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1H-Indene, octahydro-, cis-

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

1H-Indene, octahydro-, cis- = 1H-Indene, octahydro-, trans-

By formula: C9H16 = C9H16

Quantity Value Units Method Reference Comment
Deltar-3.10kJ/molEqkFinke, McCullough, et al., 1972liquid phase
Deltar-2.4 ± 0.2kJ/molEqkBlanchard and Schleyer, 1963liquid phase; Heat of isomerization
Deltar-4.5 ± 0.4kJ/molEqkAllinger and Coke, 1960liquid phase

8Hydrogen + 2Indene = 1H-Indene, octahydro-, trans- + 1H-Indene, octahydro-, cis-

By formula: 8H2 + 2C9H8 = C9H16 + C9H16

Quantity Value Units Method Reference Comment
Deltar-585.2 ± 4.2kJ/molChydDolliver, Gresham, et al., 1937gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -587.4 ± 4.2 kJ/mol; At 355 °K

6Hydrogen + 2Indane = 1H-Indene, octahydro-, trans- + 1H-Indene, octahydro-, cis-

By formula: 6H2 + 2C9H10 = C9H16 + C9H16

Quantity Value Units Method Reference Comment
Deltar-377.1 ± 2.1kJ/molChydDolliver, Gresham, et al., 1937gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -383. ± 2. kJ/mol; At 355 °K

3Hydrogen + Indane = 1H-Indene, octahydro-, cis-

By formula: 3H2 + C9H10 = C9H16

Quantity Value Units Method Reference Comment
Deltar-192.kJ/molEqkFrye and Weitkamp, 1969gas phase

1H-Indene, octahydro-, trans- = 1H-Indene, octahydro-, cis-

By formula: C9H16 = C9H16

Quantity Value Units Method Reference Comment
Deltar4.456kJ/molEqkFinke, McCullough, et al., 1972gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Finke, McCullough, et al., 1972
Finke, H.L.; McCullough, J.P.; Messerly, J.F.; Osborn, A.; Douslin, D.R., cis- and trans-Hexahydroindan. Chemical thermodynamic properties and isomerization equilibrium, J. Chem. Thermodyn., 1972, 4, 477-494. [all data]

Blanchard and Schleyer, 1963
Blanchard, K.R.; Schleyer, P., Quantitative study of the interconversion of hydrindane isomers by aluminum bromide, J. Org. Chem., 1963, 28, 247-248. [all data]

Allinger and Coke, 1960
Allinger, N.L.; Coke, J.L., The relative stabilities of cis and trans isomers. VII. The hydrindanes, J. Am. Chem. Soc., 1960, 82, 2553-2556. [all data]

Dolliver, Gresham, et al., 1937
Dolliver, M.a.; Gresham, T.L.; Kistiakowsky, G.B.; Vaughan, W.E., Heats of organic reactions. V. Heats of hydrogenation of various hydrocarbons, J. Am. Chem. Soc., 1937, 59, 831-841. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Frye and Weitkamp, 1969
Frye, C.G.; Weitkamp, A.W., Equilibrium hydrogenations of multi-ring aromatics, J. Chem. Eng. Data, 1969, 14, 372-376. [all data]


Notes

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