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Naphthalene, decahydro-, cis-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Deltafgas-40.45 ± 0.55kcal/molCcbSperos and Rossini, 1960ALS
Deltafgas-40.54kcal/molN/ADavies and Gilbert, 1941Value computed using «DELTA»fHliquid° value of -219.9±1.3 kj/mol from Davies and Gilbert, 1941 and «DELTA»vapH° value of 50.3 kj/mol from Speros and Rossini, 1960.; DRB

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
9.50050.Dorofeeva O.V., 1988Recommended values agree with results of statistical calculations [ Miyazawa T., 1958, Chang S., 1970] within their uncertainties. These functions are also reproduced in the reference book [ Frenkel M., 1994].; GT
14.31100.
19.83150.
25.848200.
36.264273.15
40.19 ± 0.24298.15
40.480300.
56.506400.
71.121500.
83.528600.
93.922700.
102.67800.
110.08900.
116.381000.
121.761100.
126.361200.
130.311300.
133.711400.
136.651500.

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
56.589400.Miyazawa T., 1958GT
65.010450.

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafliquid-52.45 ± 0.22kcal/molCcbSperos and Rossini, 1960 
Deltafliquid-52.55 ± 0.32kcal/molCcbDavies and Gilbert, 1941Reanalyzed by Cox and Pilcher, 1970, Original value = -52.75 kcal/mol
Quantity Value Units Method Reference Comment
Deltacliquid-1502.92 ± 0.22kcal/molCcbSperos and Rossini, 1960Corresponding «DELTA»fliquid = -52.43 kcal/mol (simple calculation by NIST; no Washburn corrections)
Deltacliquid-1502.80 ± 0.30kcal/molCcbDavies and Gilbert, 1941Reanalyzed by Cox and Pilcher, 1970, Original value = -1502.4 ± 0.1 kcal/mol; Corresponding «DELTA»fliquid = -52.55 kcal/mol (simple calculation by NIST; no Washburn corrections)
Deltacliquid-1499.9kcal/molCcbHuckel and Mentzel, 1926Corresponding «DELTA»fliquid = -55.4 kcal/mol (simple calculation by NIST; no Washburn corrections)
Deltacliquid-1501.18 ± 0.97kcal/molCcbRoth and Lasse, 1925Corresponding «DELTA»fliquid = -54.17 kcal/mol (simple calculation by NIST; no Washburn corrections)

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Speros and Rossini, 1960
Speros, D.M.; Rossini, F.D., Heats of combustion and formation of naphthalene, the two methylnaphthalenes, cis and trans decahydronaphthalene and related compounds, J. Phys. Chem., 1960, 64, 1723-1727. [all data]

Davies and Gilbert, 1941
Davies, G.F.; Gilbert, E.C., The heat of combustion of cis- and trans-decahydronaphthalene, J. Am. Chem. Soc., 1941, 63, 1585-1586. [all data]

Dorofeeva O.V., 1988
Dorofeeva O.V., Thermodynamic Properties of Polycyclic Aromatic Hydrocarbons in the Gaseous Phase. Institute for High Temperatures, USSR Academy of Sciences, Preprint No.1-238 (in Russian), Moscow, 1988. [all data]

Miyazawa T., 1958
Miyazawa T., Thermodynamic functions for gaseous cis- and trans-decalins from 298 to 1000 K, J. Am. Chem. Soc., 1958, 80, 60-62. [all data]

Chang S., 1970
Chang S., The heats of combustion and strain energies of bicyclo[n.m.0]alkanes, J. Am. Chem. Soc., 1970, 92, 3109-3118. [all data]

Frenkel M., 1994
Frenkel M., Thermodynamics of Organic Compounds in the Gas State, Vol. I, II, Thermodynamics Research Center, College Station, Texas, 1994, 1994. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Huckel and Mentzel, 1926
Huckel, W.; Mentzel, R., Zur Stereochemie bicyclischer Ringsteme II. Die Stereoisomerie des Dekahydronaphtalins und seiner Derivate II. Stereoisomere «beta»-substituierte Dekaline, Ann., 1926, 451, 109-132. [all data]

Roth and Lasse, 1925
Roth, W.A.; Lasse, R., Verbrennungswarme der Dekahydro-naphthaline und der Dekalone, Ann., 1925, 441, 48-53. [all data]


Notes

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