Diazene, bis(4-ethoxyphenyl)-, 1-oxide

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-37.4 ± 3.7kJ/molCcbAcree, Tucker, et al., 1993 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DH - Eugene S. Domalski and Elizabeth D. Hearing
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-163.6 ± 2.6kJ/molCcbAcree, Tucker, et al., 1993ALS
Δfsolid-45.6kJ/molCcbLemoul, 1908ALS
Δfsolid-45.86kJ/molCcbLemoult, 1906Author value for hf298-condensed=21.1 kcal/mol; ALS
Quantity Value Units Method Reference Comment
Δcsolid-8705.0 ± 1.5kJ/molCcbAcree, Tucker, et al., 1993ALS
Δcsolid-8822.8kJ/molCcbLemoul, 1908ALS
Δcsolid-8822.8kJ/molCcbLemoult, 1906Author value for hf298-condensed=21.1 kcal/mol; ALS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
607.430.Kreutzer, 1938Value a few degrees below anisotropic-isotropic liquid-liquid transition at 436 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δsub126.2 ± 2.7kJ/molCAcree, Tucker, et al., 1993ALS
Δsub126.2 ± 2.7kJ/molCAcree, 1993AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
27.000406.5Acree, Tucker, et al., 1993DH

Enthalpy of phase transition

ΔHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
1.700438.5liquidliquidAcree, Tucker, et al., 1993Nematic/liq.; DH

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Additional Data

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Owner SRD/NIST
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin EPA-IR VAPOR PHASE LIBRARY
State gas

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin P.A. Leclercq, Lab. Instrum. Anal., Tech. Univ. Eindhoven, Netherlands
NIST MS number 221615

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Acree, Tucker, et al., 1993
Acree, W.E., Jr.; Tucker, S.A.; Pilcher, G.; Paz Andrade, M.I.; Ribeiro da Silva, M.D.M.C., Enthalpies of combustion of p-azoxyanisole p-azoxyphenetole: the dissociation enthalpy of the N-O bonds. Enthalpies of crystal-to-(liquid crystal) transitions, J. Chem. Thermodyn., 1993, 25, 653-659. [all data]

Lemoul, 1908
Lemoul, M.P., Recherches theoriques et experimentals sur les chaleurs de combustion et de formation des couposes organiques, Anal. Chem., 1908, 184-190. [all data]

Lemoult, 1906
Lemoult, M.P., Thermochimie. - Chaleur de combustion et de formation de quelques composes cycliques azotes, Compt. Rend., 1906, 143, 772-775. [all data]

Kreutzer, 1938
Kreutzer, C., Kalorimetrische Messungen beim Übergang von der anisotropen zur isotropen flüssigen Phase, Ann. Physik. [5]33, 1938, 192-209. [all data]

Acree, 1993
Acree, W., Enthalpies of combustion of p-azoxyanisole and p-azoxyphenetole: the dissociation enthalpy of the N-O bonds. Enthalpies of crystal-to-(liquid crystal) transitions, The Journal of Chemical Thermodynamics, 1993, 25, 5, 653-659, https://doi.org/10.1006/jcht.1993.1062 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References