen, A.,
Screening of the antioxidative and antimicrobial properties of the essential oils of Pimpinella anisetum and Pimpinella flabellifolia from Turkey,
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Asuming, Beauchamp, et al., 2005
Asuming, W.A.; Beauchamp, P.S.; Descalzo, J.T.; Dev, B.C.; Dev, V.; Frost, S.; Ma, C.W.,
Essential oil composition of four Lomatium Raf. species and their chemotaxonomy,
Biochem. Syst. Ecol., 2005, 33, 1, 17-26, https://doi.org/10.1016/j.bse.2004.06.005
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Shatar S., 2005
Shatar S.,
Essential oil of Ferula ferulaoides from Western Mongolia,
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Behera, Nagarajan, et al., 2004
Behera, S.; Nagarajan, S.; Rao, L.J.M.,
Microwave heating and conventional roasting of cumin seeds (Cuminum cyminum L.) and effect on chemical composition of volatiles,
Food Chem., 2004, 87, 1, 25-29, https://doi.org/10.1016/j.foodchem.2003.10.012
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Juliani, Zygadlo, et al., 2004
Juliani, H.R.; Zygadlo, J.A.; Scrivanti, R.; de la Sota, E.; Simon, J.E.,
The essential oil of Anemia tomentosa (Savigny) Sw. var. anthriscifolia (Schrad.) Mickel,
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Lopes, Strobl, et al., 2004
Lopes, D.; Strobl, H.; Kolodziejczyk, P.,
14-Methylpentadecano-15-lactone (Muscolide): a new macrocyclic lactone from the oil of Angelica archangelica L.,
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Amparo Blázquez, Pérez, et al., 2003
Amparo Blázquez, M.; Pérez, I.; Boira, H.,
Essential oil analysis of Teucrium libanitis and T. turredanum by GC and GC-MS,
Flavour Fragr. J., 2003, 18, 6, 497-501, https://doi.org/10.1002/ffj.1256
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Baranauskiene, Venskutonis, et al., 2003
Baranauskiene, R.; Venskutonis, R.P.; Demyttenaere, J.C.R.,
Sensory and instrumental evaluation of catnip (Nepeta cataria L.) aroma,
J. Agric. Food Chem., 2003, 51, 13, 3840-3848, https://doi.org/10.1021/jf021187b
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Baranauskiene, Venskutonis, et al., 2003, 2
Baranauskiene, R.; Venskutonis, P.R.; Viskelis, P.; Dambrauskiene, E.,
Influence of nitrogen fertilizers on the yield and composition of thyme (Thymus vulgaris),
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Gkinis, Tzakou, et al., 2003
Gkinis, G.; Tzakou, O.; Iliopoulou, D.; Roussis, V.,
Chemical Composition and Biological Activity of Nepeta parnassica Oils and Isolated Nepetalactones,
Z. Naturforsch. C:, 2003, 58, 681-686. [all data]
Ogunwande, Olawore, et al., 2003
Ogunwande, I.A.; Olawore, N.O.; Adeleke, K.A.; Ekundayo, O.; Koenig, W.A.,
Chemical composition of the leaf volatile oil of Psidium guajava L. growing in Nigeria,
Flavour Fragr. J., 2003, 18, 2, 136-138, https://doi.org/10.1002/ffj.1175
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Raina, Srivastava, et al., 2003
Raina, V.K.; Srivastava, S.K.; Syamasunder, K.V.,
Essential oil composition of Acorus calamus L. from the lower region of the Himalayas,
Flavour Fragr. J., 2003, 18, 1, 18-20, https://doi.org/10.1002/ffj.1136
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Jayaprakasha, Jena, et al., 2002
Jayaprakasha, G.K.; Jena, B.S.; Negi, P.S.; Sakariah, K.K.,
Evaluation of antioxidant activities and antimutagenicity of turmeric oil: a byproduct from curcumin production,
Z. Naturforsch. C:, 2002, 57c, 828-835, retrieved from http://www.znaturforsch.com/57c/s57c0828.pdf. [all data]
Juliani and Simon, 2002
Juliani, H.R.; Simon, J.E.,
Antioxidant acitivity of basil
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Mevy, Bessiere, et al., 2002
Mevy, J.P.; Bessiere, J.-M.; Dherbomez, M.; Viano, J.,
Composition and some biological activities of the essential oils from an African pasture grass: Elionurus elegans Kunth.,
J. Agric. Food Chem., 2002, 50, 15, 4240-4243, https://doi.org/10.1021/jf0115140
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Raina, Srivastava, et al., 2002
Raina, V.K.; Srivastava, S.K.; Syamasunder, K.V.,
The essential oil of 'greater galangal' [Alpinia galanga (L.) Willd.] from the lower Himalayan region of India,
Flavour Fragr. J., 2002, 17, 5, 358-360, https://doi.org/10.1002/ffj.1105
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Raina, Srivastava, et al., 2002, 2
Raina, V.K.; Srivastava, S.K.; Jain, N.; Ahmad, A.; Syamasundar, K.V.; Aggarwal, K.K.,
Essential oil composition of Curcuma longa L. cv. Roma from the plains of northern India,
Flavour Fragr. J., 2002, 17, 2, 99-102, https://doi.org/10.1002/ffj.1053
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Salido, Altarejos, et al., 2002
Salido, S.; Altarejos, J.; Nogueras, M.; Sánchez, A.; Pannecouque, C.; Witvrouw, M.; De Clercq, E.,
Chemical studies of essential oils of Juniperus oxycedrus ssp. badia,
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Shawl, Srivastava, et al., 2002
Shawl, A.S.; Srivastava, S.K.; Syamasundar, K.V.; Tripathi, S.; Raina, V.K.,
Essential oil composition of Achillea millefolium L. growing wild in Kashmir, India,
Flavour Fragr. J., 2002, 17, 3, 165-168, https://doi.org/10.1002/ffj.1074
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Rajeswara Rao, 2001
Rajeswara Rao, B.R.,
Biomass and essential oil yields of rainfed palmarosa (Cymbopogon martinii (Roxb.) Wats. var. motia Burk.) supplied with different levels of organic manure and fertilizer nitrogen in semi-arid tropical climate,
Ind. Crops Prod., 2001, 14, 3, 171-178, https://doi.org/10.1016/S0926-6690(01)00081-4
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Tzakou and Couladis, 2001
Tzakou, O.; Couladis, M.,
The essential oil of Micromeria graeca (L.) Bentham et Reichenb. growing in Greece,
Flavour Fragr. J., 2001, 16, 2, 107-109, https://doi.org/10.1002/ffj.955
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Adams, 2000
Adams, R.P.,
Systematics of the one seeded Juniperus of the eastern hemisphere based on leaf essential oils and random amplified polymorphic DNAs (RAPDs),
Biochem. Syst. Ecol., 2000, 28, 6, 529-543, https://doi.org/10.1016/S0305-1978(99)00096-4
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Adams, 1999
Adams, R.P.,
Systematics of multi-seeded eastern hemisphere Juniperus based on leaf essential oils and RAPD DNA fingerprinting,
Biochem. Syst. Ecol., 1999, 27, 7, 709-725, https://doi.org/10.1016/S0305-1978(99)00016-2
. [all data]
Jantan I. and Ahmad A.S., 1999
Jantan I.; Ahmad A.S.,
Oleoresins of three pinus species from malaysian pine plantations,
ASEAN Review of BiodiversityEnvironment Conservation, 1999, November-December, 1-9. [all data]
Kuiate, Zollo, et al., 1999
Kuiate, J.-R.; Zollo, P.-H.A.; Lamaty, G.; Menut, C.; Bessière, J.-M.,
Composition of the essential oils from the leaves of two varieties of Aspilia africana (Pers.) C. D. Adams from Cameroon,
Flavour Fragr. J., 1999, 14, 3, 167-169, https://doi.org/10.1002/(SICI)1099-1026(199905/06)14:3<167::AID-FFJ802>3.0.CO;2-O
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Sajjadi and Ghassemi, 1999
Sajjadi, S.E.; Ghassemi, N.,
Volatile constituents of Nepeta glomerulosa Boiss. subsp. carmanica,
Flavour Fragr. J., 1999, 14, 5, 265-267, https://doi.org/10.1002/(SICI)1099-1026(199909/10)14:5<265::AID-FFJ822>3.0.CO;2-A
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Siani, Ramos, et al., 1999
Siani, A.C.; Ramos, M.F.S.; Menezes-de-Lima, O., Jr.; Ribeiro-dos-Santos, R.; Fernadez-Ferreira, E.; Soares, R.O.A.; Rosas, E.C.; Susunaga, G.S.; Guimarães, A.C.; Zoghbi, M.G.B.; Henriques, M.G.M.O.,
Evaluation of anti-inflammatory-related activity of essential oils from the leaves and resin of species of Protium,
J. Ethnopharmacol., 1999, 66, 1, 57-69, https://doi.org/10.1016/S0378-8741(98)00148-2
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Adegoke, Rao, et al., 1998
Adegoke, G.O.; Rao, L.J.M.; Shankaracharya, N.B.,
A comparison of the essential oils of Aframomum daniellii (Hook. f.) K. Schum. and Amomum subulatum Roxb,
Flavour Fragr. J., 1998, 13, 5, 349-352, https://doi.org/10.1002/(SICI)1099-1026(1998090)13:5<349::AID-FFJ758>3.0.CO;2-O
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Mallavarapu, Rao, et al., 1998
Mallavarapu, G.R.; Rao, B.R.R.; Kaul, P.N.; Ramesh, S.; Bhattacharya, A.K.,
Volatile constituents of the essential oils of the seeds and the herb of palmarosa (Cymbopogon martinii (Roxb.) Wats. var. motia Burk.),
Flavour Fragr. J., 1998, 13, 3, 167-169, https://doi.org/10.1002/(SICI)1099-1026(199805/06)13:3<167::AID-FFJ719>3.0.CO;2-B
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Szafranek, Malinski, et al., 1998
Szafranek, B.; Malinski, E.; Szafranek, J.,
The sesquiterpene composition of leaf cuticular neutral lipids of ten varieties of polish Solanum tuberosum,
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Jantan, Ahmad, et al., 1996
Jantan, I.; Ahmad, A.S.; Ahmad, A.R.; Ali, N.A.M.; Ayop, N.,
Chemical composition of some citrus oils from Malaysia,
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Saad, El-Sharkawy, et al., 1995
Saad, H.-E.A.; El-Sharkawy, S.H.; Halim, A.F.,
Essential oils of Daucus carota ssp. maximus,
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. [all data]
Ekundayo, Laakso, et al., 1988
Ekundayo, O.; Laakso, I.; Adegbola, R.-M.; Oguntimein, B.; Sofowora, A.; Hiltunen, R.,
Essential oil constituents of Ashanti pepper (Piper guineense) fruits (berries),
J. Agric. Food Chem., 1988, 36, 5, 880-882, https://doi.org/10.1021/jf00083a001
. [all data]
Notes
Go To: Top, Kovats' RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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