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Phenol, 4-methyl-2-(1-methylethyl)-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-198.4kJ/molCcbBertholon, Giray, et al., 1971 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafliquid-280.kJ/molCcbBertholon, Giray, et al., 1971 
Quantity Value Units Method Reference Comment
Deltacliquid-5661.kJ/molCcbBertholon, Giray, et al., 1971Corresponding «DELTA»fliquid = -280. kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil507.65KN/ASowa, Hinton, et al., 1932Uncertainty assigned by TRC = 4. K; TRC
Quantity Value Units Method Reference Comment
Tfus308.15KN/ADewar and Puttnam, 1959Uncertainty assigned by TRC = 2. K; TRC
Tfus310.15KN/AKarr, 1957Uncertainty assigned by TRC = 2. K; TRC
Tfus306.65KN/AStroh, Seydel, et al., 1957Uncertainty assigned by TRC = 2. K; TRC
Tfus309.65KN/ACarpenter and Easter, 1955Uncertainty assigned by TRC = 2. K; TRC
Tfus309.15KN/AGuillaumin, 1910Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Deltavap77.74kJ/molCBertholon, Giray, et al., 1971ALS
Deltavap81.6kJ/molN/ABertholon, Giray, et al., 1971DRB

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas Chromatography

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryCP Sil 5 CB1262.Weyerstahl, Marschall, et al., 1999N2, 5. K/min; Column length: 25. m; Phase thickness: 0.39 «mu»m; Tstart: 60. C; Tend: 220. C

Normal alkane RI, polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryDB-Wax2179.Weyerstahl, Marschall, et al., 1999N2, 5. K/min; Column length: 60. m; Phase thickness: 0.25 «mu»m; Tstart: 60. C; Tend: 220. C

Normal alkane RI, polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryHP-Innowax FSC2181.Demirci, Baser, et al., 200360. m/0.25 mm/0.25 «mu»m, He; Program: 60C (10min) => 4C/min => 220C (10min) => 1C/min => 240C
CapillaryInnowax2181.Baser, Nuriddinov, et al., 200260. m/0.25 mm/0.25 «mu»m, He; Program: 60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bertholon, Giray, et al., 1971
Bertholon, G.; Giray, M.; Perrin, R.; Vincent-Falquet-Berny, M.F., No. 532. - Etude physicochimique des phenols. OX. - Ethanlpies de combustion et energies de resonance des alcoyl et aryphenols, Bull. Soc. Chim. France, 1971, 3180-3187. [all data]

Sowa, Hinton, et al., 1932
Sowa, F.J.; Hinton, H.D.; Nieuwland, J.A., Organic Reactions with Boron FLuoride II. The Rearrangement of Alkyl Phenyl Ethers, J. Am. Chem. Soc., 1932, 54, 2019. [all data]

Dewar and Puttnam, 1959
Dewar; Puttnam, J. Chem. Soc., 1959, 1959, 4086. [all data]

Karr, 1957
Karr, C., , U. S. Bur. Mines, Inform. Circ. IC 7802, 1957. [all data]

Stroh, Seydel, et al., 1957
Stroh, R.; Seydel, R.; Hahn, W., Alkylation of phenols with olefins., Angew. Chem., 1957, 69, 699. [all data]

Carpenter and Easter, 1955
Carpenter; Easter, J. Org. Chem., 1955, 20, 401. [all data]

Guillaumin, 1910
Guillaumin, C., Bull. Soc. Chim. Fr., 1910, 7, 332. [all data]

Weyerstahl, Marschall, et al., 1999
Weyerstahl, P.; Marschall, H.; Thefeld, K.; Rustaiyan, A., Constituents of the essential oil of Tanacetum (syn. Chrysanthemum) fruticulosum Ledeb. from Iran, Flavour Fragr. J., 1999, 14, 2, 112-120, https://doi.org/10.1002/(SICI)1099-1026(199903/04)14:2<112::AID-FFJ786>3.0.CO;2-1 . [all data]

Demirci, Baser, et al., 2003
Demirci, B.; Baser, K.H.C.; Yildiz, B.; Bahcecioglu, Z., Composition of the essential oils of six endemic Salvia spp. from Turkey, Flavour Fragr. J., 2003, 18, 2, 116-121, https://doi.org/10.1002/ffj.1173 . [all data]

Baser, Nuriddinov, et al., 2002
Baser, K.H.C.; Nuriddinov, H.R.; Ozek, T.; Demirci, A.B.; Azcan, N.; Nigmatullaev, A.M., Essential oil of Arischrada korolkowii from the Chatkal mountains of Uzbekistan, Chem. Nat. Compd. (Engl. Transl.), 2002, 38, 1, 51-53, https://doi.org/10.1023/A:1015729731464 . [all data]


Notes

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