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Tetrakis(diethylamino)titanium


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas-628.2 ± 9.6kJ/molReviewMartinho Simões 
Deltafgas-410. ± 18.kJ/molReviewMartinho Simões 
Deltafgas-392.3 ± 7.1kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -1461.2 ± 3.1 kJ/mol for the enthalpy of formation of Ti(OEt)4(l)
Deltafgas-403.4 ± 8.1kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -1579.0 ± 3.9 kJ/mol for the enthalpy of formation of Ti(O-i-Pr)4(l)

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafliquid-722.8 ± 8.7kJ/molReviewMartinho Simões 
Deltafliquid-505. ± 18.kJ/molReviewMartinho Simões 
Deltafliquid-486.9 ± 5.9kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -1461.2 ± 3.1 kJ/mol for the enthalpy of formation of Ti(OEt)4(l)
Deltafliquid-498.0 ± 7.1kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -1579.0 ± 3.9 kJ/mol for the enthalpy of formation of Ti(O-i-Pr)4(l)
Quantity Value Units Method Reference Comment
Deltacliquid-12452. ± 18.kJ/molCC-SBMakhailov, Baev, et al., 1986 
Deltacliquid-12234.0 ± 8.4kJ/molCC-SBKol'yakova, Rabinovich, et al., 1971Please also see Pedley and Rylance, 1977.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltavap94.6 ± 4.0kJ/molCC-SBBaev, Mikhailov, et al., 1985 

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Makhailov, Baev, et al., 1986
Makhailov, V.E.; Baev, A.K.; Sachek, A.I.; Al'khimovich, V.M., Zh. Fiz. Khim., 1986, 60, 2306. [all data]

Kol'yakova, Rabinovich, et al., 1971
Kol'yakova, G.M.; Rabinovich, I.B.; Vyazanken, N.S., Dokl. Akad. Nauk SSSR, 1971, 200, 735. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Baev, Mikhailov, et al., 1985
Baev, A.K.; Mikhailov, V.E.; Baev, A.A., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1985, 28, 115. [all data]


Notes

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