1,2-Butanediamine

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-17.58 ± 0.20kcal/molCcbMesserly, Finke, et al., 1975 
Δfgas-17.68 ± 0.20kcal/molCcrGood and Moore, 1970 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-28.74 ± 0.19kcal/molCcrGood and Moore, 1970 
Quantity Value Units Method Reference Comment
Δcliquid-757.35 ± 0.18kcal/molCcrGood and Moore, 1970 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Δvap11.1 ± 0.05kcal/molIPDouslin and Osborn, 2002See also Good and Moore, 1970.; AC
Δvap11.16kcal/molVMesserly, Finke, et al., 1975ALS
Δvap11.2kcal/molIPMesserly, Finke, et al., 1975, 2Based on data from 251. - 293. K.; AC
Δvap11.06 ± 0.05kcal/molVGood and Moore, 1970ALS
Δvap11.0kcal/molN/AGood and Moore, 1970DRB

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Reference Comment
12.0278.Stephenson and Malanowski, 1987Based on data from 251. - 293. K. See also Messerly, Finke, et al., 1975, 2.; AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Messerly, Finke, et al., 1975
Messerly, J.F.; Finke, H.L.; Osborn, A.G.; Douslin, D.R., Low-temperature calorimetric and vapor-pressure studies on alkanediamines, J. Chem. Thermodyn., 1975, 7, 1029-10. [all data]

Good and Moore, 1970
Good, W.D.; Moore, R.T., Enthalpies of formation of ethylenediamine, 1,2,-propanediamine, 1,2,-butanediamine, 2-methyl-1,2-propanediamine, and isobutylamine C-N and N-F Thermochemical bond energies, J. Chem. Eng. Data, 1970, 15, 150-154. [all data]

Douslin and Osborn, 2002
Douslin, D.R.; Osborn, A., Pressure measurements in the 0.01-30 torr range with an inclined-piston gauge, J. Sci. Instrum., 2002, 42, 6, 369-373, https://doi.org/10.1088/0950-7671/42/6/301 . [all data]

Messerly, Finke, et al., 1975, 2
Messerly, J.F.; Finke, H.L.; Osborn, A.G.; Douslin, D.R., Low-temperature calorimetric and vapor-pressure studies on alkanediamines, J. Chem. Thermodynam., 1975, 7, 1029-1046. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

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