(+)-2-Bornanone

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
solid,1 bar69.254cal/mol*KN/ANagumo, Matsuo, et al., 1989crystaline, I phase; Annealed sample.

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
59.11300.13Nagumo, Matsuo, et al., 1989crystaline, I phase; T = 14 to 375 K. Unsmoothed experimental datum.
58.1259.White and Morgan, 1935crystaline, I phase; T = 213 to 259 K.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tfus451.8KN/AAndersson and Ross, 1992Crystal phase 1 phase; Uncertainty assigned by TRC = 0.5 K; TRC
Tfus463.38KN/ADonnelly, Drewes, et al., 1990Uncertainty assigned by TRC = 0.2 K; TRC
Tfus452.KN/AMjojo, 1979Crystal phase 1 phase; Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Δvap13.2kcal/molGCvan Roon, Parsons, et al., 2002AC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Method Reference Comment
1.3452.DSCMjojo, 1979, 2AC

Temperature of phase transition

Ttrs (K) Initial Phase Final Phase Reference Comment
244.19crystaline, IIcrystaline, INagumo, Matsuo, et al., 1989DH

Enthalpy of phase transition

ΔHtrs (kcal/mol) Temperature (K) Initial Phase Final Phase Reference Comment
1.671243.9crystaline, IIcrystaline, ISchfer, 1953DH
1.859243.crystaline, IIcrystaline, IWhite and Morgan, 1935DH

Entropy of phase transition

ΔStrs (cal/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
6.86243.9crystaline, IIcrystaline, ISchfer, 1953DH
7.65243.crystaline, IIcrystaline, IWhite and Morgan, 1935DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nagumo, Matsuo, et al., 1989
Nagumo, T.; Matsuo, T.; Suga, H., Thermodynamic study on camphor crystals, Thermochim. Acta, 1989, 139, 121-132. [all data]

White and Morgan, 1935
White, A.H.; Morgan, S.O., Transitions in camphor and chemically related compounds. II. Vibration of atomic groups, J. Am. Chem. Soc., 1935, 57, 2078-2086. [all data]

Andersson and Ross, 1992
Andersson, O.; Ross, R.G., Thermal conductivity of (+)- and (±)-camphor at pressures up to 0.5 GPa and temperatures down to 40 K, Mol. Phys., 1992, 76, 433-44. [all data]

Donnelly, Drewes, et al., 1990
Donnelly, J.R.; Drewes, L.A.; Johnson, R.L.; Munslow, W.D.; Knapp, K.K.; Sovocool, G.W., Purity and heat of fusion data for environmental standards as determined by differential scanning calorimetry, Thermochim. Acta, 1990, 167, 2, 155, https://doi.org/10.1016/0040-6031(90)80476-F . [all data]

Mjojo, 1979
Mjojo, C.C., Order-disorder phenomena: part 2. order-disorder phase equilibria in d-and l-systems of camphor and related compounds., J. Chem. Soc., Faraday Trans. 2, 1979, 75, 692-703. [all data]

van Roon, Parsons, et al., 2002
van Roon, André; Parsons, John R.; Govers, Harrie A.J., Gas chromatographic determination of vapour pressure and related thermodynamic properties of monoterpenes and biogenically related compounds, Journal of Chromatography A, 2002, 955, 1, 105-115, https://doi.org/10.1016/S0021-9673(02)00200-5 . [all data]

Mjojo, 1979, 2
Mjojo, Chodziwadziwa C., Order?disorder phenomena. Part 2.?Order?disorder phase equilibria in D- and L-systems of camphor and related compounds, J. Chem. Soc., Faraday Trans. 2, 1979, 75, 692, https://doi.org/10.1039/f29797500692 . [all data]

Schfer, 1953
Schfer, K., Fenomenos de orden y desorden en solidos, An. R. Soc. Esp. Fis. Quim. Ser., 1953, B 49, 161-174. [all data]


Notes

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