Tris(dimethylamino)borane

• Formula: C₆H₁₈BN₃
• Molecular weight: 143.038
• IUPAC Standard InChI: InChI=1S/C6H18BN3/c1-8(2)7(9(3)4)10(5)6/h1-6H3 Copy

  
• IUPAC Standard InChIKey: SOLWORTYZPSMAK-UHFFFAOYSA-N Copy
• CAS Registry Number: 4375-83-1
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: B(N(CH3)2)3; Boranetriamine, hexamethyl-
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• Information on this page:
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • UV/Visible spectrum
  • References
  • Notes
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

UV/Visible spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Alexander N. Yermakov, Alexy A. Usov, Antonina A. Goncharova, Axlexander N. Leskin, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

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Additional Data

References

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), UV/Visible spectrum, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lappert, Litzow, et al., 1970
Lappert, M.F.; Litzow, M.R.; Pedley, J.B.; Riley, P.N.K.; Spalding, T.R.; Tweedale, A., Bonding studies of compounds of boron and the group IV elements. Part III.First ionisation potentials of some simple boron compounds by electron impact and by a new empirical molecular orbital method, J. Chem. Soc. A, 1970, 2320. [all data]

Lappert, Pedley, et al., 1966
Lappert, M.F.; Pedley, J.B.; Riley, P.N.K.; Tweedale, A., Ionisation potentials and electronic spectra of halogeno- and amino-boranes, and a study of some redistribution reactions, Chem. Commun., 1966, 788. [all data]

Baldwin, Lappert, et al., 1965
Baldwin, J.C.; Lappert, M.F.; Pedley, J.B.; Riley, P.N.K.; Sedgwick, R.D., Ionisation potentials and π-bonding in the series Cl_nB(NMe₂)_3-n, Inorg. Nucl. Chem. Letters, 1965, 1, 57. [all data]

King, Krishnamurthy, et al., 1972
King, G.H.; Krishnamurthy, S.S.; Lappert, M.F.; Pedley, J.B., Bonding studies of compounds of boron and the Group 4 elements. Part 9. Photoelectron spectra and bonding studies of halogeno-, dimethylamino-, and methyl-boranes, BX₃ and BX₂Y, Faraday Discuss. Chem. Soc., 1972, 54, 70. [all data]

Fuss, 1974
Fuss, W., Z. Naturforsch., 1974, 29b, 514. [all data]

Notes

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• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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