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Benzene, 1,2,3,4-tetramethyl-

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Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SPB-5HP-5Petrocol DHDB-5DB-5
Column length (m) 60.30.50.30.30.
Carrier gas  HeHeHeHe
Substrate      
Column diameter (mm) 0.320.250.250.250.25
Phase thickness (mum) 1.0.250.50.250.25
Tstart (C) 40.50.35.40.40.
Tend (C) 230.220.200.310.310.
Heat rate (K/min) 3.3.3.4.4.
Initial hold (min) 2. 10. 5.
Final hold (min) 10.20.10.  
I 1120.1122.1145.31149.91148.2
ReferenceEngel and Ratel, 2007Xian Q., Chen H., et al., 2006Censullo, Jones, et al., 2003Song, Lai, et al., 2003Song, Lai, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5DB-5OV-1DB-5
Column length (m) 30.30.30.25.30.
Carrier gas HeHeHe He
Substrate      
Column diameter (mm) 0.250.250.250.20.25
Phase thickness (mum) 0.250.250.250.330.25
Tstart (C) 40.40.40.100.40.
Tend (C) 310.310.310.180.310.
Heat rate (K/min) 2.4.6.5.2.
Initial hold (min)      
Final hold (min)      
I 1144.21149.91153.81175.21144.2
ReferenceSong, Lai, et al., 2003Song, Lai, et al., 2003Song, Lai, et al., 2003Zhang, Shen, et al., 2000Lai and Song, 1995
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5DB-5DB-5Petrocol DH
Column length (m) 30.30.30.30.100.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (mum) 0.250.250.250.250.5
Tstart (C) 40.40.40.40.30.
Tend (C) 310.310.310.310.220.
Heat rate (K/min) 4.6.4.4.1.
Initial hold (min)    5. 
Final hold (min)      
I 1149.91153.81149.91148.21135.84
ReferenceLai and Song, 1995Lai and Song, 1995Lai and Song, 1995Lai and Song, 1995White, Douglas, et al., 1992
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillary
Active phase Petrocol DHOV-101
Column length (m) 100.108.
Carrier gas He 
Substrate   
Column diameter (mm) 0.250.25
Phase thickness (mum) 0.50.2
Tstart (C) 30.35.
Tend (C) 220.200.
Heat rate (K/min) 1.1.
Initial hold (min)   
Final hold (min)   
I 1136.1133.
ReferenceWhite, Hackett, et al., 1992Hayes and Pitzer, 1981
Comment MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Engel and Ratel, 2007
Engel, E.; Ratel, J., Correction of the data generated by mass spectrometry analyses of biological tissues: Application to food authentication, J. Chromatogr. A, 2007, 1154, 1-2, 331-341, https://doi.org/10.1016/j.chroma.2007.02.012 . [all data]

Xian Q., Chen H., et al., 2006
Xian Q.; Chen H.; Zou H.; Yin D., Chemical composition of essential oils of two submerged macrophytes, Ceratophyllum demersum L. and Vallisneria spiralis L., Flavour Fragr. J., 2006, 21, 3, 524-526, https://doi.org/10.1002/ffj.1588 . [all data]

Censullo, Jones, et al., 2003
Censullo, A.C.; Jones, D.R.; Wills, M.T., Speciation of the volatile organic compounds (VOCs) in solventborne aerosol coatings by solid phase microextraction-gas chromatography, J. Coat. Technol., 2003, 75, 936, 47-53, https://doi.org/10.1007/BF02697922 . [all data]

Song, Lai, et al., 2003
Song, C.; Lai, W.-C.; Madhusudan Reddy, K.; Wei, B., Chapter 7. Temperature-programmed retention indices for GC and GC-MS of hydrocarbon fuels and simulated distillation GC of heavy oils in Analytical advances for hydrocarbon research, Hsu,C.S., ed(s)., Kluwer Academic/Plenum Publishers, New York, 2003, 147-193. [all data]

Zhang, Shen, et al., 2000
Zhang, M.-J.; Shen, S.-D.; Chen, S.-Y.; Sun, Y.-H., Analysis of heavy oil fractions in high-temperature coal tar by capillary gas chromatography/fourier transform infrared spectrometry, Chin. J. Chromatogr., 2000, 18, 3, 241-246. [all data]

Lai and Song, 1995
Lai, W.-C.; Song, C., Temperature-programmed retention indices for g.c. and g.c.-m.s. analysis of coal- and petroleum-derived liquid fuels, Fuel, 1995, 74, 10, 1436-1451, https://doi.org/10.1016/0016-2361(95)00108-H . [all data]

White, Douglas, et al., 1992
White, C.M.; Douglas, L.J.; Hackett, J.P.; Anderson, R.R., Characterization of synthetic gasoline from the chloromethane-zeolite reaction, Energy Fuels, 1992, 6, 1, 76-82, https://doi.org/10.1021/ef00031a012 . [all data]

White, Hackett, et al., 1992
White, C.M.; Hackett, J.; Anderson, R.R.; Kail, S.; Spock, P.S., Linear temperature programmed retention indices of gasoline range hydrocarbons and chlorinated hydrocarbons on cross-linked polydimethylsiloxane, J. Hi. Res. Chromatogr., 1992, 15, 2, 105-120, https://doi.org/10.1002/jhrc.1240150211 . [all data]

Hayes and Pitzer, 1981
Hayes, P.C., Jr.; Pitzer, E.W., Kovats indices as a tool in characterizing hydrocarbon fuels in temperature programmed glass capillary gas chromatography. Part 1. Qualitative identification, Inhouse rpt. for Air Force Wright Aeronautical Labs., Air Force Wright Aeronautical Labs., Wright-Patterson AFB, Ohio, 1981, 75. [all data]


Notes

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References