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1,3-Difluoro-2-propanol


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

CN- + 1,3-Difluoro-2-propanol = (CN- bullet 1,3-Difluoro-2-propanol)

By formula: CN- + C3H6F2O = (CN- bullet C3H6F2O)

Quantity Value Units Method Reference Comment
Deltar98.3kJ/molICRLarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971
Quantity Value Units Method Reference Comment
Deltar109.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971
Quantity Value Units Method Reference Comment
Deltar66.1kJ/molICRLarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971

Chlorine anion + 1,3-Difluoro-2-propanol = (Chlorine anion bullet 1,3-Difluoro-2-propanol)

By formula: Cl- + C3H6F2O = (Cl- bullet C3H6F2O)

Quantity Value Units Method Reference Comment
Deltar98.7kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3COOH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3COOH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2
Quantity Value Units Method Reference Comment
Deltar67.4kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3COOH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2

Fluorine anion + 1,3-Difluoro-2-propanol = (Fluorine anion bullet 1,3-Difluoro-2-propanol)

By formula: F- + C3H6F2O = (F- bullet C3H6F2O)

Quantity Value Units Method Reference Comment
Deltar158.kJ/molICRLarson and McMahon, 1983gas phase; switching reaction(H2O), Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970
Quantity Value Units Method Reference Comment
Deltar111.J/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(H2O), Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970
Quantity Value Units Method Reference Comment
Deltar125.kJ/molICRLarson and McMahon, 1983gas phase; switching reaction(H2O), Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Larson and McMahon, 1987
Larson, J.W.; McMahon, T.B., Hydrogen bonding in gas phase anions. The energetics of interaction between cyanide ion and bronsted acids, J. Am. Chem. Soc., 1987, 109, 6230. [all data]

Payzant, Yamdagni, et al., 1971
Payzant, J.D.; Yamdagni, R.; Kebarle, P., Hydration of CN-, NO2-, NO3-, and HO- in the gas phase, Can. J. Chem., 1971, 49, 3308. [all data]

Larson and McMahon, 1984
Larson, J.W.; McMahon, T.B., Hydrogen bonding in gas phase anions. An experimental investigation of the interaction between chloride ion and bronsted acids from ICR chloride exchange equilibria, J. Am. Chem. Soc., 1984, 106, 517. [all data]

Larson and McMahon, 1984, 2
Larson, J.W.; McMahon, T.B., Gas phase negative ion chemistry of alkylchloroformates, Can. J. Chem., 1984, 62, 675. [all data]

Larson and McMahon, 1983
Larson, J.W.; McMahon, T.B., Strong hydrogen bonding in gas-phase anions. An ion cyclotron resonance determination of fluoride binding energetics to bronsted acids from gas-phase fluoride exchange equilibria measurements, J. Am. Chem. Soc., 1983, 105, 2944. [all data]

Arshadi, Yamdagni, et al., 1970
Arshadi, M.; Yamdagni, R.; Kebarle, P., Hydration of Halide Negative Ions in the Gas Phase. II. Comparison of Hydration Energies for the Alkali Positive and Halide Negative Ions, J. Phys. Chem., 1970, 74, 7, 1475, https://doi.org/10.1021/j100702a014 . [all data]


Notes

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