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Naphthalene, decahydro-, cis-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil466. ± 5.KAVGN/AAverage of 15 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus230. ± 2.KAVGN/AAverage of 12 out of 14 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple230.15 ± 0.09KAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Tc704. ± 3.KN/ADaubert, 1996 
Tc681.KN/AMatzik and Schneider, 1985Uncertainty assigned by TRC = 1.5 K; TRC
Tc705.0KN/APak and Kay, 1972Uncertainty assigned by TRC = 1. K; extrapolated to zero time to correct for decomposition; TRC
Tc702.2KN/ACheng, McCoubrey, et al., 1962Uncertainty assigned by TRC = 1.5 K; extrapolated to zero time to correct for decomposition; calibr. vs NPL thermometer; TRC
Quantity Value Units Method Reference Comment
Pc32. ± 2.barN/ADaubert, 1996 
Pc24.90barN/AMatzik and Schneider, 1985Uncertainty assigned by TRC = 0.50 bar; TRC
Pc32.07barN/APak and Kay, 1972Uncertainty assigned by TRC = 0.2068 bar; corrected for vapor pressure of Hg, and extrapolated to zero time to correct for decompostion; TRC
Quantity Value Units Method Reference Comment
Deltavap50.2 ± 2.1kJ/molVSperos and Rossini, 1960ALS
Deltavap50.3kJ/molN/ASperos and Rossini, 1960DRB
Quantity Value Units Method Reference Comment
Deltasub62.5kJ/molHBondi, 1963See also Chickos, Hosseini, et al., 1993.; AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
45.5386.A,GSStephenson and Malanowski, 1987Based on data from 371. - 473. K. See also Camin and Rossini, 1955.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
373.03 - 469.534.000471594.687-69.731Camin and Rossini, 1955Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
64.8230.BBondi, 1963AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
14.43242.8Domalski and Hearing, 1996AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Daubert, 1996
Daubert, T.E., Vapor-Liquid Critical Properties of Elements and Compounds. 5. Branched Alkanes and Cycloalkanes, J. Chem. Eng. Data, 1996, 41, 365-372. [all data]

Matzik and Schneider, 1985
Matzik, I.; Schneider, G.M., Fluid phase equilibria of binary mixtures of sulfur hexafluoride with octane, nonane, hendecane, and cis-decahydronaphthalene at temperature between 280 K and 440 K and at pressures up to 140 MPa, Ber. Bunsen-Ges. Phys. Chem., 1985, 89, 551. [all data]

Pak and Kay, 1972
Pak, S.C.; Kay, W.B., Gas-Liquid Critical Temperatures of Mixtures. Benzene + n-Alkanes and Hexafluorobenzene + n-Alkanes, Ind. Eng. Chem. Fundam., 1972, 11, 255. [all data]

Cheng, McCoubrey, et al., 1962
Cheng, D.C.H.; McCoubrey, J.C.; Phillips, D.G., Critical Temperatures of Some Organic Cyclic Compounds, Trans. Faraday Soc., 1962, 58, 224. [all data]

Speros and Rossini, 1960
Speros, D.M.; Rossini, F.D., Heats of combustion and formation of naphthalene, the two methylnaphthalenes, cis and trans decahydronaphthalene and related compounds, J. Phys. Chem., 1960, 64, 1723-1727. [all data]

Bondi, 1963
Bondi, A., Heat of Siblimation of Molecular Crystals: A Catalog of Molecular Structure Increments., J. Chem. Eng. Data, 1963, 8, 3, 371-381, https://doi.org/10.1021/je60018a027 . [all data]

Chickos, Hosseini, et al., 1993
Chickos, James S.; Hosseini, Sarah; Hesse, Donald G.; Liebman, Joel F., Heat capacity corrections to a standard state: a comparison of new and some literature methods for organic liquids and solids, Struct Chem, 1993, 4, 4, 271-278, https://doi.org/10.1007/BF00673701 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Camin and Rossini, 1955
Camin, David L.; Rossini, Frederick D., Physical Properties of Fourteen API Research Hydrocarbons, C 9 to C 15, J. Phys. Chem., 1955, 59, 11, 1173-1179, https://doi.org/10.1021/j150533a014 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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