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Benzene, (1-ethylbutyl)-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltacliquid-1615.kcal/molCcbLamberti and Wise, 1953Corresponding «DELTA»fliquid = -128. kcal/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director

Quantity Value Units Method Reference Comment
Tboil481.4KN/ALamberti and Wise, 1953, 2Uncertainty assigned by TRC = 0.2 K
Tboil474.9KN/AGilman and Meals, 1943Uncertainty assigned by TRC = 4. K
Tboil483.KN/AHuston and Kaye, 1942Uncertainty assigned by TRC = 2. K
Quantity Value Units Method Reference Comment
Tfus217.78KN/ALamberti and Wise, 1953, 2Uncertainty assigned by TRC = 0.2 K

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Benzene, (1-ethylbutyl)- = Benzene, (1-methylpentyl)-

By formula: C12H18 = C12H18

Quantity Value Units Method Reference Comment
Deltar-0.07 ± 0.17kcal/molEqkPimerzin, Nesterova, et al., 1986liquid phase
Deltar-0.07 ± 0.02kcal/molEqkPimerzin, Nesterova, et al., 1985liquid phase; AlCl3
Deltar-0.07 ± 0.02kcal/molEqkNesterova, Pimerzin, et al., 1984liquid phase; At 325.0 K, see Pimerzin, Nesterova, et al., 1985, see Pimerzin, Nesterova, et al., 1986

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin CONTINENTAL OIL CO., PONCA CITY, OKLA, USA
NIST MS number 34754

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryCarbowax 20M90.1352.4Döring, Estel, et al., 1974Column length: 100. m; Column diameter: 0.2 mm

Normal alkane RI, polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillaryCarbowax 20M90.1352.Sutter, Peterson, et al., 1997 

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lamberti and Wise, 1953
Lamberti, J.M.; Wise, P.H., Synthesis and physical properties of some C12 and C13 phenylalkane and cyclohexylalkane hydrocarbons, J. Am. Chem. Soc., 1953, 75, 4787-4789. [all data]

Lamberti and Wise, 1953, 2
Lamberti, J.M.; Wise, P.H., Synthesis and Physical Properties of Some C11 ANd C12 Phenylalkane and Cyclohexylalkane Hydrocarbons, J. Am. Chem. Soc., 1953, 75, 4787. [all data]

Gilman and Meals, 1943
Gilman, H.; Meals, R.N., Rearrangements in the Friedel-Crafts Alkylation of Benzene, J. Org. Chem., 1943, 8, 126. [all data]

Huston and Kaye, 1942
Huston, R.C.; Kaye, I.A., The condensation of some secondary aliphatic alcohols with benzene in the presence of aluminum chloride, J. Am. Chem. Soc., 1942, 64, 1576-80. [all data]

Pimerzin, Nesterova, et al., 1986
Pimerzin, A.A.; Nesterova, T.N.; Rozhnov, A.M., Equilibria of isomeric transformations and relations between thermodynamic properties of secondary alkylbenzenes, J. Chem. Thermodyn., 1986, 17, 641-648. [all data]

Pimerzin, Nesterova, et al., 1985
Pimerzin, a.A.; Nesterova, T.N.; Rozhnov, A.M., Equilibria of isomeric transformations and relations between thermodynamic properties of secondary alkylbenzenes, J. Chem. Thermodyn., 1985, 17, 641-648. [all data]

Nesterova, Pimerzin, et al., 1984
Nesterova, T.N.; Pimerzin, A.A.; Rozhnov, A.M.; Roshchupkina, I.Ya., Thermodynamics of aromatic hydrocarbons, Probl. Kalorim. Khim. Termodin., Dokl. Vses. Konf., 10th, 1984, 1, 225-227. [all data]

Döring, Estel, et al., 1974
Döring, C.E.; Estel, D.; Fischer, R., Kapillar-gaschromatographische Charakterisierung von C10-bis C12-Aromaten, J. Prakt. Chem., 1974, 316, 1, 1-12, https://doi.org/10.1002/prac.19743160102 . [all data]

Sutter, Peterson, et al., 1997
Sutter, J.M.; Peterson, T.A.; Jurs, P.C., Prediction of gas chromatographic retention indices of alkylbenzenes, Anal. Chim. Acta., 1997, 342, 2-3, 113-122, https://doi.org/10.1016/S0003-2670(96)00578-8 . [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), Gas Chromatography, References