3-Cyclopentene-1-acetaldehyde, 2,2,3-trimethyl-, (R)-


Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP-Sil PONA GBHP-5BP-1DB-5SPB-1
Column length (m) 100.25.50.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.220.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 140.60.60.60.50.
Tend (C) 230.240.220.240.250.
Heat rate (K/min) 5.4.2.3.5.
Initial hold (min) 10.2.  3.
Final hold (min) 25. 20. 15.
I 1120.1119.1102.1127.1128.
ReferenceCunicao, Lopes, et al., 2007Dehghan, Solaimanian, et al., 2007Duquesnoy, Castola, et al., 2007Flamini, Cioni, et al., 2007Radulovic, Lazarevic, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSHP-5MSHP-5MSBP-1BP-1
Column length (m) 30.30.30.50.50.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.220.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.80.60.60.
Tend (C) 280.280.300.220.220.
Heat rate (K/min) 4.4.4.2.2.
Initial hold (min) 5.5.   
Final hold (min)    20.20.
I 1125.1135.1130.51100.1103.
ReferenceRadulovic, Lazarevic, et al., 2007Saroglou, Marin, et al., 2007Zeng, Zhao, et al., 2007Boti, Bighelli, et al., 2006Bousmaha, Boti, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase 5 % Phenyl methyl siloxaneDB-5BP-1HP-5MSHP-1
Column length (m) 25.50.50.20.25.
Carrier gas HeN2He He
Substrate      
Column diameter (mm) 0.250.20.220.250.2
Phase thickness (μm) 0.250.320.250.250.33
Tstart (C) 60.60.60.60.60.
Tend (C) 280.220.220.240.300.
Heat rate (K/min) 3.5.2.5.5.
Initial hold (min)  3. 4.3.
Final hold (min) 20.5.20.15.30.
I 1125.1125.1102.1128.1099.
ReferenceDjarri, Medjroubi, et al., 2006Esmaeili, Nematollahi, et al., 2006Gonny, Cavaleiro, et al., 2006Kallio, Jussila, et al., 2006Nath, Baruah, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSSPB-1HP-5MSDB-5HP-5MS
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeH2
Substrate      
Column diameter (mm) 0.250.20.250.250.25
Phase thickness (μm) 0.250.20.250.250.25
Tstart (C) 60.70.60.50.50.
Tend (C) 280.220.280.250.285.
Heat rate (K/min) 3.3.4.5.4.3
Initial hold (min)   5.2. 
Final hold (min)  15.   
I 1104.1102.1125.1126.1119.
ReferencePavlovic, Kovacevic, et al., 2006Salgueiro L.R., Pinto E., et al., 2006Saroglou, Dorizas, et al., 2006Su, Ho, et al., 2006Vujisic L., Vuckovic I., et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SE-54HP-5RTX-1CP Sil 5 CBHP-5
Column length (m) 50.30.60.50.30.
Carrier gas H2N2 H2He
Substrate      
Column diameter (mm) 0.250.250.220.220.25
Phase thickness (μm) 0.270.250.250.130.25
Tstart (C) 50.60.60.40.60.
Tend (C) 300.220.220.300.260.
Heat rate (K/min) 5.5.2.4.3.
Initial hold (min)  10.   
Final hold (min)   20.10. 
I 1125.1127.1107.1105.1126.
ReferenceBrantner, Pfeifhofer, et al., 2005Cioni, Flamini, et al., 2005Cozzani, Muselli, et al., 2005Idzojtic, Kajba, et al., 2005Javidnia, Miri, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-1SE-54SPB-1SPB-1
Column length (m) 30.30.30.30.30.
Carrier gas HeN2HeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.2
Phase thickness (μm) 0.250.250.250.250.2
Tstart (C) 40.50.60.70.70.
Tend (C) 260.200.260.220.220.
Heat rate (K/min) 2.5.2.3.3.
Initial hold (min) 5. 5.  
Final hold (min) 20.  15.15.
I 1122.1114.1122.1104.1102.
ReferenceSenatore, Napolitano, et al., 2005Tchoumbougnang, Zollo, et al., 2005Alma, Nitz, et al., 2004Antunes, Sevinate-Pinto, et al., 2004Cavaleiro, Salgueiro, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5DB-5HP-5MSHP-5HP-5
Column length (m) 30.30.30.30.30.
Carrier gas  N2HeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.25 
Tstart (C) 60.60.60.60.60.
Tend (C) 220.240.280.260.260.
Heat rate (K/min) 5.3.4.3.3.
Initial hold (min) 10. 5.  
Final hold (min)      
I 1127.1127.1125.1126.1125.
ReferenceCeccarini, Macchia, et al., 2004Flamini, Cioni, et al., 2004Grujic-Jovanovic, Skaltsa, et al., 2004Javidnia, Miri, et al., 2004Javidnia, Miri, et al., 2004, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSHP-5Optima 5HP-5MSDB-5
Column length (m) 30.50.25.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.20.250.250.25
Phase thickness (μm) 0.250.20.250.250.25
Tstart (C) 60.40.60.50.60.
Tend (C) 280.250.280.200.240.
Heat rate (K/min) 4.3.3.6.3.
Initial hold (min) 5.15. 1.5 
Final hold (min)  40.20.5.30.
I 1125.1130.1123.1133.1127.
ReferenceKarioti, Hadjipavlou-Litina, et al., 2004Stashenko, Jaramillo, et al., 2004Vérité, Nacer, et al., 2004Weissbecker, Holighaus, et al., 2004Bader, Caponi, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SPB-1DB-5HP-5HP-5MSHP-5
Column length (m) 30.25.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.20.250.250.250.25
Phase thickness (μm) 0.2 0.250.250.25
Tstart (C) 70.60.60.60.60.
Tend (C) 220.260.240.280.280.
Heat rate (K/min) 3.4.3.3.4.
Initial hold (min)     5.
Final hold (min) 15.    
I 1104.1127.1128.1126.1125.
ReferenceCavaleiro, Salgueiro, et al., 2003Javidnia, Miri, et al., 2003Macchioni, Cioni, et al., 2003Mimica-Dukic, Kujundzic, et al., 2003Skaltsa, Demetzos, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5HP-5MSHP-5CP Sil 5 CB
Column length (m) 30.30.30.30.25.
Carrier gas HeHeHeHeN2
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.60.60.
Tend (C) 280.280.300.280.280.
Heat rate (K/min) 3.3.3.3.4.
Initial hold (min)    5.6.
Final hold (min)      
I 1126.1126.1125.1125.1099.
ReferenceTsiri, Kretsi, et al., 2003Tzakou, Couladis, et al., 2003Couladis, Chinou, et al., 2002Magiatis, Skaltsounis, et al., 2002Pino, Marbot, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP Sil 5 CBDB-1RTX-5RTX-5HP-5
Column length (m) 30.50.30.30.30.
Carrier gas H2HeHeHeHe
Substrate      
Column diameter (mm) 0.250.220.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.45.45.60.
Tend (C) 280.220.250.250.280.
Heat rate (K/min) 2.2.3.3.3.
Initial hold (min) 10. 6.6.5.
Final hold (min) 40.20.   
I 1099.1102.1125.1135.1123.
ReferencePino, Marbot, et al., 2002, 2Pintore, Usai, et al., 2002Shellie, Mondello, et al., 2002Shellie, Mondello, et al., 2002Aligiannis, Kalpoutzakis, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5HP-5MSDB-1BP-1
Column length (m) 30.30.30.60.50.
Carrier gas HeHeHeHe 
Substrate      
Column diameter (mm) 0.250.250.250.320.22
Phase thickness (μm) 0.250.250.251.0.25
Tstart (C) 60.60.60.40.60.
Tend (C) 260.380.280.220.220.
Heat rate (K/min) 3.3.3.2.2.
Initial hold (min)   5.5. 
Final hold (min) 10.   20.
I 1125.1121.1125.1106.1102.
ReferenceCouladis, Baziou, et al., 2001Couladis, Tsortanidou, et al., 2001Giamakis, Kretsi, et al., 2001Kim, 2001Rezzi, Cavaleiro, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSCP Sil 5 CBHP-5DB-1CP Sil 5 CB
Column length (m) 30.50.30.30.25.
Carrier gas HeH2He He
Substrate      
Column diameter (mm) 0.250.220.250.250.25
Phase thickness (μm) 0.250.130.250.25 
Tstart (C) 60.40.50.50.60.
Tend (C) 280.300.280.220.260.
Heat rate (K/min) 4.4.4.3.5.
Initial hold (min) 5. 5.3. 
Final hold (min)  10.   
I 1125.1107.1122.1098.1102.
ReferenceSkaltsa, Mavrommati, et al., 2001Pfeifhofer, 2000Skaltsa, Lazari, et al., 2000Muselli, Hoi, et al., 1999Weyerstahl, Marschall, et al., 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillary
Active phase BP-1BP-1
Column length (m) 50.50.
Carrier gas HeHe
Substrate   
Column diameter (mm) 0.220.22
Phase thickness (μm) 0.250.25
Tstart (C) 60.60.
Tend (C) 230.230.
Heat rate (K/min) 2.2.
Initial hold (min)   
Final hold (min) 35.35.
I 1106.1102.
ReferenceMariotti, Costa, et al., 1997Mariotti, Tomi, et al., 1997
Comment MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Javidnia, Miri, et al., 2004
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Javidnia, Miri, et al., 2004, 2
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Notes

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References