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1,3-Butadiyne

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil284. ± 3.KAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus263.KN/APauling, Springall, et al., 1939Uncertainty assigned by TRC = 2. K; TRC
Tfus237.7KN/AStraus and Kollek, 1926Uncertainty assigned by TRC = 2.5 K; TRC
Tfus237.KN/AMueller, 1925Uncertainty assigned by TRC = 3. K; TRC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
25.4258.N/AStraus and Kollek, 2006Based on data from 195. - 273. K. See also Boublik, Fried, et al., 1984.; AC
33.4219.N/ATanneberger, 2006Based on data from 188. - 234. K. See also Boublik, Fried, et al., 1984.; AC
26.1268.AStephenson and Malanowski, 1987Based on data from 237. - 283. K. See also Dykyj, 1971.; AC
26.4267.N/AStull, 1947Based on data from 191. - 282. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
190.7 - 282.93.05288570.271-95.334Stull, 1947Coefficents calculated by NIST from author's data.
195.0 - 273.2.64407460.684-108.556Straus and Kollek, 1926, 2Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
36.3188. - 234.N/ATanneberger, 2006AC
36.2211.AStull, 1947Based on data from 190. - 232. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pauling, Springall, et al., 1939
Pauling, L.; Springall, H.D.; Palmer, K.J., The Electron Diffraction Investigation of Methylacetylene, Dimethyl- acetylene, Dimethyldiacetylene, Methyl Cyanide, Diacetylene and Cyanogen cyanogen, J. Am. Chem. Soc., 1939, 61, 927-8. [all data]

Straus and Kollek, 1926
Straus, F.; Kollek, L., About Diacetylene, Ber. Dtsch. Chem. Ges., 1926, 59, 1664-81. [all data]

Mueller, 1925
Mueller, F.G., Diacetylene (1,3-butadiyne), Helv. Chim. Acta, 1925, 8, 826-32. [all data]

Straus and Kollek, 2006
Straus, Fritz; Kollek, Leo, Über Diacetylen, Ber. dtsch. Chem. Ges. A/B, 2006, 59, 8, 1664-1681, https://doi.org/10.1002/cber.19260590804 . [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

Tanneberger, 2006
Tanneberger, H., Einige Bemerkungen über die Dampfdruck-Kurve des Diacetylens (Butadiins)., Ber. dtsch. Chem. Ges. A/B, 2006, 66, 4, 484-486, https://doi.org/10.1002/cber.19330660408 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Dykyj, 1971
Dykyj, J., Petrochemia, 1971, 11, 2, 27. [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Straus and Kollek, 1926, 2
Straus, F.; Kollek, L., Uber Diacetylen, Ber. Dtsch. Chem. Ges., 1926, 59, 8, 1664-1681, https://doi.org/10.1002/cber.19260590804 . [all data]


Notes

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