Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Cyclohexanone, 5-methyl-2-(1-methylethyl)-, cis-


Normal alkane RI, non-polar column, custom temperature program

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1Polydimethyl siloxane with 5 % Ph groupsPolydimethyl siloxane with 5 % Ph groupsSiloxane, 5 % PhPolydimethyl siloxane, 5 % phenyl
Column length (m) 30.    
Carrier gas Hydrogen    
Substrate      
Column diameter (mm) 0.25    
Phase thickness (mum) 0.25    
Program 45 0C 3 0C/min -> 175 0C 15 0C/min -> 300 0C (10 min)not specifiednot specifiednot specifiednot specified
I 1126.1165.1175.1164.1164.
ReferenceAlbano, Lima, et al., 2012Robinson, Adams, et al., 2012Robinson, Adams, et al., 2012VOC BinBase, 2012Skogerson, Wohlgemuth, et al., 2011
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1HP-5 MSDB-1DB-1DB-5 MS
Column length (m) 60.60.30.30.30.
Carrier gas HeliumHeliumHydrogenHydrogenHelium
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (mum) 0.250.250.250.250.25
Program 50 0C (5 min) 3 0C/min -> 120 0C 5 0C/min -> 250 0C (3 min) 15 0C/min -> 300 0C (20 min)60 0C ( 1 min) 5 0C/min -> 200 0C (1 min) 20 0C/min -> 280 0C (21 min)45 0C 3 0C/min -> 175 0C 15 0C/min -> 300 0C (10 min)45 0C 3 0C/min -> 175 0C 15 0C/min -> 300 0C (10 min)not specified
I 1155.1174.1126.1126.1170.
ReferenceDelort and Jaquier, 2009Jalali-Heravi, Parastar, et al., 2009Mendes, Trindade, et al., 2009Mendes, Trindade, et al., 2009, 2Su, Wang, et al., 2009
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5 MSHP-5DB-1SE-52CP Sil 8 CB
Column length (m) 30.30.30.30.50.
Carrier gas HeliumHeliumHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.320.32
Phase thickness (mum) 0.250.250.250.150.25
Program 40 0C (5 min) 2 0C/min -> 250 0C (15 min) 10 0C/min -> 270 0Cnot specified45C => 3C/min => 175C => 15C/min => 300C (10min)45C => 1C/min => 100C => 5C/min => 250C (10min)60C(2min) => 5C/min => 160C(1min) => 10C/min => 250C (3min)
I 1163.1146.1126.1163.1163.
ReferenceFormisano, Rigano, et al., 2007Ristic, Krivokuca-Dokic, et al., 2007Figueiredo A.C., Barroso J.G., et al., 2006Tognolini, Barocelli, et al., 2006Radudienë, Judpintienë, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5SE-30DB-1Polydimethyl siloxanesOV-101
Column length (m)   30. 60.
Carrier gas   He  
Substrate      
Column diameter (mm)   0.25 0.25
Phase thickness (mum)   0.25  
Program not specifiednot specified45C => 3C/min => 175C => 15C/min => 240C (10min)not specifiednot specified
I 1164.1150.1126.1151.1151.
ReferenceVilaseca, Guy, et al., 2004Vinogradov, 2004Baratta, Dorman, et al., 1998Zenkevich, 1997Shibamoto, 1987
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type Packed
Active phase OV-101
Column length (m) 2.5
Carrier gas N2
Substrate Chromosorb G 60-80mesh DMCS
Column diameter (mm)  
Phase thickness (mum)  
Program not specified
I 1151.
ReferenceSwigar and Silverstein, 1981
Comment MSDC-RI

References

Go To: Top, Normal alkane RI, non-polar column, custom temperature program, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Albano, Lima, et al., 2012
Albano, S.M.; Lima, A.S.; Miguel, M.G.; Pedro, L.G.; Barroso, J.G.; Figueiredo, A.C., Antioxidant, anti-5-lipoxygenase and antiacetylcholinesterase activities of essential oils and decoction water of some aromatic plants, Rec. Nat. Prod., 2012, 6, 1, 35-48. [all data]

Robinson, Adams, et al., 2012
Robinson, A.L.; Adams, D.O.; Boss, P.K.; Heymann, H.; Solomon, P.S.; Trengove, R.D., Influence of geographic origine on the sensory characteristics and wine composition of Vitus viniferas cv. Cabernet Sauvignon wines from Australia (Supplemental data), Am. J. Enol. Vitic., 2012, 64, 4, 467-476, https://doi.org/10.5344/ajev.2012.12023 . [all data]

VOC BinBase, 2012
VOC BinBase, The volatile compound BinBase (VOC BinBase), 2012, retrieved from http://fiehnlab.ucdavis.edu/projects/VocBinBase and http://binbase.sourceforge.net. [all data]

Skogerson, Wohlgemuth, et al., 2011
Skogerson, K.; Wohlgemuth, G.; Fiehn, O., VocBinNase, 2011, retrieved from http://fiehnlab.ucdavis.edu/projects//VocBinBase. [all data]

Delort and Jaquier, 2009
Delort, E.; Jaquier, A., Novel terpenyl esters from Australian finger lime (Citrus australasica) peel extract, Flav. Fragr. J., 2009, 24, 3, 123-132, https://doi.org/10.1002/ffj.1922 . [all data]

Jalali-Heravi, Parastar, et al., 2009
Jalali-Heravi, M.; Parastar, H.; Ebrahimi-Najafabadi, H., Chracterization of volatile components of Iranian saffron using factorial-based response surface modeling of ultrasonic extraction combined with gas chromatography - mass spectrometry analysis, J. Chromatogr. A, 2009, 1216, 33, 6088-6097, https://doi.org/10.1016/j.chroma.2009.06.067 . [all data]

Mendes, Trindade, et al., 2009
Mendes, M.D.; Trindade, H.; Figueiredo, A.C.; Pedro, L.G.; Barroso, J.G., Chaerophyllum azoricun Trel. grown in the Azores archipelago, Portugal: evaluation of the genetic diversity using molecular markers and comparison with volatile oils profiles, Flavour Fragr. J., 2009, 24, 5, 259-265, https://doi.org/10.1002/ffj.1939 . [all data]

Mendes, Trindade, et al., 2009, 2
Mendes, M.D.; Trindade, H.; Figueiredo, A.C.; Barroso, J.G.; Fontinha, S.S.; Pedro, L.G., Volatile and molecular characterization of two Portuguese endemic species: Angelica lignescens and Melanoselinium decipiens, Biochen. Systematics Ecol., 2009, 37, 2, 98-105, https://doi.org/10.1016/j.bse.2008.12.006 . [all data]

Su, Wang, et al., 2009
Su, Y.; Wang, C.; Yinlong, G., Analysis of volatile compounds from Mentha hapioealyx Briq. by GC-MS based on accurate mass measurements and retention indices, Acta Chem. Sinica, 2009, 67, 6, 546-554. [all data]

Formisano, Rigano, et al., 2007
Formisano, C.; Rigano, D.; Napolitano, F.; Senatore, F.; Arnold, N.A.; Piozzi, F.; Rosselli, S., Volatile constituents of Calamintha ariganifolia Boiss. growing wild in Lebanon, Natural Product Communications, 2007, 2, 12, 1253-1256. [all data]

Ristic, Krivokuca-Dokic, et al., 2007
Ristic, M.; Krivokuca-Dokic, D.; Radanovic, D.; Nastovski, T., Etarsko ulje Arnica montata i Arnica chamissonis, Hem. Ind., 2007, 61, 5, 272-277, https://doi.org/10.2298/HEMIND0704272R . [all data]

Figueiredo A.C., Barroso J.G., et al., 2006
Figueiredo A.C.; Barroso J.G.; Pedro L.G.; Fontinha S.S.; Sim-Sim M.; Sergio C.; Luis L.; Scheffers J.J.C., Asterella africana (Mont.) A. Evans grown on Madeira and in mainland Portugal: morphological data and composition of the essential oil, Flavour Fragr. J., 2006, 21, 3, 534-538, https://doi.org/10.1002/ffj.1611 . [all data]

Tognolini, Barocelli, et al., 2006
Tognolini, M.; Barocelli, E.; Ballabeni, V.; Bruni, R.; Bianchi, A.; Chiavarini, M.; Impicciatore, M., Comparative screening of plant essential oils: Phenylpropanoid moiety as basic core for antiplatelet activity, Life Sciences, 2006, 78, 13, 1419-1432, https://doi.org/10.1016/j.lfs.2005.07.020 . [all data]

Radudienë, Judpintienë, et al., 2005
Radudienë, J.; Judpintienë, A.; Peèiulytë, D.; Janulis, V., Chemical composition of essential oil and antimicrobial activity of Origanum vulgare, Biologija, 2005, 4, 53-58. [all data]

Vilaseca, Guy, et al., 2004
Vilaseca, A.; Guy, I.; Charles, B.; Guinaudeau, H.; de Arias, A.R.; Fournet, A., Chemical composition and insecticidal activity of Hedeoma mandoniana essential oils, J. Essent. Oil Res., 2004, 16, 4, 380-383, https://doi.org/10.1080/10412905.2004.9698749 . [all data]

Vinogradov, 2004
Vinogradov, B.A., Production, composition, properties and application of essential oils, 2004, retrieved from http://viness.narod.ru. [all data]

Baratta, Dorman, et al., 1998
Baratta, M.T.; Dorman, H.J.; Deans, S.G.; Figueiredo, A.C.; Barroso, J.G.; Ruberto, G., Antimicrobial and antioxidant properties of some commercial essential oils, Flavour Fragr. J., 1998, 13, 4, 235-244, https://doi.org/10.1002/(SICI)1099-1026(1998070)13:4<235::AID-FFJ733>3.0.CO;2-T . [all data]

Zenkevich, 1997
Zenkevich, I.G., Analytical Parameters of Components of Essential Oils for their Chromatographic and Chromato-Spectral Identificaiton. Oxsigenated derivatives of Mono- and Sesquiterpene Hydrocarbons, Rastit, Resursy (Rus.), 1997, 33, 1, 16-28. [all data]

Shibamoto, 1987
Shibamoto, T., Retention Indices in Essential Oil Analysis in Capillary Gas Chromatography in Essential Oil Analysis, Sandra, P.; Bicchi, C., ed(s)., Hutchig Verlag, Heidelberg, New York, 1987, 259-274. [all data]

Swigar and Silverstein, 1981
Swigar, A.A.; Silverstein, R.M., Monoterpenes, Aldrich Chemical Company, Milwaukee, WI, USA, 1981, 130. [all data]


Notes

Go To: Top, Normal alkane RI, non-polar column, custom temperature program, References